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US4387129A Expired / Lapsed US ⏱️ 0.0 years remaining

Laminates having optically clear laminates having high molecular weight phenoxy-high crystallinity polyurethane adhesive

Assignee: HP Inc
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Filing: 1982-02-02
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Granted: 1983-06-07
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Expires: 2002-02-02
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Abstract

Abstract An adhesive for bonding polyethylene terephthalate, polycarbonate and other transparent thermoplastic sheets to form optically clear laminants with improved bond strengths which remain intact over temperature exposures ranging from -40° C. to 70° C. and humidities ranging up to 90% at 40° C. is provided. The adhesive is a combination of approximately 20% molecular weight phenoxy resin and approximately 80% molecular weight polyurethane resin.

Inventors

  • 👤 Kent D. Vincent

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 01:12
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B7/00; B32B7/04; B32B7/12; B32B2375/00; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24843; Y10T428/24851; Y10T428/24868; Y10T428/24884; Y10T428/24893; Y10T428/24901; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/2848; Y10T428/2852; Y10T428/2896; Y10T428/31504; Y10T428/31507; Y10T428/31551; Y10T428/31565; Y10T428/31786

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 119 words
A printed label for laminating substrates comprising: a substrate having a first surface and a second surface; a first printed layer of graphical information printed on the first surface of the substrate; and an optically clear adhesive layer applied to the second surface of the substrate, the adhesive comprising a polyurethane resin and up to 50% phenoxy resin by weight, wherein said polyurethane resin is represented by the following formula: ##STR3## where R' is a long chain predominantly linear diol, R is any chemical structure which ties two isocyanate groups together and m is an integer greater than one, and wherein said phenoxy resin is represented by the following formula: ##STR4## where m is an integer greater than one.
Claim 2
Dependent Claim 119 words
A printed label for laminating substrates comprising: a substrate having a first surface and a second surface; a first printed layer of graphical information printed on the first surface of the substrate; and an optically clear adhesive layer applied to the second surface of the substrate, the adhesive comprising a polyurethane resin and up to 50% phenoxy resin by weight, wherein said polyurethane resin is represented by the following formula: ##STR3## where R' is a long chain predominantly linear diol, R is any chemical structure which ties two isocyanate groups together and m is an integer greater than one, and wherein said phenoxy resin is represented by the following formula: ##STR4## where m is an integer greater than one.
Claim 3
Dependent Claim 21 words
A label as in claim 1 wherein the adhesive layer comprises approximately 20% phenoxy resin and 80% polyurethane resin by weight.
Claim 4
Dependent Claim 11 words
A label as in claim 1 wherein the substrate comprises polycarbonate.
Claim 5
Dependent Claim 12 words
A label as in claim 1 wherein the substrate comprises polyethylene terephthalate.
Claim 6
Dependent Claim 118 words
An optically clear adhesive panel for laminating substrates comprising: a substrate having a first surface and a second surface; and a first layer of optically clear adhesive cast to the first surface and a second layer of optically clear adhesive cast to the second surface, the adhesive comprising a polyurethane resin and up to 50% phenoxy resin by weight, wherein said polyurethane resin is represented by the following formula: ##STR5## where R' is a long chain predominantly linear diol, R is any chemical structure which ties two isocyanate groups together and m is an integer greater than one, and wherein said phenoxy resin is represented by the following formula: ##STR6## where m is an integer greater than one.
Claim 7
Dependent Claim 118 words
An optically clear adhesive panel for laminating substrates comprising: a substrate having a first surface and a second surface; and a first layer of optically clear adhesive cast to the first surface and a second layer of optically clear adhesive cast to the second surface, the adhesive comprising a polyurethane resin and up to 50% phenoxy resin by weight, wherein said polyurethane resin is represented by the following formula: ##STR5## where R' is a long chain predominantly linear diol, R is any chemical structure which ties two isocyanate groups together and m is an integer greater than one, and wherein said phenoxy resin is represented by the following formula: ##STR6## where m is an integer greater than one.
Claim 8
Dependent Claim 22 words
The optically clear adhesive as in claim 5 wherein the adhesive comprises approximately 20% phenoxy resin and 80% polyurethane resin by weight.
Claim 9
Dependent Claim 14 words
The optically clear adhesive panel as in claim 5 wherein the substrate comprises polycarbonate.
Claim 10
Dependent Claim 15 words
The optically clear adhesive panel as in claim 5 wherein the substrate comprises polyethylene terephthalate.
Claim 11
Dependent Claim 79 words
An optically clear adhesive panel as in claim 5 for laminating substrates as a membrane switch further comprising: a flexible membrane having a first electrical contact on a membrane surface, said membrane surface adhering to said first layer of adhesive; and a base having a second electrical contact on a base surface, said base surface adhering to said second layer of adhesive, said substrate being cleared of said electrical contacts and serving to separate said first and second contacts.

References Cited (Backward Citations)

US3320090A Cited
US3440086A Cited
DE2443252A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-06 1986-12-06 1987-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-06 1990-12-06 1991-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-06 1994-12-06 1995-06-07 $7700.00 Window Closed / Lapsed

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