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US4400496A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-soluble graft copolymers of starch-acrylamide and uses therefor

Assignee: University of Florida
•
Filing: 1980-09-22
•
Granted: 1983-08-23
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Expires: 2000-09-22
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Abstract

Abstract Graft copolymers having starch as the central chain with grafted side chains of acrylamide or acrylamide-acrylic acid, and a process for preparation of such copolymers in the presence of Ce+4 or other redox initiators. These copolymers are employed in preparing highly viscous aqueous solutions that are particularly useful in oil recovery from subterranean wells.

Inventors

  • 👤 George B. Butler
  • 👤 Thieo E. Hogen-Esch
  • 👤 John J. Meister
  • 👤 Huey Pledger, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 21:59
CPC Classifications
C; C08; C08F; C08F251/00

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 31 words
Water-soluble graft copolymer comprising a backbone molecule of water-soluble starch with branch chains grafted thereto of polymerized acrylamide units or a mixture of polymerized acrylamide units and polymerized acrylic acid units.
Claim 2
Dependent Claim 31 words
Water-soluble graft copolymer comprising a backbone molecule of water-soluble starch with branch chains grafted thereto of polymerized acrylamide units or a mixture of polymerized acrylamide units and polymerized acrylic acid units.
Claim 3
Dependent Claim 15 words
The graft copolymer of claim 1 wherein all of said branch chains are polymerized acrylamide.
Claim 4
Dependent Claim 37 words
The graft copolymer of claim 1 which has the property of increasing the viscosity of water from 2 to 1000 times that of pure water when dissolved in water at concentrations of 0.001 to 2.0 weight percent.
Claim 5
Dependent Claim 14 words
The graft copolymer of claim 1 having a molecular weight of 300,000 to 20,000,000.
Claim 6
Dependent Claim 26 words
The graft copolymer of claim 3 in which the molecular weight is 1,000,000 to 5,000,000 and each starch molecule has 1-18 of said grafted branch chains.

References Cited (Backward Citations)

US3095391A Cited
US3332897A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-22 1987-02-21 1987-08-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-22 1991-02-21 1991-08-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-22 1995-02-21 1995-08-23 $7700.00 Window Closed / Lapsed

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