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US4376732A Expired / Lapsed US ⏱️ 0.0 years remaining

Niobium or tantalum catalysts for the preparation of ethylenimine

Assignee: Dow Chemical Co
•
Filing: 1981-07-09
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Granted: 1983-03-15
•
Expires: 2001-07-09
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Abstract

Abstract An improved catalyst suitable for the dehydration of an alkanolamine in the vapor phase to produce an alkylenimine which catalyst contains an oxide of niobium or tantalum. Optionally an alkaline earth oxide is employed as a promoter. The catalyst is generally used on an inert low surface area support at a concentration of less than 5% of the tantalum or niobium oxide and less than 0.5% of the promoter oxide.

Inventors

  • 👤 Enrique G. Ramirez

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 18:38
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/16; B01J23/20

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 31 words
An improved process for dehydrating ethanolamine in the vapor phase to produce ethylenimine which comprises employing a supported catalyst of niobium or tantalum oxide together with an alkaline earth oxide promoter.
Claim 2
Dependent Claim 31 words
An improved process for dehydrating ethanolamine in the vapor phase to produce ethylenimine which comprises employing a supported catalyst of niobium or tantalum oxide together with an alkaline earth oxide promoter.
Claim 3
Dependent Claim 31 words
The process of claim 1 wherein the niobium or tantalum oxide is present at a concentration of from about 0.5 to about 5% based on total weight of catalyst and support.
Claim 4
Dependent Claim 16 words
The process of claim 2 wherein barium oxide is present as a promoter for the catalyst.
Claim 5
Dependent Claim 27 words
The process of claim 2 wherein the alkaline earth oxide promoter is present in amount of from 0.1 to 0.5% based on the niobium or tantalum oxide.

References Cited (Backward Citations)

US2441966A Cited
DE871149C Cited
US2694704A Cited
US3717628A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-03-14 1986-09-13 1987-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-03-14 1990-09-13 1991-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-03-14 1994-09-13 1995-03-15 $7700.00 Window Closed / Lapsed

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