Boilers

Claim 2

A shell boiler comprising a housing, a primary flame combustion chamber in said housing, an inlet for leading a fuel or a fuel/gas mixture into said primary flame combustion chamber whereby the fuel or fuel/gas mixture is burned to generate hot exhaust gases, at least two arrays of pipes in series with and separate from the primary combustion chamber adapted to receive the hot gases from said primary flame combustion chamber, an exit in said housing communicating with the last of said arrays for leading exhaust gases away from the boiler and fluid heat transfer means for taking up heat from the exhaust gases and thereby cooling the pipes and the primary combustion chamber, characterised in that the boiler includes at least one secondary combustion chamber in communication with the primary combustion chamber so as to receive exhaust gases therefrom, said secondary combustion chamber being disposed at a position intermediate the first array of pipes and the second array of pipes and including a catalyst disposed in such a position that at least a proportion of any unburnt fuel/gas mixture in the exhaust gases leaving the primary combustion chamber undergoes catalytic combustion in the secondary combustion chamber, the said catalyst comprising a ceramic or metallic support, an intermediate layer of a refractory metal oxide and a catalytic material selected from the group consisting of ruthenium, rhodium, palladium, iridium and platinum and alloys of the said metals with each other and with one or more base metals.

Claim 3

A shell boiler comprising a housing, a primary flame combustion chamber in said housing, an inlet for leading a fuel or a fuel/gas mixture into said primary flame combustion chamber whereby the fuel or fuel/gas mixture is burned to generate hot exhaust gases, at least two arrays of pipes in series with and separate from the primary combustion chamber adapted to receive the hot gases from said primary flame combustion chamber, an exit in said housing communicating with the last of said arrays for leading exhaust gases away from the boiler and fluid heat transfer means for taking up heat from the exhaust gases and thereby cooling the pipes and the primary combustion chamber, characterised in that the boiler includes at least one secondary combustion chamber in communication with the primary combustion chamber so as to receive exhaust gases therefrom, and in that the secondary chamber includes a catalyst disposed in such a position that at least a proportion of any unburnt fuel/gas mixture in the exhaust gases leaving the primary combustion chamber undergoes catalytic combustion in the secondary combustion chamber, the said catalyst comprising a ceramic or metallic support, an intermediate layer of a refractory metal oxide and a catalytic material selected from the group consisting of ruthenium, rhodium, palladium, iridium and platinum and alloys of the said metals with each other and with one or more base metals, the secondary combustion chamber comprising the second array of the said array of pipes, and the said catalyst being supported on at least some of the internal walls of the said array of pipes.

Claim 4

A shell boiler comprising a housing, a primary flame combustion chamber in said housing, an inlet for leading a fuel or a fuel/gas mixture into said primary flame combustion chamber whereby the fuel or fuel/gas mixture is burned to generate hot exhaust gases, at least two arrays of pipes in series with and separate from the primary combustion chamber adapted to receive the hot gases from said primary flame combustion chamber, an exit in said housing communicating with the last of said arrays for leading exhaust gases away from the boiler and fluid heat transfer means for taking up heat from the exhaust gases and thereby cooling the pipes and the primary combustion chamber, characterised in that the boiler includes at least one secondary combustion chamber in communication with the primary combustion chamber so as to receive exhaust gases therefrom, and in that the secondary chamber includes a catalyst disposed in such a position that at least a proportion of any unburnt fuel/gas mixture in the exhaust gases leaving the primary combustion chamber undergoes catalytic combustion in the secondary combustion chamber, the said catalyst comprising a ceramic or metallic support, an intermediate layer of a refractory metal oxide and a catalytic material selected from the group consisting of ruthenium, rhodium, palladium, iridium and platinum and alloys of the said metals with each other and with one or more base metals, the secondary combustion chamber comprising the second array of the said array of pipes, and the said catalyst being supported on at least some of the internal walls of the said array of pipes.