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US4394485A Expired / Lapsed US ⏱️ 0.0 years remaining

Four component adhesive blends and composite structures

Assignee: Enron Chemical Co
•
Filing: 1982-03-31
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Granted: 1983-07-19
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Expires: 2002-03-31
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Abstract

Abstract Compositions of matter having properties that make them strong adhesives to various substrates and especially for adhering polypropylene and polyethylene to various polar substrates. These compositions comprise blends of a graft copolymer of a polyethylene backbone grafted with at least one grafting monomer comprising one or more of polymerizable ethylenically unsaturated carboxylic acids of the anhydrides of such acids blended with a blending resin that is a mixture of one or more high density polyethylenes, one or more linear low density polyethylenes and one or more polypropylenes. The disclosure also includes composite structures comprising one or more substrates and a blend of the above as the adhesive in contact with the substrate or substrates and the method of preparing these composite structures. This invention relates to adhesive blends comprising modified polyolefin resins with improved adhesion to substrates and especially polar substrates such as metals, glass, paper, wood and polar polymers such as polyamides, polyureas, polycarbonates, polyurethanes, copolymers of olefins with vinyl esters and with vinyl alcohols, cellulose and its derivatives, etc. These adhesive blend resins can be used in any conventional process for combining dissimilar materials. Examples of these methods are lamination, coextrusion, powder and/or extrusion coating, blow molding, etc., or any combination of these processes. The adhesive blends of this invention also have excellent moisture-barrier properties.

Inventors

  • 👤 Ashok M. Adur

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 18:44
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/32; B32B27/04; B32B15/00; B32B15/04; B32B15/043; B32B27/322; C; C09; C09J; C09J123/00; C09J123/02; B32B2323/00; B32B2323/04; B32B2323/043; B32B2323/046; B32B2323/10; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/24

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 53 words
A modified polyolefin blend consisting essentially of: (A) HDPE having a density of about 0.94-0.97 g/cc; (B) at least one polypropylene polymer or copolymer; (C) LDPE having a density of about 0.91-0.94 g/cc; and (D) a polyethylene polymer grafted with at least one grafting monomer polymerizable ethylenically unsaturated carboxylic acid or acid derivative.
Claim 2
Dependent Claim 53 words
A modified polyolefin blend consisting essentially of: (A) HDPE having a density of about 0.94-0.97 g/cc; (B) at least one polypropylene polymer or copolymer; (C) LDPE having a density of about 0.91-0.94 g/cc; and (D) a polyethylene polymer grafted with at least one grafting monomer polymerizable ethylenically unsaturated carboxylic acid or acid derivative.
Claim 3
Dependent Claim 25 words
The blend of claim 1 wherein said propylene polymer or copolymer comprises propylene homopolymers and copolymers of propylene and one or more unsaturated aliphatic hydrocarbons.
Claim 4
Dependent Claim 16 words
The blend of claim 1 wherein said polypropylene polymer comprises a copolymer of propylene and ethylene.
Claim 5
Dependent Claim 66 words
The blend of claim 1 wherein said grafting monomer comprises at least one of acrylic acid, methacrylic acid, fumaric acid, maleic acid, itaconic acid, citraconic acid, mesaconic acid, maleic anhydride, 4-methyl cyclohex-4-ene-1,2-dicarboxylic acid anhydride, bicyclo(2.2.2)oct-5-ene-2,3-dicarboxylic acid anhydride, 1,2,3,4,5,8,9,10-octahydronaphthalene-2,3-dicarboxylic acid anhydride, 2-oxa-1,3-diketospiro(4.4)non-7-ene, bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid anhydride, maleopimaric acid, tetrahydrophthalic anhydride, norborn-5-ene-2,3-dicarboxylic acid anhydride, Nadic anhydride, methyl Nadic anhydride, Himic anhydride, methyl Himic anhydride, and x-methyl bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid anhydride.
Claim 6
Dependent Claim 53 words
The blend of claim 1 wherein said unsaturated or saturated carboxylic acids or acid derivatives of (D) comprise the acids, metal salts of said acids, acid esters, acid anhydrides, acid amines, acid halides and acid derivatives of aliphatic, alicyclic, aromatic fused ring, heterocyclic moieties and copolymers containing one or more of these groups.
Claim 7
Dependent Claim 42 words
The blend of claim 1 wherein the polyethylene of (D) comprises ethylene homopolymers and copolymers of ethylene with one or more of butene, hexene, octene, 4-methyl pentene-1 or other unsaturated aliphatic or aromatic hydrocarbons in the density range 0.91 to 0.97 g/cc.
Claim 8
Dependent Claim 13 words
The blend of claim 6 wherein the polyolefin of (D) comprises linear polyethylenes.
Claim 9
Dependent Claim 25 words
The blend of claim 1 wherein said HDPE of (A) comprises an ethylene homopolymer and copolymers of ethylene with olefin monomers containing 3-15 carbon atoms.
Claim 10
Dependent Claim 24 words
The blend of claim 8 wherein said HDPE has a density of about 0.94-0.97 g/cc and a melt index of about 0.01-50 g/10 min.
Claim 11
Dependent Claim 25 words
The blend of claim 1 wherein the propylene polymer of (B) comprises propylene homopolymers, copolymers or terpolymers containing less than 40% of a polymerizable comonomer.
Claim 12
Dependent Claim 39 words
The blend of claim 1 wherein said LDPE of (C) comprises high pressure low density polyethylene or low pressure linear low density polyethylene, each having a density of about 0.91-0.94 g/cc and a melt index of 1.0-50 g/10 min.

References Cited (Backward Citations)

US3697465A Cited
US3868433A Cited
US3886227A Cited
US3856889A Cited
GB2081723A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-18 1987-01-17 1987-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-18 1991-01-17 1991-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-18 1995-01-17 1995-07-19 $7700.00 Window Closed / Lapsed

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