Condensation polymeric photoconductors containing pendant arylamines

Claim 2

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a condensation polymer containing, as repeating units, the condensation residues of: (a) a diacid, and (b) an organic difunctional compound capable of undergoing condensation polymerization with said diacid, wherein at least one of said residues contains an appended arylamine photoconductor group.

Claim 3

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a condensation polymer containing, as repeating units, the condensation residues of: (a) a first diacid,

Claim 4

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a condensation polymer containing, as repeating units, the condensation residues of: (a) a first diacid,

Claim 5

(b) a second diacid containing an anionic iminodisulfonyl or sulfo group, and (c) at least one organic difunctional compound capable of undergoing condensation polymerization with said first and second diacids, wherein at least one of said first diacid and organic difunctional compound residues contains said appended arylamine photoconductor group.

Claim 6

(b) a second diacid containing an anionic iminodisulfonyl or sulfo group, and (c) at least one organic difunctional compound capable of undergoing condensation polymerization with said first and second diacids, wherein at least one of said first diacid and organic difunctional compound residues contains said appended arylamine photoconductor group.

Claim 7

The element of claim 2 wherein said support is an electrically conducting paper support.

Claim 8

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a spectral sensitizer and a polymeric photoconductor having the structure ##STR33## wherein π and π 1 , which are the same or different, are organic groups containing an arylamine which confers photoconductivity upon the polymer; R 1 -π 1 together with G and G 1 represents an arylamine-containing organic condensation residue of a difunctional compound capable of undergoing condensation with organic diacids; R together with G 2 and G 3 represents at least one organic condensation residue of a difunctional compound capable of undergoing condensation with organic diacids; G and G 1 , which are the same or different, and G 2 and G 3 , which are the same or different, represent -O- or -NH-; A 1 , A 2 and A 3 , which are the same or different, represent the condensation residues of acid groups; R 2 ⊖ is an organic group which contains an anionic iminodisulfonyl or sulfo group; M + is a cation; -A 3 -R 3 -A 3 represents an organic diacid condensation residue; x is 0 to 100 mole percent of the total diacid content; y is 0 to about 35 mole percent of the total diacid content; z is 0 to 100 mole percent of the total diacid content; the sum of x, y and z is 100; v is 0 to 100 mole percent of the total difunctional compound content; and v+x is at least 20.

Claim 9

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a spectral sensitizer and a polymeric photoconductor having the structure ##STR33## wherein π and π 1 , which are the same or different, are organic groups containing an arylamine which confers photoconductivity upon the polymer; R 1 -π 1 together with G and G 1 represents an arylamine-containing organic condensation residue of a difunctional compound capable of undergoing condensation with organic diacids; R together with G 2 and G 3 represents at least one organic condensation residue of a difunctional compound capable of undergoing condensation with organic diacids; G and G 1 , which are the same or different, and G 2 and G 3 , which are the same or different, represent -O- or -NH-; A 1 , A 2 and A 3 , which are the same or different, represent the condensation residues of acid groups; R 2 ⊖ is an organic group which contains an anionic iminodisulfonyl or sulfo group; M + is a cation; -A 3 -R 3 -A 3 represents an organic diacid condensation residue; x is 0 to 100 mole percent of the total diacid content; y is 0 to about 35 mole percent of the total diacid content; z is 0 to 100 mole percent of the total diacid content; the sum of x, y and z is 100; v is 0 to 100 mole percent of the total difunctional compound content; and v+x is at least 20.

Claim 10

The element of claim 4 wherein π and πHU 1 have the structure ##STR34## wherein u is an integer from 1 to 6; R 5 and R 6 are the same or different and represent alkyl, cycloalkyl, aryl or aralkyl; R 4 is alkylene, cycloalkylene, arylene or arylenealkylene; at least one of R 4 , R 5 and R 6 comprises an aromatic group appended to the nitrogen atom; R 3 is an alkylene, arylene, arylenealkylene, cycloalkylene, heterocyclic or an ethylenically unsaturated group; and A 1 , A 2 and A 3 are ##STR35## and said spectral sensitizer is a pyrylium dye salt.

Claim 11

The element of claim 5 wherein R 4 is phenylene, R 5 and R 6 are each phenyl or tolyl, u is 1, v is 0 and R 2 is selected from the group consisting of ##STR36##

Claim 12

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a polyester containing, as repeating units, the condensation residues of: (a) a dicarboxylic acid, and (b) an organic diol capable of undergoing condensation polymerization with said dicarboxylic acid, wherein at least one of said residues contains an appended arylamine photoconductive group.

Claim 13

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a polyester containing, as repeating units, the condensation residues of: (a) a dicarboxylic acid, and (b) an organic diol capable of undergoing condensation polymerization with said dicarboxylic acid, wherein at least one of said residues contains an appended arylamine photoconductive group.

