US4377710A
Expired / Lapsed
US
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Quaternized epichlorohydrin adducts of perfluoro substituted ethanols
Assignee: CHEMICAL Co
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Filing: 1982-03-08
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Granted: 1983-03-22
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Expires: 2002-03-08
Abstract
Abstract A composition represented by the formula: ##STR1## wherein x is an integer of from 2-12; y is an integer or fractional integer of from 1-20; Q is chosen from the group consisting of: (a) chloro, bromo, and iodo halogen radicals, and (b) a cationic nitrolgen radical represented by the formula: ##STR2## wherein R 1 , R 2 , and R 3 are aliphatic hydrocarbon radicals which contain from 1-30 carbon atoms and are further selected from the group consisting of alkyl, aryl, alkaryl and cyclo aliphatic radicals, with the proviso that when any of R 1 , R 2 , and R 3 exceed four carbon atoms, the other two hydrocarbon radicals are each chosen from the group consisting of ethyl and methyl hydrocarbon radicals; Z is a halogen anion chosen from the group consisting of chloride, bromide, and iodide with the further proviso that at least 50% of the radicals represented by Q are (b) radicals.
Inventors
- 👤 Virgil L. Seale
- 👤 James R. Stanford
- 👤 James E. Briscoe
- 👤 Glenn S. Penny
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 04:55
CPC Classifications
C; C07; C07C; C07C43/00; C07C43/02; C07C43/03; C07C43/04; C07C43/13; C07C43/137; C07C43/10; C07C43/11
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
156 words
A composition represented by the formula: ##STR5## wherein x is an integer of from 2-12; y is an integer or fractional integer of from 1-20; Q is chosen from the group consisting of: (a) chloro, bromo, and iodo halogen radicals, and (b) a cationic nitrogen radical represented by the formula: ##STR6## wherein R 1 , R 2 , and R 3 are hydrocarbon radicals which contain from 1-30 carbon atoms and are further selected from the group consisting of alkyl, aryl, alkaryl and cyclo aliphatic radicals, with the proviso that when any of R 1 , R 2 , and R 3 exceed four carbon atoms, the other two hydrocarbon radicals are each chosen from the group consisting of ethyl and methyl hydrocarbon radicals; Z is a halogen anion chosen from the group consisting of chloride, bromide, and iodide with the further proviso that at least 50% of the radicals represented by Q are (b) radicals.
Claim 2
Dependent Claim
156 words
A composition represented by the formula: ##STR5## wherein x is an integer of from 2-12; y is an integer or fractional integer of from 1-20; Q is chosen from the group consisting of: (a) chloro, bromo, and iodo halogen radicals, and (b) a cationic nitrogen radical represented by the formula: ##STR6## wherein R 1 , R 2 , and R 3 are hydrocarbon radicals which contain from 1-30 carbon atoms and are further selected from the group consisting of alkyl, aryl, alkaryl and cyclo aliphatic radicals, with the proviso that when any of R 1 , R 2 , and R 3 exceed four carbon atoms, the other two hydrocarbon radicals are each chosen from the group consisting of ethyl and methyl hydrocarbon radicals; Z is a halogen anion chosen from the group consisting of chloride, bromide, and iodide with the further proviso that at least 50% of the radicals represented by Q are (b) radicals.
Claim 3
Dependent Claim
34 words
The composition of claim 1 where x has an average value of from 6-8; and R 1 , R 2 , and R 3 are each methyl radicals; and Z represents the chloride anion.
Claim 4
Dependent Claim
14 words
The composition of claim 1 where y has the value of 1.5 to 2.5.
Claim 5
Dependent Claim
27 words
The composition of claim 3 wherein Q is at least 80% trimethyl amine cationic nitrogen radical, the remainder of Q being represented by the chloro halogen radical.
Claim 6
Dependent Claim
123 words
The composition of claim 1 wherein x is an integer of from 2-12; y is an integer or fractional integer of from 1-20; Q is a cationic nitrogen radical represented by: ##STR7## wherein R 1 , R 2 , and R 3 are aliphatic hydrocarbon radicals which contain from 1-30 carbon atoms and are further selected from the group consisting of alkyl, aryl, alkaryl, and cyclo aliphatic carbon radicals, with the proviso that when any of R 1 , R 2 , and R 3 exceed four carbon atoms, the other two hydrocarbon radicals are each chosen from the group consisting of ethyl and methyl hydrocarbon radicals; and Z is a halogen anion chosen from the group consisting of chloride, bromide, and iodide.
Claim 7
Dependent Claim
34 words
The composition of claim 5 wherein x has an average value of from 6-8; and R 1 , R 2 , and R 3 are each methyl radicals; and Z represents the chloride anion.
Claim 8
Dependent Claim
14 words
The composition of claim 6 wherein y has the value of 1.5 to 2.5.
Claim 9
Dependent Claim
42 words
The compositions of claims 1 and 5 wherein R 1 and R 2 are each chosen from the group consisting of methyl and ethyl hydrocarbon radical and R 3 is chosen from the group consisting of phenyl, cyclohexyl, and isopropyl hydrocarbon radicals.
References Cited (Backward Citations)
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US3496109A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-03-21 | 1986-09-20 | 1987-03-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-03-21 | 1990-09-20 | 1991-03-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-03-21 | 1994-09-20 | 1995-03-22 | $7700.00 | Window Closed / Lapsed |