Lubricant antioxidants

Claim 2

A lubricating oil composition resistant to oxidative deterioration comprising a major proportion of hydrocarbon oil and about 0.1% to 10% of an additive having the structure A[(X) m-1 Y] n wherein: (a) A is an antioxidant functional moiety comprising pyridyl phenyl ketimine having the structure ##STR7## wherein R 1 is hydrogen, alkyl, alkenyl, or aryl, and (b) [(X) m-1 Y] n is an oil soluble moiety wherein (1) X is a divalent member connected directly to A and Y respectively, and is selected from the group consisting of succinyl, imine, amino, and dialkyl piperazine succinimide having the structures ##STR8## wherein p and q are whole numbers from 1 to 6, (2) m is a whole number from 1 to 2, (3) Y is a monovalent aliphatic chain of from 12 to 50 carbon atoms whose valence is connected directly to X when m is 2 and directly to A when m is 1, (4) n is a whole number from 1 to 2 and corresponds to the number of free valences in A.

Claim 3

The composition of claim 1 containing said additive wherein A is a pyridyl phenyl ketimine, X is a dialkyl piperazine succinimide, Y is a C 12 to C 50 olefin polymer, m is 2, and n is 1.

Claim 4

The composition of claim 2 wherein the additive comprises phenyl pyridyl ketimine of NN' diaminopropylpiperazine polybutyl succinimide.

Claim 5

An antioxidant catalyst which functions as a chain terminating species in the chain oxidation reaction that occurs in lubricant compositions under conditions of use comprising an antioxidant additive having the structure A[(X) m-1 Y] n wherein: (a) A is an antioxidant functional moiety selected from the group consisting of: (1) pyridyl phenyl ketimine having the structure ##STR9## wherein R 1 is hydrogen, alkyl, alkenyl, or aryl, and (b) [(X) m-1 Y] n is an oil soluble moiety wherein (1) X is a divalent member connected directly to A and Y respectively, and is selected from the group consisting of succinyl, imine, amino, and dialkyl piperazine succinimide having the structures ##STR10## wherein p and q are whole numbers from 1 to 6, (2) m is a whole number from 1 to 2, (3) Y is a monovalent aliphatic chain of from 12 to 50 carbon atoms whose valence is connected directly to X when m is 2 and directly to A when m is 1, (4) n is a whole number from 1 to 2 and corresponds to the number of free valences in A; whose calculated energy of the nearest unoccupied molecular orbital is greater than or equal to 0.7 and whose corresponding lubricant viscosity requires greater than or equal to 60 hours of use to increase to four times its initial value.

Claim 6

An antioxidant catalyst which functions as a chain terminating species in the chain oxidation reaction that occurs in lubricant compositions under conditions of use comprising an antioxidant additive having the structure A[(X) m-1 Y] n wherein: (a) A is an antioxidant functional moiety selected from the group consisting of: (1) pyridyl phenyl ketimine having the structure ##STR9## wherein R 1 is hydrogen, alkyl, alkenyl, or aryl, and (b) [(X) m-1 Y] n is an oil soluble moiety wherein (1) X is a divalent member connected directly to A and Y respectively, and is selected from the group consisting of succinyl, imine, amino, and dialkyl piperazine succinimide having the structures ##STR10## wherein p and q are whole numbers from 1 to 6, (2) m is a whole number from 1 to 2, (3) Y is a monovalent aliphatic chain of from 12 to 50 carbon atoms whose valence is connected directly to X when m is 2 and directly to A when m is 1, (4) n is a whole number from 1 to 2 and corresponds to the number of free valences in A; whose calculated energy of the nearest unoccupied molecular orbital is greater than or equal to 0.7 and whose corresponding lubricant viscosity requires greater than or equal to 60 hours of use to increase to four times its initial value.

Claim 7

The antioxidant catalyst of claim 4 wherein A is a pyridyl phenyl ketimine, X is a dialkyl piperazine succinimide, Y is a C 12 to C 50 olefin polymer, m is 2, and n is 1.

Claim 8

The antioxidant catalyst of claim 5 comprising phenyl pyridyl ketimine of NN' diaminopropylpiperazine polybutyl succinimide.