Process for producing new polyester resin and product thereof

Claim 2

In a process for producing a polyester resin by condensation polymerization of (a) a diol component having the formula: ##STR7## wherein R 1 is an alkylene group of 2 to 4 carbon atoms, and x and y are positive integers, the sum of x and y being 2 to 16, and (b) an acid component selected from the group consisting of polybasic carboxylic acids, anhydrides thereof, and lower alkyl esters thereof, the improvement which comprises: said acid component (b) contains (1) 1 to 50 mol % of a dibasic carboxylic acid or anhydride thereof having the formula: ##STR8## wherein R 2 and R 3 are saturated or unsaturated hydrocarbon groups of 4 to 20 carbon atoms, and (2) 10 to 30 mol % of trimellitic acid or anhydride thereof.

Claim 3

A process as claimed in claim 1, wherein said dibasic carboxylic acid or anhydride thereof of the formula (II) or (III) is selected from the group consisting of n-dodecenylsuccinic acid, iso-dodecenylsuccinic acid, n-dodecylsuccinic acid, iso-dodecylsuccinic acid, iso-octylsuccinic acid, and n-butylsuccinic acid.

Claim 4

A process as claimed in claim 1, wherein said condensation polymerization is conducted at 180° to 250° C. in an inert gas atmosphere, in the presence of an esterification catalyst.

Claim 5

A process as claimed in claim 3 in which the balance of said acid component (b) is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, fumaric acid, maleic acid, available anhydrides thereof and lower alkyl esters thereof.

Claim 6

A process according to claim 3, wherein said esterification catalyst is selected from the group consisting of zinc oxide, stannous oxide, dibutyltin oxide, dibutyltin dilaurate, and diisopropyl orthotitanate.

Claim 7

A process according to claim 1, wherein the balance of said acid component (b) is fumaric acid or maleic acid.

Claim 8

A process according to claim 1, wherein the amount of said trimellitic acid or anhydride thereof in said acid component (b) is 20 to 30 mol %.

Claim 9

A process for preparing a polyester resin which consists essentially of the steps of: condensation polymerizing a reaction mixture consisting essentially of (1) a diol compound of the formula: ##STR9## wherein R' is alkylene having 2 to 4 carbon atoms and x and y are positive integers such that the sum of x and y is from 2 to 16; (2) a dibasic carboxylic acid or anhydride thereof having the formula ##STR10## wherein R 2 and R 3 are saturated or unsaturated hydrocarbon groups having 4 to 20 carbon atoms, and (3) at least one compound selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, fumaric acid, maleic acid, available anhydrides thereof and lower alkyl esters thereof, at a temperature in the range of 180° C. to 250° C., in an inert atmosphere, in the presence of an esterification catalyst, while removing by-produced water from said reaction mixture, until substantially no further water can be removed therefrom; then adding (4) trimellitic acid or anhydride thereof to said reaction mixture and effecting further condensation polymerization of the resulting reaction mixture; with the provisos that the amount of said trimellitic acid or anhydride added is 10 to 30 mol % based on the total amount of (2), (3) and (4) and the amount of said acid or anhydride (2) is 1 to 50 mol % based onthe total amount of (2), (3) and (4); and then recovering the resulting polyester resin.

Claim 10

A process for preparing a polyester resin which consists essentially of the steps of: condensation polymerizing a reaction mixture consisting essentially of (1) a diol compound of the formula: ##STR9## wherein R' is alkylene having 2 to 4 carbon atoms and x and y are positive integers such that the sum of x and y is from 2 to 16; (2) a dibasic carboxylic acid or anhydride thereof having the formula ##STR10## wherein R 2 and R 3 are saturated or unsaturated hydrocarbon groups having 4 to 20 carbon atoms, and (3) at least one compound selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, fumaric acid, maleic acid, available anhydrides thereof and lower alkyl esters thereof, at a temperature in the range of 180° C. to 250° C., in an inert atmosphere, in the presence of an esterification catalyst, while removing by-produced water from said reaction mixture, until substantially no further water can be removed therefrom; then adding (4) trimellitic acid or anhydride thereof to said reaction mixture and effecting further condensation polymerization of the resulting reaction mixture; with the provisos that the amount of said trimellitic acid or anhydride added is 10 to 30 mol % based on the total amount of (2), (3) and (4) and the amount of said acid or anhydride (2) is 1 to 50 mol % based onthe total amount of (2), (3) and (4); and then recovering the resulting polyester resin.

Claim 11

A polyester resin prepared by the process as claimed in claim 1.

Claim 12

A polyester resin prepared by the process as claimed in claim 4.

Claim 13

A polyester resin prepared by the process as claimed in claim 6.

Claim 14

A polyester resin prepared by the process as claimed in claim 8.