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US4377066A Expired / Lapsed US ⏱️ 0.0 years remaining

Pollution-free pressurized fluidized bed combustion utilizing a high concentration of water vapor

Assignee: ENERTECH ENVIRONMENTAL Inc (DELAWARE C CORP)
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Filing: 1980-05-27
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Granted: 1983-03-22
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Expires: 2000-05-27
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Abstract

Abstract A continuous process for the combustion of solid fuels in a fluidized bed of solid particles under conditions such that flue gas is essentially free of dust and oxides of sulfur and nitrogen. Fuel is charged as an aqueous slurry and additional water condensed from the flue gas is recycled to the combustion zone. Combustion is promoted both by water vapor and alkali added with fuel slurry, while the alkali serves also to neutralize and remove sulfur in completely oxidized, or sulfate, form. Useful heat is recovered from the hot gases leaving the combustion zone and, in some cases, from the fluidized bed itself. Under the pressure of the system recovery of heat results in condensation of water which serves to scrub dust from the flue gas, slurry product ash and furnish recycle water, which controls reaction temperature as well as promoting the combustion.

Inventors

  • 👤 Norman L. Dickinson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:23
CPC Classifications
B; B01; B01D; B01D47/00; F; F01; F01K; F01K3/00; F01K3/18; F01K3/188; F23; F23C; F23C10/00; F23C10/16; F23J; F23J15/00; F23J15/006; F23K; F23K1/00; F23K1/02; Y; Y02; Y02E; Y02E20/00; Y02E20/16; Y02P; Y02P70/00; Y02P70/10

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 141 words
A continuous pressurized fluidized bed combustion process comprising charging an aqueous slurry of solid fuel particles and alkali in an amount at least the chemical equivalent of the sulfur content of the fuel as alkali sulfate, to a combustion zone comprising a bed of solid particles; fluidizing the bed with an upward velocity between 1 and 10 feet per second of a gas containing oxygen and at least 3 atmospheres partial pressure of water vapor measured at the outlet of the zone; maintaining the combustion zone at a temperature between 710 and 1600 degrees Fahrenheit; withdrawing gaseous products containing entrained solid matter from above the zone; cooling the gaseous products below their dewpoint at essentially combustion pressure by the indirect transfer of useful heat; and separating from uncondensed gaseous products an aqueous condensate carrying essentially all of the entrained solid matter.
Claim 2
Dependent Claim 141 words
A continuous pressurized fluidized bed combustion process comprising charging an aqueous slurry of solid fuel particles and alkali in an amount at least the chemical equivalent of the sulfur content of the fuel as alkali sulfate, to a combustion zone comprising a bed of solid particles; fluidizing the bed with an upward velocity between 1 and 10 feet per second of a gas containing oxygen and at least 3 atmospheres partial pressure of water vapor measured at the outlet of the zone; maintaining the combustion zone at a temperature between 710 and 1600 degrees Fahrenheit; withdrawing gaseous products containing entrained solid matter from above the zone; cooling the gaseous products below their dewpoint at essentially combustion pressure by the indirect transfer of useful heat; and separating from uncondensed gaseous products an aqueous condensate carrying essentially all of the entrained solid matter.
Claim 3
Dependent Claim 25 words
A process as in claim 1 in which the fluidized bed is comprised in part of inert particles other than ash, alkali and spent alkali.
Claim 4
Dependent Claim 73 words
A process as in claim 1 and comprising the additional step of passing the gaseous products containing entrained solid matter through a gas-solids separating device forming a powdered dry ash and cleaned gaseous products containing fine dust; cooling the cleaned gaseous producte below their dewpoint at essentially combustion pressure by the indirect transfer of useful heat; and separating from the uncondensed gaseous products an aqueous condensate carrying essentially all of the fine dust.
Claim 5
Dependent Claim 20 words
A process as in claim 3 in which the powdered dry ash is removed from the apparatus as a product.
Claim 6
Dependent Claim 34 words
A process as in claim 3 and comprising the additional step of mixing at least part of the aqueous condensate with the powdered dry ash at essentially combustion pressure to form an ash slurry.
Claim 7
Dependent Claim 40 words
A process as in claim 3 and comprising the additional step of further cooling the uncondensed gaseous products by the indirect transfer of useful heat, forming a wet flue gas and a second aqueous condensate essentially free of solid matter.
Claim 8
Dependent Claim 28 words
A process as in claim 3 and comprising the additional step of returning at least a portion of the aqueous condensate carrying fine dust to the fluidized bed.
Claim 9
Dependent Claim 24 words
A process as in claim 3 in which the temperature of the fluidized bed is regulated by means of the injection of water thereinto.
Claim 10
Dependent Claim 26 words
A process as in claim 3 in which the temperature of the fluidized bed is regulated by means of the indirect transfer therefrom of useful heat.
Claim 11
Dependent Claim 21 words
A process as in claim 3 and comprising the additional step of returning the powdered dry ash to the fluidized bed.
Claim 12
Dependent Claim 37 words
A process as in claim 10 and comprising the additional step of maintaining the inventory of solid particles in the fluidized bed essentially constant by withdrawing therefrom a portion of its contents as a dry solids product.
Claim 13
Dependent Claim 22 words
A process as in claim 3 and comprising the additional step of washing the uncondensed gaseous products by direct contact with water.
Claim 14
Dependent Claim 26 words
A process as in claim 12 and comprising the additional step of reheating the washed uncondensed gaseous products by indirect exchange with the cleaned gaseous products.
Claim 15
Dependent Claim 64 words
A process as in claim 12 in which the water used to wash the uncondensed gaseous products is cooled by the indirect transfer therefrom of useful heat so that, when recirculated to the washing step, it is capable of cooling the uncondensed gaseous products to a temperature at which their water vapor content is less than 12 volume percent, forming a dried flue gas.
Claim 16
Dependent Claim 84 words
A process as in claim 14 and comprising the recovery of potential energy in the dried flue gas by the additional steps of reheating the dried flue gas by indirect exchange with the cleaned gaseous products and expanding the heated flue gas through a gas turbine, one or more times, the reheat temperature being sufficiently high as to cause the turbines to yield at least as much mechanical energy as required to deliver the oxygen-containing gas to the lower part of the fluidized bed.
Claim 17
Dependent Claim 20 words
A process as in claim 12 and comprising the additional step of adding alkali to the recirculating stream of water.

References Cited (Backward Citations)

US2672012A Cited
US2718754A Cited
GB935658A Cited
US3972180A Cited
US4164846A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-03-21 1986-09-20 1987-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-03-21 1990-09-20 1991-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-03-21 1994-09-20 1995-03-22 $7700.00 Window Closed / Lapsed

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