US4387193A
Expired / Lapsed
US
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Blends of polyetherimides and organopolysiloxane-polycarbonate block copolymers
Assignee: General Electric Co
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Filing: 1982-03-18
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Granted: 1983-06-07
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Expires: 2002-03-18
Abstract
Abstract Disclosed are blends of (a) a polyetherimide and (b) an organopolysiloxane - polycarbonate block copolymer. Such blends exhibit a good combination impact strength and flexural properties particularly at relatively high proportions of polyetherimide, and elastomeric behavior at relative high concentrations of the block copolymer of organopolysiloxane and polycarbonate.
Inventors
- 👤 Harold F. Giles, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 02:13
CPC Classifications
C; C08; C08L; C08L69/00; C08L79/00; C08L79/04; C08L79/08; C08L83/00; C08L83/10
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
15 words
A composition comprising a blend proportion of (a) a polyetherimide and (b) a organopolysiloxane-polycarbonate copolymer.
Claim 2
Dependent Claim
15 words
A composition comprising a blend proportion of (a) a polyetherimide and (b) a organopolysiloxane-polycarbonate copolymer.
Claim 3
Dependent Claim
166 words
A composition in accordance with claim 1 wherein the polyetherimide has the formula; ##STR17## where a represents a whole number in excess of 1, the group --O--A< is selected from: ##STR18## R' being hydrogen, lower alkyl or lower alkoxy, Z is a member selected from the class consisting of (1) ##STR19## and (2) divalent organic radicals of the general formula: ##STR20## where X is a member selected from the class consisting of divalent radicals of the formulas, ##STR21## where q is 0 or 1, y is a whole number from 1 to 5, and R is a divalent organic radical selected from the class consisting of (1) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (2) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (3) divalent radicals included by the formula ##STR22## where Q is a member selected from the class consisting of ##STR23## where x is a whole number from 1 to 5 inclusive.
Claim 4
Dependent Claim
33 words
A composition in accordance with claim 2 wherein the polyetherimide is of the formula; ##STR24## and the divalent bonds of the --O--Z--O-- radical are in the 3,3'; 3,4'; 4,3' or the 4,4' position.
Claim 5
Dependent Claim
17 words
A composition in accordance with claim 3 wherein Z is; ##STR25## and R is selected from; ##STR26##
Claim 6
Dependent Claim
15 words
A composition in accordance with claim 4 wherein the polyetherimide is of the formula: ##STR27##
Claim 7
Dependent Claim
181 words
A composition in accordance with claims 1, 2, 3, 4, or 5 wherein the organopolysiloxane-polycarbonate copolymer is represented by the structural formula: ##STR28## where n is at least 1, and preferably n is an integer equal to from 1 to about 1000, inclusive, b is equal to from 1 to about 200, inclusive, c is equal to from about 5 to about 200, inclusive, while the ratio of b to c can vary from about 0.05 to about 3, inclusive, d is 1 or more, u is an integer from 1 to 4 inclusive, B is ##STR29## where T is a member selected from hydrogen and ##STR30## R 1 is a member selected from the class of hydrogen, monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, R 2 is a member selected from the class of monovalent hydrocarbon radicals, halogenated monovalent hydrocarbon radicals and cyanoalkyl radicals, R 3 is a member selected from the class consisting of monovalent hydrocarbon radicals and halogenated hydrocarbon radicals, and Y is a member selected from hydrogen, lower alkyl radicals and halogen radicals and mixtures thereof.
Claim 8
Dependent Claim
59 words
A composition in accordance with claim 6 wherein R 1 is selected from hydrogen, aryl radicals, halogenated aryl radicals, aralkyl radicals aliphatic, haloaliphatic and cycloaliphatic radicals; R 2 is selected from aryl radicals, halogenated aryl radicals; aralkyl radicals; aliphatic, haloaliphatic, cycloaliphatic radicals, and cyanoalkyl radicals. Y is selected from hydrogen, methyl, ethyl, propyl, chloro, bromo, iodo, and combinations thereof.
Claim 9
Dependent Claim
46 words
A composition in accordance with claim 7 wherein R 1 is selected from hydrogen, phenyl, chlorophenyl, xylyl, toyl, phenylethyl, benzyl, methyl, ethyl, propyl, chlorobutyl, and cyclohexyl, and R 2 is selected from phenyl, chlorophenyl, xylyl, toyl, phenylethyl, benzyl, methyl, ethyl, propyl, chlorobutyl, cyclohexyl, cyanoethyl and cyanobutyl.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-06-06 | 1986-12-06 | 1987-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-06-06 | 1990-12-06 | 1991-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-06-06 | 1994-12-06 | 1995-06-07 | $7700.00 | Window Closed / Lapsed |