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US4386165A Expired / Lapsed US ⏱️ 0.0 years remaining

Styrenic polymer foams and preparation thereof

Assignee: Dow Chemical Co
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Filing: 1981-09-28
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Granted: 1983-05-31
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Expires: 2001-09-28
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Abstract

Abstract Extruded styrenic polymer foams having improved flammability characteristics are obtained when using volatile fluid blowing agents by incorporating therein a small amount (e.g., from about 0.03 to about 2 weight percent based on polymer) of a waxy material in conjunction with at least one conventional non-waxy halogenated flame retarding agent.

Inventors

  • 👤 Kyung W. Suh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 02:38
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0061; C08J9/0014; C08J9/0019; C08J2325/00; C08J2325/02; C08J2491/00; Y; Y10; Y10S; Y10S521/00; Y10S521/907

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 53 words
An expandable styrenic polymer composition comprising a styrenic polymer, at least one volatile organic blowing agent, at least one non-waxy halogenated flame retarding agent and from about 0.03 to less than 2 weight percent of a waxy material melting above the foaming point of the styrenic polymer composition but below about 140° C.
Claim 2
Dependent Claim 53 words
An expandable styrenic polymer composition comprising a styrenic polymer, at least one volatile organic blowing agent, at least one non-waxy halogenated flame retarding agent and from about 0.03 to less than 2 weight percent of a waxy material melting above the foaming point of the styrenic polymer composition but below about 140° C.
Claim 3
Dependent Claim 14 words
The expandable styrenic polymer composition of claim 1 wherein the styrenic polymer is polystyrene.
Claim 4
Dependent Claim 15 words
The expandable styrenic polymer composition of claim 1 wherein the waxy material is chlorinated paraffin.
Claim 5
Dependent Claim 16 words
The expandable styrenic polymer composition of claim 1 wherein the halogenated flame retarding agent is monochloropentabromocyclohexane.
Claim 6
Dependent Claim 30 words
The expandable styrenic polymer composition of claim 1 wherein the waxy material is present in an amount of from 0.1 to about 1.5 weight percent based upon the styrenic polymer.
Claim 7
Dependent Claim 30 words
The expandable styrenic polymer composition of claim 1 wherein the waxy material is present in an amount of from 0.1 to about 1.0 weight percent based upon the styrenic polymer.
Claim 8
Dependent Claim 125 words
In a process for preparing an extruded styrenic polymer foam wherein a heat-plastified styrenic polymer gel containing at least one volatile fluid foaming agent and at least one non-waxy halogenated flame retarding agent is expressed from a die into a region of reduced pressure and wherein the expressed gel expands into cellular form and is cooled to a temperature at which the expanded cellular gel is self supporting; the improvement which comprises incorporating into the heat-plastified unfoamed gal from about 0.03 to less than 2 weight percent, based upon the styrenic polymer weight, of a waxy material which has a melting point below about 140° C. and which imparts improved flammability characteristics to the resulting styrenic polymer foam without significantly increasing the cell size thereof.
Claim 9
Dependent Claim 125 words
In a process for preparing an extruded styrenic polymer foam wherein a heat-plastified styrenic polymer gel containing at least one volatile fluid foaming agent and at least one non-waxy halogenated flame retarding agent is expressed from a die into a region of reduced pressure and wherein the expressed gel expands into cellular form and is cooled to a temperature at which the expanded cellular gel is self supporting; the improvement which comprises incorporating into the heat-plastified unfoamed gal from about 0.03 to less than 2 weight percent, based upon the styrenic polymer weight, of a waxy material which has a melting point below about 140° C. and which imparts improved flammability characteristics to the resulting styrenic polymer foam without significantly increasing the cell size thereof.
Claim 10
Dependent Claim 31 words
The process improvement of claim 7 in which the waxy material has a melting point which is equal to or greater than the foaming temperature employed for the heat-plastified polymer gel.
Claim 11
Dependent Claim 13 words
The process improvement of claim 8 wherein the waxy material is chlorinated paraffin.
Claim 12
Dependent Claim 30 words
The process improvement of claim 8 wherein the waxy material is employed in an amount of from about 0.1 to about 1.5 weight percent based upon the styrenic polymer weight.
Claim 13
Dependent Claim 30 words
The process improvement of claim 8 wherein the waxy material is employed in an amount of from about 0.1 to about 1.0 weight percent based upon the styrenic polymer weight.
Claim 14
Dependent Claim 14 words
The process improvement of claim 8 wherein the halogenated flame retarding agent is monochloropentabromocyclohexane.
Claim 15
Dependent Claim 12 words
The process improvement of claim 8 wherein the styrenic polymer is polystyrene.

References Cited (Backward Citations)

US2894918A Cited
US3004935A Cited
US3668155A Cited
US3635850A Cited
US3655589A Cited
US4229396A Cited
US4325852A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-30 1986-11-29 1987-05-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-30 1990-11-29 1991-05-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-30 1994-11-29 1995-05-31 $7700.00 Window Closed / Lapsed

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