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US4390660A Expired / Lapsed US ⏱️ 0.0 years remaining

Ultraviolet light absorbing compositions

Assignee: General Electric Co
•
Filing: 1981-12-09
•
Granted: 1983-06-28
•
Expires: 2001-12-09
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Abstract

Abstract There are provided ultraviolet light absorbing agents of the formula ##STR1## wherein: X is >C═O, or ##STR2## Y is H or OH; Z is H, OH, OQ or OW, where at least one Z is OH if Y is H; Q is --CONH(CH 2 ) 3 Si(R 2 ) x (OR 1 ) y or --CONH(CH 2 ) 3 Si(R 2 ) x (OCOR 1 ) y ; and W is --C m H 2m+1 ; where x=0, 1 or 2, y=1, 2 or 3, x+y=3, R 1 and R 2 , independently are each alkyl having 1 to 6 carbon atoms and m=1 to 18. Also provided are organopolysiloxane protective coating compositions containing said ultraviolet light absorbing agents having unique utility for protecting transparent plastic articles.

Inventors

  • 👤 Bruce A. Ashby

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:17
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08K5/544; C08K5/5475; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08K5/5455; C09; C09D; C09D183/00; C09D183/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 220 words
An aqueous coating composition, which comprises: (a) a dispersion of a colloidal silica in a solution of the partial condensate of a silanol having the formula RSi(OH) 3 , where R is selected from the group consisting of alkyl having 1 to 3 carbon atoms and aryl, at least 70 weight percent of which is CH 3 Si(OH) 3 , in a mixture of an aliphatic alcohol and water, said dispersion containing from 10 to 50 percent by weight of solids, said solids consisting essentially of 10 to 70 percent by weight of the colloidal silica and 30 to 90 percent by weight of the partial condensate, and (b) an effective amount of an ultraviolet light absorbing agent consisting of a compound having the formula ##STR11## wherein: X is >C=O, or ##STR12## Y is H or OH; Z is H, OH, OQ or OW, where at least one Z is OH if Y is H; Q is --CONH(CH 2 ) 3 Si(R 2 ) x (OR 1 ) y or --CONH(CH 2 ) 3 Si(R 2 ) x (OCOR 1 ) y ; and W is C m H 2m+1 where x=0, 1 or 2, y=1, 2 or 3, x+y=3, and R 1 and R 2 , independently, are alkyl having 1 to 6 carbon atoms and m=1 to 18.
Claim 2
Dependent Claim 220 words
An aqueous coating composition, which comprises: (a) a dispersion of a colloidal silica in a solution of the partial condensate of a silanol having the formula RSi(OH) 3 , where R is selected from the group consisting of alkyl having 1 to 3 carbon atoms and aryl, at least 70 weight percent of which is CH 3 Si(OH) 3 , in a mixture of an aliphatic alcohol and water, said dispersion containing from 10 to 50 percent by weight of solids, said solids consisting essentially of 10 to 70 percent by weight of the colloidal silica and 30 to 90 percent by weight of the partial condensate, and (b) an effective amount of an ultraviolet light absorbing agent consisting of a compound having the formula ##STR11## wherein: X is >C=O, or ##STR12## Y is H or OH; Z is H, OH, OQ or OW, where at least one Z is OH if Y is H; Q is --CONH(CH 2 ) 3 Si(R 2 ) x (OR 1 ) y or --CONH(CH 2 ) 3 Si(R 2 ) x (OCOR 1 ) y ; and W is C m H 2m+1 where x=0, 1 or 2, y=1, 2 or 3, x+y=3, and R 1 and R 2 , independently, are alkyl having 1 to 6 carbon atoms and m=1 to 18.
Claim 3
Dependent Claim 36 words
A composition as defined in claim 1, which contains from about 5.0 to about 10.0 parts by weight of the ultraviolet light absorbing agent per 100 parts by weight of said composition, on a solids basis.
Claim 4
Dependent Claim 52 words
A composition as defined in claim 1, in which the ultraviolet light absorbing agent is selected from ##STR13## where Q is --CONH(CH 2 ) 3 Si(OCH 3 ) 3 , --CONH(CH 2 ) 3 SiCH 3 (OCH 3 ) 2 or --CONH(CH 2 ) 3 Si(CH 3 ) 2 (OCH 3 ).
Claim 5
Dependent Claim 15 words
A composition as defined in claim 3 wherein said ultraviolet light absorbing agent is 4-[γ-(trimethoxysilyl)propylcarbamyloxy]-2,2',4'-trihydroxybenzophenone.
Claim 6
Dependent Claim 21 words
A composition as defined in claim 1, in which the aliphatic alcohol comprises a mixture of methyl alcohol and isobutyl alcohol.
Claim 7
Dependent Claim 17 words
A composition as defined in claim 1, in which the silanol is CH 3 Si(OH) 3 .
Claim 8
Dependent Claim 13 words
A composition as defined in claim 1, which also includes a polysiloxane-polyether copolymer.
Claim 9
Dependent Claim 51 words
A composition as defined in claim 1, in which the colloidal dispersion contains from about 18 to about 25% by weight of solids consisting essentially of from about 25 to about 45% by weight of the colloidal silica and from about 55 to about 75% by weight of the partial condensate.

References Cited (Backward Citations)

US3708225A Cited
US4051161A Cited
US3976497A Cited
US3986997A Cited
US4177315A Cited
US4188451A Cited
US4278804A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-27 1986-12-27 1987-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-27 1990-12-27 1991-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-27 1994-12-27 1995-06-28 $7700.00 Window Closed / Lapsed

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