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US4385305A Expired / Lapsed US ⏱️ 0.0 years remaining

Recording member

Assignee: Hitachi Ltd
•
Filing: 1981-08-06
•
Granted: 1983-05-24
•
Expires: 2001-08-06
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Abstract

Abstract Disclosed is a recording member which comprises a substrate and a recording layer containing at least selenium and at least one element selected from the group consisting of tellurium and bismuth, wherein the selenium content is higher in the vicinity of the surface of the recording layer and/or in the vicinity of the interface between the recording layer and the substrate than the average selenium content in other portions. By virtue of the presence of this high selenium content portion, the oxidation resistance and water resistance are improved, and a recording member having stable characteristics can be obtained.

Inventors

  • 👤 Motoyasu Terao
  • 👤 Shinkichi Horigome
  • 👤 Munehisa Mitsuya
  • 👤 Sakae Ota

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 07:19
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/243; G11B2007/24302; G11B2007/24314; G11B2007/24316; Y; Y10; Y10S; Y10S430/00; Y10S430/146; Y10S430/165

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 117 words
A recording member for recording informations, which comprises a substrate and a recording layer formed on the substrate, which is deformed or removed under irradiation with energy beams, wherein said recording layer contains at least selenium and at least one element selected from the group consisting of tellurium and bismuth, and the selenium content is higher in the vicinity of the surface of the recording layer and/or the vicinity of the interface between the recording layer and the substrate than the average selenium content in other portions and wherein the thickness of the high selenium content portion is 1 to 5 nm, whereby oxidation of said recording layer is decreased to provide a more stable recording member.
Claim 2
Dependent Claim 117 words
A recording member for recording informations, which comprises a substrate and a recording layer formed on the substrate, which is deformed or removed under irradiation with energy beams, wherein said recording layer contains at least selenium and at least one element selected from the group consisting of tellurium and bismuth, and the selenium content is higher in the vicinity of the surface of the recording layer and/or the vicinity of the interface between the recording layer and the substrate than the average selenium content in other portions and wherein the thickness of the high selenium content portion is 1 to 5 nm, whereby oxidation of said recording layer is decreased to provide a more stable recording member.
Claim 3
Dependent Claim 25 words
A recording member as set forth in claim 1, wherein in the high selenium content portion, the selenium content is 50 to 100 atomic %.
Claim 4
Dependent Claim 46 words
A recording member as set forth in any of claims 1 through 2, wherein the high selenium content portion is formed either in the vicinity of the surface of the recording layer or in the vicinity of the interface between the substrate and the recording layer.
Claim 5
Dependent Claim 55 words
A recording member as set forth in claim 3, wherein the high selenium content portion formed in the vicinity of the surface of the recording layer is located on the inner side from the surface and the distance of the center of said high selenium content portion from the surface is up to 10 nm.
Claim 6
Dependent Claim 35 words
A recording member as set forth in claim 3, wherein the high selenium content portion formed in the vicinity of the surface of the recording layer is located in the surface of the recording layer.
Claim 7
Dependent Claim 58 words
A recording member as set forth in claim 3, wherein the high selenium content portion formed in the vicinity of the interface between the substrate and the recording layer is located on the inner side from said interface and the distance of the center of the high selenium content portion from said interface is up to 15 nm.
Claim 8
Dependent Claim 31 words
A recording member as set forth in claim 3, wherein the high selenium content portion formed in the vicinity of the interface and the recording layer is located in said interface.
Claim 9
Dependent Claim 32 words
A recording member as set forth in any of claims 1 through 2, wherein the high selenium content portion is formed only in the vicinity of the surface of the recording layer.
Claim 10
Dependent Claim 55 words
A recording member as set forth in claim 9, wherein the high selenium content portion formed in the vicinity of the surface of the recording layer is located on the inner side from the surface and the distance of the center of said high selenium content portion from the surface is up to 10 nm.
Claim 11
Dependent Claim 35 words
A recording member as set forth in claim 8, wherein the high selenium content portion formed in the vicinity of the surface of the recording layer is located in the surface of the recording layer.
Claim 12
Dependent Claim 35 words
A recording member as set forth in any of claims 1 through 2, wherein the high selenium content portion is formed only in the vicinity of the interface between the substrate and the recording layer.
Claim 13
Dependent Claim 58 words
A recording member as set forth in claim 11, wherein the high selenium content portion formed in the vicinity of the interface between the substrate and the recording layer is located on the inner side from said interface and the distance of the center of the high selenium content portion from said interface is up to 15 nm.
Claim 14
Dependent Claim 27 words
A recording member as set forth in claim 11, wherein the high selenium content portion formed in the vicinity of the interface is located in said interface.
Claim 15
Dependent Claim 24 words
A recording member as set forth in claim 1, wherein the average selenium content in the recording layer is 0.5 to 30 atomic %.
Claim 16
Dependent Claim 25 words
A recording member as set forth in any of claims 1 through 2, wherein the thickness of the recording layer is 5 to 10 nm.
Claim 17
Dependent Claim 19 words
A recording member as set forth in claim 15, wherein the thickness of the recording layer is 20-100 nm.
Claim 18
Dependent Claim 19 words
A recording member as set forth in claim 16, wherein the thickness of the recording layer is 25-60 nm.
Claim 19
Dependent Claim 25 words
A recording member as set forth in claim 15; wherein said recording layer has a protective film on the surface thereof not adjacent said substrate.
Claim 20
Dependent Claim 23 words
A recording member as set forth in any of claims 1 through 2, wherein the recording layer contains at least tellurium and selenium.
Claim 21
Dependent Claim 45 words
A recording member as set forth in any of claims 1 through 2, wherein the recording layer contains up to 30 atomic % of at least one additive element selected from the group consisting of silicon, germanium, arsenic, thallium, tin, lead, indium, antimony and tantalum.
Claim 22
Dependent Claim 22 words
A recording member as set forth in claim 20, wherein the content of said additive element is 1 to 5 atomic %.
Claim 23
Dependent Claim 25 words
A recording member as set forth in any of claims 1 through 2, wherein the recording layer contains up to 30 atomic % of lead.
Claim 24
Dependent Claim 19 words
A recording member as set forth in claim 22, wherein the lead content is 1 to 5 atomic %.
Claim 25
Dependent Claim 43 words
A recording member as set forth in claim 1, wherein the content of the selenium in said high selenium content portion is 50 to 100 atomic %, and wherein the average selenium content in the recording layer is 0.5 to 30 atomic %.
Claim 26
Dependent Claim 29 words
A recording member as set forth in any one of claims 1 through 2, wherein the average Se content in the recording layer is 10 to 20 atomic %.
Claim 27
Dependent Claim 36 words
A recording member as set forth in any one of claims 1 through 2, wherein the Se content of the portions of the recording layer other than said high selenum content portion is 0-29.8 atomic %.
Claim 28
Dependent Claim 35 words
A recording member as set forth in claim 26, wherein the Se content of the portions other than the high selenium content portion is greater than 0 atomic % but lower than 29.8 atomic %.

References Cited (Backward Citations)

US4032691A Cited
US4238803A Cited
US4296419A Cited
US4264911A Cited
US4318112A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-23 1986-11-22 1987-05-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-23 1990-11-22 1991-05-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-23 1994-11-22 1995-05-24 $7700.00 Window Closed / Lapsed

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