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US4387193A Expired / Lapsed US ⏱️ 0.0 years remaining

Blends of polyetherimides and organopolysiloxane-polycarbonate block copolymers

Assignee: General Electric Co
•
Filing: 1982-03-18
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Granted: 1983-06-07
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Expires: 2002-03-18
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Abstract

Abstract Disclosed are blends of (a) a polyetherimide and (b) an organopolysiloxane - polycarbonate block copolymer. Such blends exhibit a good combination impact strength and flexural properties particularly at relatively high proportions of polyetherimide, and elastomeric behavior at relative high concentrations of the block copolymer of organopolysiloxane and polycarbonate.

Inventors

  • 👤 Harold F. Giles, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 02:13
CPC Classifications
C; C08; C08L; C08L69/00; C08L79/00; C08L79/04; C08L79/08; C08L83/00; C08L83/10

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 15 words
A composition comprising a blend proportion of (a) a polyetherimide and (b) a organopolysiloxane-polycarbonate copolymer.
Claim 2
Dependent Claim 15 words
A composition comprising a blend proportion of (a) a polyetherimide and (b) a organopolysiloxane-polycarbonate copolymer.
Claim 3
Dependent Claim 166 words
A composition in accordance with claim 1 wherein the polyetherimide has the formula; ##STR17## where a represents a whole number in excess of 1, the group --O--A< is selected from: ##STR18## R' being hydrogen, lower alkyl or lower alkoxy, Z is a member selected from the class consisting of (1) ##STR19## and (2) divalent organic radicals of the general formula: ##STR20## where X is a member selected from the class consisting of divalent radicals of the formulas, ##STR21## where q is 0 or 1, y is a whole number from 1 to 5, and R is a divalent organic radical selected from the class consisting of (1) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (2) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (3) divalent radicals included by the formula ##STR22## where Q is a member selected from the class consisting of ##STR23## where x is a whole number from 1 to 5 inclusive.
Claim 4
Dependent Claim 33 words
A composition in accordance with claim 2 wherein the polyetherimide is of the formula; ##STR24## and the divalent bonds of the --O--Z--O-- radical are in the 3,3'; 3,4'; 4,3' or the 4,4' position.
Claim 5
Dependent Claim 17 words
A composition in accordance with claim 3 wherein Z is; ##STR25## and R is selected from; ##STR26##
Claim 6
Dependent Claim 15 words
A composition in accordance with claim 4 wherein the polyetherimide is of the formula: ##STR27##
Claim 7
Dependent Claim 181 words
A composition in accordance with claims 1, 2, 3, 4, or 5 wherein the organopolysiloxane-polycarbonate copolymer is represented by the structural formula: ##STR28## where n is at least 1, and preferably n is an integer equal to from 1 to about 1000, inclusive, b is equal to from 1 to about 200, inclusive, c is equal to from about 5 to about 200, inclusive, while the ratio of b to c can vary from about 0.05 to about 3, inclusive, d is 1 or more, u is an integer from 1 to 4 inclusive, B is ##STR29## where T is a member selected from hydrogen and ##STR30## R 1 is a member selected from the class of hydrogen, monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, R 2 is a member selected from the class of monovalent hydrocarbon radicals, halogenated monovalent hydrocarbon radicals and cyanoalkyl radicals, R 3 is a member selected from the class consisting of monovalent hydrocarbon radicals and halogenated hydrocarbon radicals, and Y is a member selected from hydrogen, lower alkyl radicals and halogen radicals and mixtures thereof.
Claim 8
Dependent Claim 59 words
A composition in accordance with claim 6 wherein R 1 is selected from hydrogen, aryl radicals, halogenated aryl radicals, aralkyl radicals aliphatic, haloaliphatic and cycloaliphatic radicals; R 2 is selected from aryl radicals, halogenated aryl radicals; aralkyl radicals; aliphatic, haloaliphatic, cycloaliphatic radicals, and cyanoalkyl radicals. Y is selected from hydrogen, methyl, ethyl, propyl, chloro, bromo, iodo, and combinations thereof.
Claim 9
Dependent Claim 46 words
A composition in accordance with claim 7 wherein R 1 is selected from hydrogen, phenyl, chlorophenyl, xylyl, toyl, phenylethyl, benzyl, methyl, ethyl, propyl, chlorobutyl, and cyclohexyl, and R 2 is selected from phenyl, chlorophenyl, xylyl, toyl, phenylethyl, benzyl, methyl, ethyl, propyl, chlorobutyl, cyclohexyl, cyanoethyl and cyanobutyl.

References Cited (Backward Citations)

US3779990A Cited
US3781237A Cited
US4011274A Cited
US4225687A Cited
US4258155A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-06 1986-12-06 1987-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-06 1990-12-06 1991-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-06 1994-12-06 1995-06-07 $7700.00 Window Closed / Lapsed

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