Nitrogen-containing ashless dispersants and lubricating oil composition containing same

Claim 2

An ashless dispersant for use in lubricating oil, characterised in that said dispersant is the product of reacting at a temperature of from about 100° to 350° C. (a) about 0.9 to 1.1 moles of a hydrocarbon-substituted succinic acid or anhydride wherein said hydrocarbon substituent has an average molecular weight of at least about 700, (b) about 0.1 to 1.0 moles of an alcohol containing 1 to 6 hydroxy groups, (c) about 0.01 to 0.5 moles of a primary or secondary hydroxy-substituted amine containing 1 to 3 hydroxy groups, (d) about 0.01 to 2.5 moles of a hydrocarbyl succinimide or succinamide, and (e) about 0.005 to 0.5 moles of a polyoxyalkylene amine having the structure ##STR7## wherein R is a divalent aliphatic hydrocarbon group containing 2 to 4 carbon atoms, R 1 is a polyvalent saturated hydrocarbon radical having the valence p and containing 2 to 10 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 40 such that the sum of all n's is from about 3 to 40 and p is an integer from 3 to 6, wherein said hydrocarbyl succinimide or succinamide in (d) is the product made by reacting a hydrocarbyl succinic anhydride, acid, or ester with an amine containing 2 to 6 amino nitrogen atoms, at least one of which is primary, and about 1 to 30 carbon atoms, at least part of said hydrocarbyl succinimide or succinamide containing at least one reactive primary or secondary amine group.

Claim 3

An ashless dispersant as claimed in claim 1 further characterized in that said alcohol is a hindered polyol containing 3 to 4 hydroxy groups.

Claim 4

An ashless dispersant as claimed in claim 2 further characterized in that the said hydrocarbon substituent of the hydrocarbon-substituted succinic acid or anhydride has a molecular weight from 700 to 5000.

Claim 5

An ashless dispersant as claimed in claim 2 further characterized in that said hydrocarbon substituted succinic acid or anhydride is a polyisobutylene-substituted succinic anhydride wherein said polyisobutylene substituent has an average molecular weight of about 700 to 2000 and said hindered polyol is selected from the group consisting of trimethylol ethane, trimethylol propane and pentaerythritol.

Claim 6

An ashless dispersant as claimed in claim 4 further characterized in that said primary or secondary hydroxy-substituted amine is selected from the group consisting of alkanol amines, dialkanol amines and tri-hydroxymethylaminomethane.

Claim 7

An ashless dispersant as claimed in claim 5 wherein said hydroxy substituted amine is selected from the group consisting of ethanol amine, diethanol amine and tri-hydroxymethylaminomethane.

Claim 8

An ashless dispersant as claimed in claim 6 further characterized in that said hydrocarbyl succinimide or succinamide is the product made by reacting polyisobutenyl succinic anhydride with a polyethyleneamine.

Claim 9

An ashless dispersant of claim 7 wherein said hindered polyol is pentaerythritol.

Claim 10

An ashless dispersant as claimed in claim 1 further characterized in that it is made by a process comprising reacting in a first stage: (a) about 0.9 to 1.1 moles of a hydrocarbon-substituted succinic acid or anhydride wherein said hydrocarbon substituent has an average molecular weight of at least about 700, (b) about 0.1 to 1.0 moles of an alcohol containing 1 to 6 hydroxy groups, and (c) about 0.01 to 0.5 moles of a primary or secondary hydroxy substituted amine containing 1 to 3 hydroxy groups, to form an intermediate and in a second stage reacting said intermediate with: (d) about 0.01 to 2.5 moles of a hydrocarbyl succinimide or succinamide, and (e) about 0.005 to 0.5 moles of a polyoxyalkylene amine having the structure ##STR8## wherein R is a divalent aliphatic hydrocarbon group containing 2 to 4 carbon atoms, R 1 is a polyvalent saturated hydrocarbon radical having the valence p and containing 2 to 10 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 40, such that the sum of all n's is from 3 to 40 and p is an integer from 3 to 6, wherein said hydrocarbyl succinimide or succinamide in (d) is the product made by reacting a hydrocarbyl succinic anhydride, acid, or ester with an amine containing 2 to 6 amino nitrogen atoms, at least one of which is primary, and about 1 to 30 carbon atoms, at least part of said hydrocarbyl succinimide or succinamide containing at least one reactive primary or secondary amine group.

Claim 11

An ashless dispersant as claimed in claim 9 further characterized in that it is made by a process comprising reacting in a first stage (a) about 0.9 to 1.1 moles of a polyisobutylene-substituted succinic anhydride wherein said polyisobutylene substituent has an average molecular weight of about 700 to 2000, (b) about 0.7 to 1.0 moles of pentaerythritol, and (c) about 0.7 to 0.1 moles of tris-hydroxymethylaminomethane to form an intermediate and in a second stage reacting said intermediate with (d) about 0.01 to 0.5 moles of a polyisobutenyl succinimide, and (e) about 0.005 to about 0.15 moles of a polyoxyalkylene amine having the structure ##STR9## wherein R is a divalent aliphatic hydrocarbon group containing 2 to 4 carbon atoms, R 1 is a polyvalent saturated hydrocarbon radical having the valence p, containing 2 to 10 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 40, such that the sum of all n's is from about 3 to 40 and p is an integer from 3 to 6, wherein said polyisobutenyl succinimide in (d) is the product made by reacting a polyisobutylene-substituted succinic anhydride wherein the average molecular weight of said polyisobutylene is about 700 to 2800 with a polyethylenepolyamine at least part of said polyisobutenyl succinimide containing at least one reactive primary amine group.

Claim 12

A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and a minor amount sufficient to provide dispersancy of an ashless dispersant of claim 1.

Claim 13

A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and a minor amount sufficient to provide dispersancy of an ashless dispersant of claim 10.