US4401450A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Economic recovery of ethylene and/or propylene from low concentration feeds
Assignee: Linde GmbH
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Filing: 1981-09-11
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Granted: 1983-08-30
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Expires: 2001-09-11
Abstract
Abstract C 2 -C 3 olefins are recovered from a low concentration gaseous feedstream, e.g. a Fischer-Tropsch waste gas. In a first process stage, the weight percent concentration of the olefins is enriched to at least about 25%. One specific enrichment technique includes scrubbing, preferably 2-stage scrubbing, with hydrocarbon scrubbing agents. Another technique comprises condensation of the olefin in regenerators and absorbing same in a purge phase. The resultant enriched stream, in any case, is then subjected to conventional low temperature separation to recover relatively pure individual streams of ethylene and propylene.
Inventors
- 👤 Walter Schramm
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 17:16
CPC Classifications
C; C07; C07C; C07C11/00; C07C11/02; B; B01; B01D; B01D53/00; B01D53/14; B01D53/1406; B01D53/1418; B01D53/1487; C07C7/00; C07C7/005; C07C7/11
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
113 words
A process for recovering C 2 -C 4 olefins from a gaseous feedstream obtained from a Fischer-Tropsch waste gas containing about 2-3 mol % ethylene or propylene, said process comprising in a first process stage, scrubbing said gaseous feedstream with a C 4 -C 8 liquid hydrocarbon, to absorb said olefin therein and recovering from said liquid hydrocarbon a gaseous stream, the weight percent concentration of said olefins in said gaseous stream being at least about 25%; and in a second process stage, recovering said olefins from said gaseous stream by a low-temperature separation, and wherein said Fischer-Tropsch waste gas is subjected to a carbon dioxide separating step before entering the first stage.
Claim 2
Dependent Claim
113 words
A process for recovering C 2 -C 4 olefins from a gaseous feedstream obtained from a Fischer-Tropsch waste gas containing about 2-3 mol % ethylene or propylene, said process comprising in a first process stage, scrubbing said gaseous feedstream with a C 4 -C 8 liquid hydrocarbon, to absorb said olefin therein and recovering from said liquid hydrocarbon a gaseous stream, the weight percent concentration of said olefins in said gaseous stream being at least about 25%; and in a second process stage, recovering said olefins from said gaseous stream by a low-temperature separation, and wherein said Fischer-Tropsch waste gas is subjected to a carbon dioxide separating step before entering the first stage.
Claim 3
Dependent Claim
21 words
A process according to claim 1, wherein the olefins are enriched in the first process stage to more than 35 mol-%.
Claim 4
Dependent Claim
60 words
A process according to claim 1, said gas scrubbing stage being a two-stage scrubbing process conducted with a temperature which is lower in the second scrubbing stage than in the first scrubbing stage, differing scrubbing media being employed in the two scrubbing stages, which scrubbing media are regenerated separately from each other and are recycled into the respective scrubbing stages.
Claim 5
Dependent Claim
50 words
A process according to claim 3, wherein the scrubbing media employed are, in the first scrubbing stage, C 4 - or higher hydrocarbons and, in the second scrubbing stage, C 6 - or higher hydrocarbons, the second stage scrubbing media having a higher normal boiling point than said first stage.
Claim 6
Dependent Claim
28 words
A process according to claim 4, wherein the scrubbing medium in the first scrubbing stage is butane and the scrubbing medium in the second scrubbing stage is hexane.
Claim 7
Dependent Claim
37 words
A process according to claim 4, wherein in the first scrubbing stage, C 3 - and higher hydrocarbons are substantially quantitatively scrubbed out and, in the second scrubbing stage, C 2 -hydrocarbons are substantially quantitatively scrubbed out.
Claim 8
Dependent Claim
39 words
A process according to claim 4, wherein in the first scrubbing stage, C 3 - and higher hydrocarbons are scrubbed out at -20° C. and, in the second scrubbing stage, C 2 -hydrocarbons are scrubbed out at -40° C.
Claim 9
Dependent Claim
26 words
A process according to claim 4, the hydrocarbons in both scrubbing stages being scrubbed out at approximately the same pressures ranging between 10 and 20 bar.
