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US4394442A Expired / Lapsed US ⏱️ 0.0 years remaining

Post-stretch water-dispersible subbing composition for polyester film base

Assignee: Agfa Gevaert NV
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Filing: 1982-03-15
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Granted: 1983-07-19
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Expires: 2002-03-15
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Abstract

Abstract To improve adhesion of a hydrophilic photographic emulsion to a hydrophobic polyester film base the latter is energy-treated as by electrical discharge or flame treatment, and then given a sub-coating composed of an aqueous dispersion of a copolyester modified with a sulfonated aromatic compound.

Inventors

  • 👤 Conrad E. Miller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 13:56
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/91; G03C1/93; G03C1/915; B; B29; B29C; B29C59/00; B29C59/08; B29C59/10; B29K; B29K2067/00; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786; Y10T428/31794

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 203 words
An article of manufacture comprising an energy-treated biaxially oriented polyester film base coated with (1) a subbing layer applied from an aqueous dispersion of a linear copolyester having a relative viscosity of from about 1.3 to about 1.7 measured as a 0.58% solution in m-cresol at 25° C. which comprises the reaction product of substantially equimolar equivalents of at least two dicarboxylic acids and at least one dihydric alcohol, said dicarboxylic acid equivalents being supplied by a plurality of acid reactants which, based on a total of 100% (molar) acid equivalents, includes from about 0.1% (molar) to about 10% (molar) equivalents of an aromatic sulfonated compound having a structural formula, ##STR3## wherein: M is a monovalent cation selected from the group of an alkali metal, ammonium substituted ammonium, and quaternary ammonium; X and Y are monovalent radicals individually selected from the group having structural formulas consisting of ##STR4## wherein A is a lower alkyl group having 1-5 carbon atoms; m and n are positive integers of less than 20 with n being greater than 1; and Z is a trivalent aromatic radical; and wherein said copolyester is not branched, cross-linked, or used with a crosslinking agent; and (2) a gelatin-containing layer contiguous thereto.
Claim 2
Dependent Claim 203 words
An article of manufacture comprising an energy-treated biaxially oriented polyester film base coated with (1) a subbing layer applied from an aqueous dispersion of a linear copolyester having a relative viscosity of from about 1.3 to about 1.7 measured as a 0.58% solution in m-cresol at 25° C. which comprises the reaction product of substantially equimolar equivalents of at least two dicarboxylic acids and at least one dihydric alcohol, said dicarboxylic acid equivalents being supplied by a plurality of acid reactants which, based on a total of 100% (molar) acid equivalents, includes from about 0.1% (molar) to about 10% (molar) equivalents of an aromatic sulfonated compound having a structural formula, ##STR3## wherein: M is a monovalent cation selected from the group of an alkali metal, ammonium substituted ammonium, and quaternary ammonium; X and Y are monovalent radicals individually selected from the group having structural formulas consisting of ##STR4## wherein A is a lower alkyl group having 1-5 carbon atoms; m and n are positive integers of less than 20 with n being greater than 1; and Z is a trivalent aromatic radical; and wherein said copolyester is not branched, cross-linked, or used with a crosslinking agent; and (2) a gelatin-containing layer contiguous thereto.
Claim 3
Dependent Claim 18 words
The article of manufacture of claim 1 wherein the energy-treated biaxially oriented polyester film base is polyethylene terephthalate.
Claim 4
Dependent Claim 24 words
A photographic element comprising the article of manufacture of claim 1 having a photosensitive silver halide emulsion layer on said contiguous gelatin-containing layer (2).
Claim 5
Dependent Claim 63 words
The photographic element of claim 3 wherein the water-dispersible copolyester is prepared from (1) ethylene glycol and diethylene glycol, employed in molar ratios of from 5:95% diethylene glycol:ethylene glycol, to 95:5%; (2) dicarboxylic acid equivalents supplied by the following acids: about 25-35% (molar) terephthalic acid; about 45-55% (molar) azelaic acid; and about 15-20% (molar) isophthalic acid; and (3) about 0.5-10% (molar) sodium 5-sulfoisophthalate.
Claim 6
Dependent Claim 79 words
A method of preparing a photographic film having a polyester film base comprising: a. extruding the film base, stretching it in two directions and heat-setting, b. energy-treating the film base, c. applying to at least one side of the film base an aqueous dispersion of a linear copolyester modified with a sulfonated aromatic compound, as further defined in claim 1, and d. coating the resulting substrate successively with (1) a gelatin-containing subbing layer, and (2) a gelatino-silver halide emulsion.
Claim 7
Dependent Claim 20 words
The method of claim 5 wherein coatings (c) and (d) are applied to both sides of the energy-treated film base.

References Cited (Backward Citations)

US3563942A Cited
US3919773A Cited
US4304851A Cited
US4181528A Cited
US4307174A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-18 1987-01-17 1987-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-18 1991-01-17 1991-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-18 1995-01-17 1995-07-19 $7700.00 Window Closed / Lapsed

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