Polyepoxide curing by polymercaptans and a reaction product of amino acids or lactams with amines

Claim 2

A curing system for epoxy resins and mixtures of epoxy resins and polyacrylate esters comprising: (a) at least one polymercaptan, and (b) at least one catalytic co-curing agent which is the reaction product of: (i) at least one amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.

Claim 3

The curing system of claim 1 wherein there is from about 0.01 to about 3.0 equivalents of amine active hydrogen of catalytic co-curing agent per epoxide equivalent and per equivalent of acrylate double bond where polyacrylate is present and from about 0.05 to about 1.5 equivalents of mercaptan active hydrogen of polymercaptan per epoxide equivalent and per equivalent of acrylate double bond where polyacrylate is present.

Claim 4

The curing system of claim 1 wherein said component (i) is selected from the group consisting of: ##STR5## where X is H or a monovalent hydrocarbon radical containing from 1 to 22 carbon atoms which is selected from the group consisting of open chain monovalent hydrocarbon radicals, monovalent cyclic hydrocarbon radicals, monovalent oxygen containing hydrocarbon radicals, monovalent sulfur containing hydrocarbon radicals, monovalent nitrogen containing hydrocarbon radicals, monovalent phosphorous containing hydrocarbon radicals and monovalent halogen containing hydrocarbon radicals, and ##STR6## where R is H or a monovalent hydrocarbon radical containing from 1 to 22 carbon atoms which is selected from the group consisting of open chain monovalent hydrocarbon radicals, monovalent cyclic hydrocarbon radicals including those cyclic radicals formed by joining together the two R radicals which are attached to the same nitrogen atom, monovalent oxygen containing hydrocarbon radicals, monovalent sulfur containing hydrocarbon radicals, monovalent nitrogen containing hydrocarbon radicals, monovalent phosphorous containing hydrocarbon radicals, and monovalent halogen containing hydrocarbon radicals, where n is 0 or 1, and where n is 1, X is a divalent hydrocarbon radical containing from 1 to 22 carbon atoms and is selected from the group consisting of open chain divalent hydrocarbon radicals, divalent cyclic hydrocarbon radicals, divalent oxygen containing hydrocarbon radicals, divalent sulfur containing hydrocarbon radicals, divalent nitrogen containing hydrocarbon radicals, divalent phosphorous containing hydrocarbon radicals and divalent halogen containing hydrocarbon radicals and R' is ethylene or alkyl substituted ethylene where alkyl can be from 1 to 10 carbon atoms.

Claim 5

The curing system of claim 1 wherein said amine is the reaction product of at least one of mono- and polycarboxylic acid and amide forming derivatives thereof with amine containing at least one primary aliphatic amine substituent.

Claim 6

The curing system of claim 1 wherein there is present tertiary amine in an amount up to about 20 parts by weight per 100 parts by weight of polyepoxide or of polyepoxide and polyacrylate ester where polyacrylate ester is present.

Claim 7

The curing system of claim 1 wherein there is present from about 0.1 to about 100 equivalents of component (i) per one equivalent of component (ii).

Claim 8

The curing system of claim 1 wherein said component (i) is obtained from diethylene triamine and adipic acid and said component (ii) is 2-pyrrolidinone.

Claim 9

The curing system of claim 1 wherein said component (i) is obtained from triethylene tetramine and adipic acid and said component (ii) is 2-pyrrolidinone.

Claim 10

The curing system of claim 1 wherein said component (ii) is ε-caprolactam.

Claim 11

A curable epoxy resin composition comprising at least one polyepoxide and a curing system comprising: (a) at least one polymercaptan, and (b) at least one co-curing agent which is the reaction product of: (i) at least one aliphatic amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.

Claim 12

A curable epoxy resin composition comprising at least one polyepoxide and a curing system comprising: (a) at least one polymercaptan, and (b) at least one co-curing agent which is the reaction product of: (i) at least one aliphatic amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.

Claim 13

The curable epoxy resin composition of claim 10 wherein there is from about 0.01 to about 3.0 equivalents of amine active hydrogen of catalytic co-curing agent per epoxide equivalent and per equivalent of acrylate double bond where polyacrylate is present and from about 0.05 to about 1.5 equivalents of mercaptan active hydrogen per epoxide equivalent and per equivalent of acrylate double bond where polyacrylate is present.

Claim 14

A substantially insoluble and infusible product which is the reaction product of a polyepoxide composition comprising at least one polyepoxide or mixtures of at least one polyepoxide and polyacrylate ester and a curing system comprising: (a) at least one polymercaptan, and (b) at least one co-curing agent which is the reaction product of: (i) at least one aliphatic amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.

Claim 15

A substantially insoluble and infusible product which is the reaction product of a polyepoxide composition comprising at least one polyepoxide or mixtures of at least one polyepoxide and polyacrylate ester and a curing system comprising: (a) at least one polymercaptan, and (b) at least one co-curing agent which is the reaction product of: (i) at least one aliphatic amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.

Claim 16

The composition of claim 12 wherein there is from about 0.01 to about 3.0 equivalents of amine active hydrogen of catalytic co-curing agent per epoxide equivalent and per equivalent of acrylate double bond where polyacrylate is present and from about 0.05 to about 1.5 equivalents of mercaptan active hydrogen per epoxide equivalent and per equivalent of acrylate double bond where polyacrylate is present.

Claim 17

A process for curing polyepoxide comprising mixing together and reacting at least one polyepoxide or mixtures of at least one polyepoxide and polyacrylate ester with a curing system comprising: (a) at least one polymercaptan, and (b) at least one catalytic co-curing agent which is the condensation product of: (i) at least one aliphatic amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.

Claim 18

A process for curing polyepoxide comprising mixing together and reacting at least one polyepoxide or mixtures of at least one polyepoxide and polyacrylate ester with a curing system comprising: (a) at least one polymercaptan, and (b) at least one catalytic co-curing agent which is the condensation product of: (i) at least one aliphatic amine containing at least one primary aliphatic amine substituent where the aliphatic moiety is ethylene or greater with (ii) at least one member of the group consisting of amino acid, its corresponding lactam and amide forming derivatives of same.