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US4400355A Expired / Lapsed US ⏱️ 0.0 years remaining

Apparatus for desulfurizing combustion gases

Assignee: Individual
•
Filing: 1981-12-07
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Granted: 1983-08-23
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Expires: 2001-12-07
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Abstract

Abstract An apparatus for removing sulfur oxides and nitrogen oxides from the gaseous combustion products of sulfur-containing fossil fuel, such as high sulfur coal, comprising passing the combustion products into a reaction chamber, introducing atomic oxygen and air into the chamber, subjecting the resulting gaseous mixture to a plurality of confined, upwardly spiralling vortical movements in series, maintaining a reservoir of sulfuric acid in the reaction chamber, each vortical movement being of sufficient velocity as to atomize and elevate the sulfuric acid in the reservoir and to intermix it with the combustion products, impinging the vortical mixture against rapidly rotating surfaces whereby to discharge the mixture outwardly against the chamber walls to fall by gravity into the reservoir, and repeating the plurality of vortical movements in series in at least one additional reaction chamber, thereby producing sulfuric acid and/or nitrosyl sulfuric acid as a saleable by-product and reducing the sulfur oxides content of the discharged gases to a level of about 100 ppm.

Inventors

  • 👤 Francis M. Donnelly, deceased
  • 👤 personal representative by Marion Y. Donnelly

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:22
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60; B01D53/48; B01D53/50; B01D53/501; B01D53/504; Y; Y02; Y02A; Y02A50/00; Y02A50/20

