Dry nonelectroscopic toners for toning tacky image surfaces

Claim 2

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of an antistatic agent in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 3

A toner according to claim 1 wherein the slip agent is polydimethylsiloxane or polymethyl(X)siloxane where X is an alkyl chain with 2 to 12 carbon atoms.

Claim 4

A toner according to claim 1 wherein the antistatic agent is an anionic antistatic agent.

Claim 5

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of an anionic antistatic agent which is a member taken from the group consisting of: (a) sodium alkyl benzene sulfonate wherein alkyl is an alkyl chain with 8 to 18 carbon atoms; (b) sodium alkyl sulfonate wherein alkyl is an alkyl chain with 10 to 20 carbon atoms; (c) secondary alkyl sulfate wherein one or both alkyl groups are substituted with functional groups taken from the group consisting of ester, ether, and alcohol, the alkyl being an alkyl chain of 1 to 18 carbon atoms; (d) phosphorous-containing compound of the formula (RO) m P(O(OX) n wherein R is an alkyl chain with 4 to 18 carbon atoms, X is an cation taken from the group consisting of H, K, Na, NH 4 , m is 1 or 2 and n is 2 or 1; and (e) amine salt of alkyl sulfate wherein alkyl is an alkyl chain of 8 to 18 carbon atoms and amine is taken from the group consisting of ammonia, diethyanolamine, triethanolamine and diethylcyclohexyl amine in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 6

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of an anionic antistatic agent which is a member taken from the group consisting of: (a) sodium alkyl benzene sulfonate wherein alkyl is an alkyl chain with 8 to 18 carbon atoms; (b) sodium alkyl sulfonate wherein alkyl is an alkyl chain with 10 to 20 carbon atoms; (c) secondary alkyl sulfate wherein one or both alkyl groups are substituted with functional groups taken from the group consisting of ester, ether, and alcohol, the alkyl being an alkyl chain of 1 to 18 carbon atoms; (d) phosphorous-containing compound of the formula (RO) m P(O(OX) n wherein R is an alkyl chain with 4 to 18 carbon atoms, X is an cation taken from the group consisting of H, K, Na, NH 4 , m is 1 or 2 and n is 2 or 1; and (e) amine salt of alkyl sulfate wherein alkyl is an alkyl chain of 8 to 18 carbon atoms and amine is taken from the group consisting of ammonia, diethyanolamine, triethanolamine and diethylcyclohexyl amine in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 7

A toner according to claim 1 wherein the antistatic agent is a cationic antistatic agent.

Claim 8

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of a cationic antistatic agent which is a member taken from the group consisting of (a) alkyl trimethyl ammonium bromide wherein alkyl is an alkyl chain with 1 to 18 carbon atoms; and (b) Quaternary ammonium compounds of the formula: ##STR6## wherein R and R 1 may be a saturated or unsaturated alkyl chain with 1 to 24 carbon atoms or mixtures thereof, R 2 may be an alkyl chain of 1 to 24 carbon atoms or R 3 wherein R 3 is a polyether substituent of the formula --(CH 2 CH 2 O) m --[CH 2 CH(CH 3 )O] n --H wherein m and n may be 0 to 20, the total of m and n being at least 1, and X is an anion taken from the group consisting of CH 3 SO 4 , C 2 H 5 SO 4 , (CH 3 ) 2 PO 4 , (C 2 H 5 ) 2 PO 4 ; the total number of carbon atoms in R,R 1 and R 2 should not exceed 38 in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 9

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of a cationic antistatic agent which is a member taken from the group consisting of (a) alkyl trimethyl ammonium bromide wherein alkyl is an alkyl chain with 1 to 18 carbon atoms; and (b) Quaternary ammonium compounds of the formula: ##STR6## wherein R and R 1 may be a saturated or unsaturated alkyl chain with 1 to 24 carbon atoms or mixtures thereof, R 2 may be an alkyl chain of 1 to 24 carbon atoms or R 3 wherein R 3 is a polyether substituent of the formula --(CH 2 CH 2 O) m --[CH 2 CH(CH 3 )O] n --H wherein m and n may be 0 to 20, the total of m and n being at least 1, and X is an anion taken from the group consisting of CH 3 SO 4 , C 2 H 5 SO 4 , (CH 3 ) 2 PO 4 , (C 2 H 5 ) 2 PO 4 ; the total number of carbon atoms in R,R 1 and R 2 should not exceed 38 in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 10

A toner according to claim 1 wherein the antistatic agent is an amphoteric antistatic agent.

