US4381339A
Expired / Lapsed
US
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Photographic recording material and non-diffusing compounds to be used in the material which contains a photographically active group which can be split off
Assignee: Agfa Gevaert AG
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Filing: 1981-04-09
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Granted: 1983-04-26
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Expires: 2001-04-09
Abstract
Abstract Novel non-diffusing reducible compounds of formula I which under alkaline development conditions release a diffusible photographically useful compound are of use in color diffusion transfer processes. ##STR1## R 0 completes a ring system; E represents a reducible group; W reduces the electron density in the position of E so that E is reducible under photographic development conditions; GR 1 represents a group from which photographically useful compound R 1 is released; XR 2 represents a group that by reduction of E is activated to cooperate with GR 1 in an intramolecular reaction with release of R 1 .
Inventors
- 👤 Gunter Renner
- 👤 Erich Wolff
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 08:33
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/02; G03C8/08; G03C8/10; G03C8/12; G03C8/22; C; C09; C09B; C09B29/00; C09B43/00; Y; Y10; Y10S; Y10S430/00; Y10S430/156; Y10S430/159
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
243 words
Photographic recording material having at least one light-sensitive silver halide emulsion layer and in association with said silver halide emulsion layer, a non-diffusing reducible compound which can be split to release a diffusible photographically useful compound, the non-diffusing reducible compound corresponding to the following formula I ##STR17## in which the substituents W, XR 2 , G--R 1 and E may be arranged in any positions in relation to each other and in which: R 0 represents the atoms required to complete a ring system comprising at least one aromatic or heteroaromatic ring; W represents a group which reduces the electron density in the ring at the position of E and is selected from the group consisting of a halogen atom, a cyano group, a nitro group, a nitroso group, a trifluoromethyl group, a quaternary ammonium group and an acyl group; m represents an integer of from 1 to 3; G represents a group from which R 1 can be split off under photographic development conditions; R 1 represents the residue of a diffusible photographically active compound; X represents an oxygen atom, a sulfur atom or the group --NR 3 --; R 2 represents hydrogen or a group which can be split off in alkaline medium, and E represents a reducible substituent selected from the group consisting of ##STR18## R 3 represents hydrogen, alkyl, aryl, a heterocyclic group or aralkyl, and the compound of formula I contains at least one substituent conferring diffusion resistance.
Claim 2
Dependent Claim
243 words
Photographic recording material having at least one light-sensitive silver halide emulsion layer and in association with said silver halide emulsion layer, a non-diffusing reducible compound which can be split to release a diffusible photographically useful compound, the non-diffusing reducible compound corresponding to the following formula I ##STR17## in which the substituents W, XR 2 , G--R 1 and E may be arranged in any positions in relation to each other and in which: R 0 represents the atoms required to complete a ring system comprising at least one aromatic or heteroaromatic ring; W represents a group which reduces the electron density in the ring at the position of E and is selected from the group consisting of a halogen atom, a cyano group, a nitro group, a nitroso group, a trifluoromethyl group, a quaternary ammonium group and an acyl group; m represents an integer of from 1 to 3; G represents a group from which R 1 can be split off under photographic development conditions; R 1 represents the residue of a diffusible photographically active compound; X represents an oxygen atom, a sulfur atom or the group --NR 3 --; R 2 represents hydrogen or a group which can be split off in alkaline medium, and E represents a reducible substituent selected from the group consisting of ##STR18## R 3 represents hydrogen, alkyl, aryl, a heterocyclic group or aralkyl, and the compound of formula I contains at least one substituent conferring diffusion resistance.
Claim 3
Dependent Claim
48 words
Photographic recording material as claimed in claim 1 in which in formula I R 0 represents the atoms required to complete a benzene ring; E is in position ortho or para to the group --XR 2 ; W is in position ortho or para to the substituent E.
Claim 4
Dependent Claim
80 words
Photographic recording material as claimed in claim 1, in which in formula I R 0 represents the atoms required to complete a benzene ring, W represents a halogen atom, an alkyl sulfonyl group or a nitro group in position ortho or para to the substituent E; m represents an integer of from 1 to 3; X represents --O--; R 2 represents an acyl group; E represents a nitro group in position ortho or para to the group --XR 2 .
Claim 5
Dependent Claim
20 words
Photographic material according to claim 1, characterized in that the photographically active residue is a dye or a dye precursor.
Claim 6
Dependent Claim
22 words
Photographic recording material as claimed in claim 1, in which the silver halide emulsion layer contains a negatively operating silver halide emulsion.
Claim 7
Dependent Claim
27 words
Photographic recording material as claimed in claim 1 containing an electron donor compound or electron donor precursor compound in effective contact with the compound of formula I.
Claim 8
Dependent Claim
112 words
Photographic recording material as claimed in claim 1 in the form of an integral color instant image unit comprising in the following order at least: (a) a light sensitive element containing at least one negatively functioning silver halide emulsion layer and in association with said silver halide emulsion layer a combination of a non-diffusing reducible compound of formula I in which R 1 represents the residue of a diffusible dye or dye precursor, and an ED compound or ED precursor compound; (b) an alkali permeable, light reflecting opaque layer; and (c) an image receiving layer for reception of the diffusible dye or dye precursor released from the reducible compound of formula I.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-04-25 | 1986-10-25 | 1987-04-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-04-25 | 1990-10-25 | 1991-04-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-04-25 | 1994-10-25 | 1995-04-26 | $7700.00 | Window Closed / Lapsed |