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 341 words
Apparatus for removing sulfur oxides from the gaseous combustion products of sulfur-containing fossil fuel, including at least one of a heat exchanger and electrostatic precipitator through which said gaseous combustion products at elevated temperature are initially passed, at least one reaction chamber in which sulfur dioxide is converted to sulfur trioxide in the presence of atomic oxygen and absorbed in sulfuric acid, and a discharge to ambient atmosphere, at least two modules in series in each said reaction chamber, each said module comprising a confining housing having top, bottom and side walls, a substantially vertical duct having orifices at the top and bottom thereof and centrally located in said housing, the top orifice being substantially horizontal, the bottom orifice having a non-horizontal configuration such that a portion of said orifice is partially submerged in a reservoir of sulfuric acid in said housing, a plurality of fan blades positioned within said housing closely above said top orifice substantially in axial alignment with said duct, at least a section of each of said fan blades functioning in the manner of backwardly inclined centrifugal blower blades when rotated rapidly, baffle means dividing said housing into inlet and outlet sections, respectively, said baffle means permitting communication between said inlet and outlet sections only through said vertical duct, an inlet to said inlet section through which gaseous combustion products are introduced, a portion of said baffle means sloping downwardly and directing incoming gaseous combustion products toward said non-horizontal bottom orifice in said inlet section where said gaseous combustion products are entrained and raised in an upwardly spiraling vortex through said duct, admixed intimately with a finely divided sulfuric acid mist, impacted against said rapidly rotating fan blades and discharged outwardly and downwardly in said outlet section within said housing to drain liquified components into said reservoir, and an outlet from said housing communicating with an inlet of a succeeding like module in said series, said sloping portion of said baffle means guiding said gaseous products from said outlet section to said inlet of said succeeding module.
Claim 2
Dependent Claim 341 words
Apparatus for removing sulfur oxides from the gaseous combustion products of sulfur-containing fossil fuel, including at least one of a heat exchanger and electrostatic precipitator through which said gaseous combustion products at elevated temperature are initially passed, at least one reaction chamber in which sulfur dioxide is converted to sulfur trioxide in the presence of atomic oxygen and absorbed in sulfuric acid, and a discharge to ambient atmosphere, at least two modules in series in each said reaction chamber, each said module comprising a confining housing having top, bottom and side walls, a substantially vertical duct having orifices at the top and bottom thereof and centrally located in said housing, the top orifice being substantially horizontal, the bottom orifice having a non-horizontal configuration such that a portion of said orifice is partially submerged in a reservoir of sulfuric acid in said housing, a plurality of fan blades positioned within said housing closely above said top orifice substantially in axial alignment with said duct, at least a section of each of said fan blades functioning in the manner of backwardly inclined centrifugal blower blades when rotated rapidly, baffle means dividing said housing into inlet and outlet sections, respectively, said baffle means permitting communication between said inlet and outlet sections only through said vertical duct, an inlet to said inlet section through which gaseous combustion products are introduced, a portion of said baffle means sloping downwardly and directing incoming gaseous combustion products toward said non-horizontal bottom orifice in said inlet section where said gaseous combustion products are entrained and raised in an upwardly spiraling vortex through said duct, admixed intimately with a finely divided sulfuric acid mist, impacted against said rapidly rotating fan blades and discharged outwardly and downwardly in said outlet section within said housing to drain liquified components into said reservoir, and an outlet from said housing communicating with an inlet of a succeeding like module in said series, said sloping portion of said baffle means guiding said gaseous products from said outlet section to said inlet of said succeeding module.
Claim 3
Dependent Claim 29 words
The apparatus claimed in claim 1, wherein said downwardly sloping portion of said baffle means terminates at its lower end beneath the surface of said reservoir of sulfuric acid.
Claim 4
Dependent Claim 242 words
In apparatus for removing sulfur oxides from the gaseous combustion products of sulfur-containing fossil fuel and for producing sulfuric acid in a reaction chamber, the improvement which comprises at least two modules in series in said reaction chamber, each said module comprising a confining housing having top, bottom and side walls, a substantially vertical elongated duct centrally positioned in said housing, said duct having orifices at the top and bottom thereof, the top orifice being substantially horizontal, the bottom orifice having a non-horizontal configuration such that a portion thereof is adapted to be partially submerged in a reservoir of sulfuric acid in said housing, a plurality of fan blades positioned within said housing closely above said top orifice substantially in axial alignment with said duct, means for rotating said fan blades whereby to raise said gaseous combustion products in an upwardly spiraling vortex through said duct, baffle means dividing said housing into inlet and outlet sections, respectively, said bottom orifice communicating only with said inlet section, said top orifice communicating with said outlet section, said baffle means permitting communication between said inlet and outlet sections only through said duct, an inlet to said housing in said inlet section, and an outlet from said housing in said outlet section communicating with an inlet of a succeeding like module in said series, said baffle means having a sloping section guiding said gaseous products from said outlet section to said inlet of said succeeding module.
Claim 5
Dependent Claim 242 words
In apparatus for removing sulfur oxides from the gaseous combustion products of sulfur-containing fossil fuel and for producing sulfuric acid in a reaction chamber, the improvement which comprises at least two modules in series in said reaction chamber, each said module comprising a confining housing having top, bottom and side walls, a substantially vertical elongated duct centrally positioned in said housing, said duct having orifices at the top and bottom thereof, the top orifice being substantially horizontal, the bottom orifice having a non-horizontal configuration such that a portion thereof is adapted to be partially submerged in a reservoir of sulfuric acid in said housing, a plurality of fan blades positioned within said housing closely above said top orifice substantially in axial alignment with said duct, means for rotating said fan blades whereby to raise said gaseous combustion products in an upwardly spiraling vortex through said duct, baffle means dividing said housing into inlet and outlet sections, respectively, said bottom orifice communicating only with said inlet section, said top orifice communicating with said outlet section, said baffle means permitting communication between said inlet and outlet sections only through said duct, an inlet to said housing in said inlet section, and an outlet from said housing in said outlet section communicating with an inlet of a succeeding like module in said series, said baffle means having a sloping section guiding said gaseous products from said outlet section to said inlet of said succeeding module.
Claim 6
Dependent Claim 30 words
The improvement claimed in claim 1, wherein said sloping section slopes downwardly and is adapted to terminate at its lower end beneath the surface of said reservoir of sulfuric acid.
Claim 7
Dependent Claim 33 words
The improvement claimed in claim 1, wherein said means for rotating said fan blades is mounted outside said housing on the upper surface thereof, said upper surface being removably secured in sealing engagement.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-22 1987-02-21 1987-08-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-22 1991-02-21 1991-08-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-22 1995-02-21 1995-08-23 $7700.00 Window Closed / Lapsed

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