Claim 11

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of an amphoteric antistatic agent which is taken from the class consisting of alkyl bis(polyethanoxy)-gamma-sulfopropyl betaine and alkyl bis(hydroxyethyl)-gamma-sulfopropyl betaine wherein alkyl is an alkyl chain with 12 to 24 carbon atoms and in the former the number of polyether units is 1 to 4 in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 12

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of an amphoteric antistatic agent which is taken from the class consisting of alkyl bis(polyethanoxy)-gamma-sulfopropyl betaine and alkyl bis(hydroxyethyl)-gamma-sulfopropyl betaine wherein alkyl is an alkyl chain with 12 to 24 carbon atoms and in the former the number of polyether units is 1 to 4 in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 13

A toner according to claim 1 wherein the antistatic agent is a nonionic antistatic agent.

Claim 14

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of a nonionic antistatic agent which is a member taken from the group consisting of a compound of the formula: (a) R(OCH 2 CH 2 ) n --OH wherein R is a saturated or unsaturated alkyl chain with 12 to 18 carbon atoms or CH 3 (CH 2 ) 7 --CH═CH(CH 2 ) 8 --, and n is 2 to 10; (b) R(OCH 2 CH 2 ) m [OCH 2 CH(CH 3 )] n --OH wherein R is an alkyl chain with 12 to 18 carbon atoms, m is 0 to 10 and n is 1 to 10; and (c) mono and diglycerides of carboxylic acids having an alkyl chain of 12 to 18 carbon atoms in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 15

A dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of a nonionic antistatic agent which is a member taken from the group consisting of a compound of the formula: (a) R(OCH 2 CH 2 ) n --OH wherein R is a saturated or unsaturated alkyl chain with 12 to 18 carbon atoms or CH 3 (CH 2 ) 7 --CH═CH(CH 2 ) 8 --, and n is 2 to 10; (b) R(OCH 2 CH 2 ) m [OCH 2 CH(CH 3 )] n --OH wherein R is an alkyl chain with 12 to 18 carbon atoms, m is 0 to 10 and n is 1 to 10; and (c) mono and diglycerides of carboxylic acids having an alkyl chain of 12 to 18 carbon atoms in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000.

Claim 16

A toner according to claim 1 wherein the pigmented resin particles are comprised of cellulose acetate particles having pigment particles embedded in their surfaces.

Claim 17

A process of preparing dry, nonelectroscopic surface coated toners from pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size which comprises adding in either order or simultaneously to the pigmented resin particles an antistatic agent and a slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of about 500 to 500,000.

Claim 18

A process of preparing dry, nonelectroscopic surface coated toners from pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size which comprises adding in either order or simultaneously to the pigmented resin particles an antistatic agent and a slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of about 500 to 500,000.

Claim 19

A process according to claim 12 wherein the antistatic agent is of the formula: R(OCH 2 CH 2 )--OH wherein R is an alkyl chain with 12 to 18 carbon atoms or CH 3 (CH 2 ) 7 --CH═CH(CH 2 ) 8 --, and n is 2 to 10.

Claim 20

A process according to claim 12 wherein the slip agent is polydimethylsiloxane or polymethyl(X)siloxane where X is an alkyl chain with 2 to 12 carbon atoms.

Claim 21

A process according to claim 12 wherein the pigmented resin particle are comprised of cellulose acetate particles having pigment particles embedded in their surfaces.