Claim 14

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising an ionic polyester containing, as repeating units, the condensation residues of: (a) a first dicarboxylic acid, (b) a second dicarboxylic acid containing an anionic iminodisulfonyl or sulfo group, and (c) at least one organic diol capable of undergoing condensation polymerization with said first and second dicarboxylic acids, wherein at least one of said first dicarboxylic acid and organic diol residues contains an appended arylamine photoconductor group.

Claim 15

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising an ionic polyester containing, as repeating units, the condensation residues of: (a) a first dicarboxylic acid, (b) a second dicarboxylic acid containing an anionic iminodisulfonyl or sulfo group, and (c) at least one organic diol capable of undergoing condensation polymerization with said first and second dicarboxylic acids, wherein at least one of said first dicarboxylic acid and organic diol residues contains an appended arylamine photoconductor group.

Claim 16

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a spectral sensitizer and a polymeric photoconductor having the structure ##STR37## wherein π and π 1 , which are the same or different, are organic groups containing an arylamine which confers photoconductivity upon the polymer; ##STR38## is the condensation residue of an arylamine-containing organic diol having from about to 2 about 40 carbon atoms; -O-R-O- is the condensation residue of at least one organic diol having from about 2 to about 40 carbon atoms; R 2 ⊖ is an organic group which contains an anionic iminodisulfonyl or sulfo group; M + is a cation; ##STR39## represents an organic dicarboxylic acid condensation residue; x is 0 to 100 mole percent of the total dicarboxylic acid content; y is 0 to about 35 mole percent of the total dicarboxylic acid content; z is 0 to 100 mole percent of the total dicarboxylic acid content; the sum of x, y and z is 100; v is 0 to 100 mole percent of the total diol content; and v+x is at least 20.

Claim 17

An electrophotographic element comprising an electrically conducting support and a photoconductive layer in electrical contact with said support, said photoconductive layer comprising a spectral sensitizer and a polymeric photoconductor having the structure ##STR37## wherein π and π 1 , which are the same or different, are organic groups containing an arylamine which confers photoconductivity upon the polymer; ##STR38## is the condensation residue of an arylamine-containing organic diol having from about to 2 about 40 carbon atoms; -O-R-O- is the condensation residue of at least one organic diol having from about 2 to about 40 carbon atoms; R 2 ⊖ is an organic group which contains an anionic iminodisulfonyl or sulfo group; M + is a cation; ##STR39## represents an organic dicarboxylic acid condensation residue; x is 0 to 100 mole percent of the total dicarboxylic acid content; y is 0 to about 35 mole percent of the total dicarboxylic acid content; z is 0 to 100 mole percent of the total dicarboxylic acid content; the sum of x, y and z is 100; v is 0 to 100 mole percent of the total diol content; and v+x is at least 20.

Claim 18

The element of claim 9 wherein π and π 1 have the structure ##STR40## wherein u is an integer from 1 to 6; R 5 and R 6 are the same or different and represent alkyl, cycloalkyl, aryl or aralkyl; R 4 is alkylene, cycloalkylene, arylene or arylenealkylene; at least one of R 4 , R 5 and R 6 comprises an aromatic group appended to the nitrogen atom; R 3 is an alkylene, arylene, arylenealkylene, cycloalkylene, heterocyclic or an ethylenically unsaturated group and said spectral sensitizer is a pyrylium dye salt.

Claim 19

The element of claim 10 wherein said support is an electrically conducting paper support, and, in said polymer, R 4 is phenylene, R 5 and R 6 are each phenyl or tolyl, u is 1, v is 0, x is from about 40 to about 60 mole percent, y is from 10 to about 30 mole percent, and R 2 is selected from the group consisting of ##STR41##

Claim 20

The element of claim 10 wherein the repeating unit ##STR42## is the condensation residue of a dicarboxylic acid selected from the group consisting of 3,3'-[(sodioimino)disulfonyl]dibenzoic acid; 3,3'-[(potassioimino)disulfonyl]dibenzoic acid; 3,3'-[(lithioimino)disulfonyl]dibenzoic acid; 4,4'-[(lithioimino)disulfonyl]dibenzoic acid; 4,4'-[(sodioimino)disulfonyl]dibenzoic acid; 4,4'-[(potassioimino)disulfonyl]dibenzoic acid; 3,4'-[(lithioimino)disulfonyl]dibenzoic acid; 3,4'-[(sodioimino)disulfonyl]dibenzoic acid; 4,4'[(potassiomino)disulfonyl]dinaphthoic acid; 5-[N-potassio-N-(4-tolylsulfonyl)sulfamoyl]isophthalic acid 5-sodiosulfoisophthalic acid, 5-(4-sodiosulfophenoxy)isophthalic acid, 5-(3-sodiosulfopropoxy)isophthalic acid, and 5-(4-sodiosulfocyclohexyloxy)-1,3-cyclohexanedicarboxylic acid.

Claim 21

A copy process for forming visible images on an electrophotographic element as in claim 1, 3, 4, 6, 7, 8, 9 or 11, said process comprising the steps of electrically charging the surface of said photoconductive layer of said element, exposing said charged surface to actinic radiation to form an electrostatic latent image, and developing said latent image to form a visible image.