US4383104A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Phenolic chelate resin, process for producing the same, and method of recovering heavy metal ions with the same
Assignee: Unitika Ltd
•
Filing: 1981-03-23
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Granted: 1983-05-10
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Expires: 2001-03-23
Abstract
Abstract The phenolic chelate resin has a chelate-forming group wherein part or all of the hydrogen atoms in a primary and/or secondary alkylamino group introduced in a phenol nucleus are replaced by a methylenephosphonate group. Also disclosed is a process for producing such a chelate resin, and a method for recovering heavy metal ions with such a resin. The resin has particularly high selectivity for adsorbing uranium ions, as well as high heat, acid and alkali resistance as well as dimensional stability. The resin is very effective for recovering uranium from various uranium-containing solutions such as sea water, crude phosphoric acid fertilizer solutions, lowgrade uranium ore, waste water from uranium refining, and uranium mine water.
Inventors
- 👤 Akio Sasaki
- 👤 Yoshiaki Echigo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 16:03
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/28; C02F1/285; B; B01; B01J; B01J45/00; C08; C08G; C08G14/00; C08G14/02; C08G14/04; C08G14/12; C08G8/00; C08G8/04; C08G8/08; C08G8/24; C08G8/28; C22; C22B; C22B3/00; C22B3/20; C22B3/42; C22B60/00; C22B60/02; C22B60/0204; C22B60/0217; C22B60/0252; C22B60/0265; C02F2101/00; C02F2101/006; Y; Y02; Y02P; Y02P10/00; Y02P10/20; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/911; Y10S210/912
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
29 words
A phenolic chelate resin having a chelate-forming group, wherein hydrogen atoms in a primary or secondary alkylamino group introduced in a phenol nucleus are substituted by a methylenephosphonate group.
Claim 2
Dependent Claim
29 words
A phenolic chelate resin having a chelate-forming group, wherein hydrogen atoms in a primary or secondary alkylamino group introduced in a phenol nucleus are substituted by a methylenephosphonate group.
Claim 3
Dependent Claim
80 words
A process for producing a phenolic chelate resin comprising the steps of: reacting a compound having a phenolic hydroxyl group and a primary or secondary alkylamino group in the same molecule with phosphorous acid and formaldehyde in the presence of a mineral acid; allowing the reaction to continue in order to form a reaction product wherein hydrogen atoms in the alkyl amino group are replaced by a methylenephosphonate group; and condensing the resulting reaction product with a phenol and aldehyde.
Claim 4
Dependent Claim
80 words
A process for producing a phenolic chelate resin comprising the steps of: reacting a compound having a phenolic hydroxyl group and a primary or secondary alkylamino group in the same molecule with phosphorous acid and formaldehyde in the presence of a mineral acid; allowing the reaction to continue in order to form a reaction product wherein hydrogen atoms in the alkyl amino group are replaced by a methylenephosphonate group; and condensing the resulting reaction product with a phenol and aldehyde.
Claim 5
Dependent Claim
40 words
A process as claimed in claim 2 wherein the compound having a phenolic hydroxyl group and a primary alkylamino group in the same molecule is represented by the formula (I): ##STR5## wherein n is an integer of 1 to 20.
Claim 6
Dependent Claim
40 words
A process as claimed in claim 2 wherein the compound having a phenolic hydroxyl group and a primary alkylamino group in the same molecule is represented by the formula (II): ##STR6## wherein n is an integer of 1 to 20.
Claim 7
Dependent Claim
43 words
A process as claimed in claim 2 wherein the compound having a phenolic hydroxyl group and a secondary alkylamino group in the same molecule is represented by for formula (III): ##STR7## wherein n and m are each an integer of 1 to 20.
Claim 8
Dependent Claim
28 words
A process as claimed in claim 2 wherein the compound having a phenolic hydroxyl group and primary and secondary alkylamino groups in the same molecule, is ammonia resol.
Claim 9
Dependent Claim
29 words
A process as claimed in claim 2 wherein the compound having a phenolic hydroxyl group and primary and secondary alkylamino groups in the same molecule is a polyethyleneimine/phenol/formalin condensate.
Claim 10
Dependent Claim
31 words
A phenolic chelate resin as claimed in claim 1, wherein hydrogen atoms in said primary and said secondary alkylamino group introduced in a phenol nucleus are substituted by a methylenephosphate group.
Claim 11
Dependent Claim
25 words
A phenolic chelate resin as claimed in any of claims 1 or 8 wherein all of said hydrogen atoms are substituted by a methylenephosphonate group.
Claim 12
Dependent Claim
29 words
A process for producing a phenolic chelate resin as claimed in claim 2, wherein said compound having a phenolic hydroxyl group has a primary and a secondary alkylamino group.
Claim 13
Dependent Claim
31 words
A process as claimed in any of claims 2 or 10, wherein all of the hydrogen atoms in the alkylamino group of the reaction product are replaced by a methylenephosphonate group.
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Cited
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-05-09 | 1986-11-08 | 1987-05-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-05-09 | 1990-11-08 | 1991-05-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-05-09 | 1994-11-08 | 1995-05-10 | $7700.00 | Window Closed / Lapsed |