Claim 10
Dependent Claim
52 words
A process according to claim 4, further comprising stripping C 3 -hydrocarbons from loaded scrubbing medium of the first scrubbing stage, withdrawing remaining scrubbing medium, heating said remaining scrubbing medium to evolve C 4 - or higher hydrocarbons out and utilizing resultant evolved gas for said stripping of the C 3 -hydrocarbons.
Claim 11
Dependent Claim
73 words
A process according to claim 9, wherein said stripping of C 3 -hydrocarbons from the scrubbing medium of the first scrubbing stage is conducted in a C 3 /C 4 -separating column, a second separating column for higher hydrocarbons being placed underneath said C 3 /C 4 separating column, the vapors from this second separating column rising through the liquid in the C 3 /C 4 -separating column and functioning as reboiler vapor.
Claim 12
Dependent Claim
116 words
A process for recovering C 2 -C 4 olefins from a gaseous feedstream obtained from a Fischer-Tropsch waste gas containing 2-3% ethylene or propylene, said process comprising in a first process stage partially condensing said feedstream in at least one of several cyclically operated and interconnected regenerators to condense out olefins in said regenerator and then removing said condensed out olefins therefrom as a gaseous stream having a weight percent concentration of said olefins of at least 25%; and in a second process stage recovering said olefins from said gaseous stream by a low temperature separation, and wherein said Fischer-Tropsch waste gas is subjected to a carbon dioxide separating step prior to entering the first stage.
Claim 13
Dependent Claim
116 words
A process for recovering C 2 -C 4 olefins from a gaseous feedstream obtained from a Fischer-Tropsch waste gas containing 2-3% ethylene or propylene, said process comprising in a first process stage partially condensing said feedstream in at least one of several cyclically operated and interconnected regenerators to condense out olefins in said regenerator and then removing said condensed out olefins therefrom as a gaseous stream having a weight percent concentration of said olefins of at least 25%; and in a second process stage recovering said olefins from said gaseous stream by a low temperature separation, and wherein said Fischer-Tropsch waste gas is subjected to a carbon dioxide separating step prior to entering the first stage.
Claim 14
Dependent Claim
13 words
A process according to claim 11, wherein at least three regenerators are employed.
Claim 15
Dependent Claim
78 words
A process according to claim 11, wherein the feedstream is a gaseous stream consisting essentially of components having a lower boiling point than the olefins, and comprising substantially entirely condensing the olefins and any corresponding paraffins during a loading phase of the regenerators while the gaseous feedstream flows therethrough, and revaporizing said olefins and any corresponding paraffins by passing a purge gas through said regenerator, and conducting resultant purge gas containing the olefins to the second process stage.
Claim 16
Dependent Claim
34 words
A process according to claim 13, wherein said gaseous feedstream is cooled during a loading phase to a temperature at which the C 2 -hydrocarbons are condensed to an extent of at least 95%.
Claim 17
Dependent Claim
25 words
A process according to claim 13, wherein a partial stream of uncondensed feedstream withdrawn from the loading phase is utilized as the purge gas stream.
Claim 18
Dependent Claim
21 words
A process according to claim 15, further comprising engine expanding said purge gas stream to provide make-up refrigeration for the regenerators.
Claim 19
Dependent Claim
32 words
A process according to claim 13, further comprising engine expanding of at least one portion of the uncondensed gaseous feedstream withdrawn from the loading phase to provide make-up refrigeration for said regenerators.
Claim 20
Dependent Claim
13 words
A process according to claim 13, wherein purge gas pressure is 0.1-2.0 bar.
Claim 21
Dependent Claim
25 words
A process according to claim 13, wherein the gaseous feedstream in the first process stage is under a pressure of between 5 and 15 bar.
Claim 22
Dependent Claim
21 words
A process according to claim 11, wherein the olefins are enriched in the first process stage to more than 35 mol-%.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-08-29 | 1987-02-28 | 1987-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-08-29 | 1991-02-28 | 1991-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-08-29 | 1995-02-28 | 1995-08-30 | $7700.00 | Window Closed / Lapsed |