US4376149A
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Silicone polymer compositions
Assignee: Wacker Chemical Corp
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Filing: 1981-07-10
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Granted: 1983-03-08
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Expires: 2001-07-10
Abstract
Abstract Silicone polymer compositions are prepared by mixing silylated polyethers with silanol terminated organopolysiloxanes in the presence or absence of solvents and/or emulsifiers. These silicone polymer compositions may be applied as a solution or as a dispersion to textile substrates to impart a soft silky coating thereon.
Inventors
- 👤 Eugene R. Martin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 13:43
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; D06M15/6436; C; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T442/00; Y10T442/20; Y10T442/2352
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
531 words
A composition for treating textile materials comprising a silanol terminated organopolysiloxane and a silylated polyether of the general formula ##STR16## in which at least one R is selected from the group consisting of an --NH radical, an ammonium radical and a radical selected from the group consisting of ##STR17## wherein the radicals are linked to the polyether through a group selected from the class consisting of an ester, amine, amide and ammonium radicals and the remaining R's are selected from the group consisting of hydroxyl, hydrocarbonoxy radicals having up to 18 carbon atoms and a radical of the formula ##STR18## R 1 is a divalent hydrocarbon radical selected from the group consisting of (--CH 2 ) y , --CH═CH-- and a cyclic radical selected from the group consisting of C 6 H 4 , C 6 H 8 , C 6 H 10 and C 10 H 6 ; A is a silicon containing radical selected from the group consisting of cationic and anionic radicals of the formula ##EQU3## and nonionic radicals of the formula ##EQU4## in which R 2 and R 3 are monovalent hydrocarbon radicals having from 1 to 18 carbon atoms, R 4 is an ionic radical linked to a silicon atom consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR19## R 5 is a nonionic divalent radical selected from the group consisting of R 6 and a radical consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of --NH--R.sup.6 --, --NHR.sup.6 --NR.sup.6 --, --NH--R.sup.6 --NHR.sup.6 --, ##STR20## with the proviso that when R is the radical ##STR21## then R.sup.5 is R.sup.6, wherein R.sup.6 is a radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical having up to 50 carbon atoms in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having up to 10 carbon atoms in which the unsatisfied valences of the R.sup.6 radical are linked to a silicon atom and the unsatisfied valences of A are satisfied by R and when A is a divalent radical, the ratio of A to R is 1:2 and when R is cationic, then A must be anionic and when R is anionic, then A must be cationic and when R is nonionic, then A must be nonionic, a is a number of from 0 to 4, b, c and d are each numbers of from 0 to 1 and the sum of b, c and d must be at least 1 and when b, c or d are 0, then R is selected from the group consisting of a hydroxyl, a hydrocarbonoxy radical and a radical of the formula ##STR22## e is a number of from 0 to 2, f is 0 or 1 and when f is 0, then R.sup.5 is a divalent hydrocarbonoxy radical linked to the silicon atom through a carbon-carbon bond, n is 2, 3 or 4, x is a number of at least 1 and up to 600 and y is a number of from 0 to 10.
Claim 2
Dependent Claim
531 words
A composition for treating textile materials comprising a silanol terminated organopolysiloxane and a silylated polyether of the general formula ##STR16## in which at least one R is selected from the group consisting of an --NH radical, an ammonium radical and a radical selected from the group consisting of ##STR17## wherein the radicals are linked to the polyether through a group selected from the class consisting of an ester, amine, amide and ammonium radicals and the remaining R's are selected from the group consisting of hydroxyl, hydrocarbonoxy radicals having up to 18 carbon atoms and a radical of the formula ##STR18## R 1 is a divalent hydrocarbon radical selected from the group consisting of (--CH 2 ) y , --CH═CH-- and a cyclic radical selected from the group consisting of C 6 H 4 , C 6 H 8 , C 6 H 10 and C 10 H 6 ; A is a silicon containing radical selected from the group consisting of cationic and anionic radicals of the formula ##EQU3## and nonionic radicals of the formula ##EQU4## in which R 2 and R 3 are monovalent hydrocarbon radicals having from 1 to 18 carbon atoms, R 4 is an ionic radical linked to a silicon atom consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR19## R 5 is a nonionic divalent radical selected from the group consisting of R 6 and a radical consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of --NH--R.sup.6 --, --NHR.sup.6 --NR.sup.6 --, --NH--R.sup.6 --NHR.sup.6 --, ##STR20## with the proviso that when R is the radical ##STR21## then R.sup.5 is R.sup.6, wherein R.sup.6 is a radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical having up to 50 carbon atoms in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having up to 10 carbon atoms in which the unsatisfied valences of the R.sup.6 radical are linked to a silicon atom and the unsatisfied valences of A are satisfied by R and when A is a divalent radical, the ratio of A to R is 1:2 and when R is cationic, then A must be anionic and when R is anionic, then A must be cationic and when R is nonionic, then A must be nonionic, a is a number of from 0 to 4, b, c and d are each numbers of from 0 to 1 and the sum of b, c and d must be at least 1 and when b, c or d are 0, then R is selected from the group consisting of a hydroxyl, a hydrocarbonoxy radical and a radical of the formula ##STR22## e is a number of from 0 to 2, f is 0 or 1 and when f is 0, then R.sup.5 is a divalent hydrocarbonoxy radical linked to the silicon atom through a carbon-carbon bond, n is 2, 3 or 4, x is a number of at least 1 and up to 600 and y is a number of from 0 to 10.
Claim 3
Dependent Claim
67 words
The composition of claim 1, wherein A is a radical of the formula ##STR23## in which R 2 and R 3 are each monovalent hydrocarbon radicals having from 1 to 18 carbon atoms, R 4 is an ionic radical linked to a silicon atom consisting of carbon, hydrogen, oxygen and nitrogen atmos which is selected from ##STR24## and e is a number of from 0 to 2.
Claim 4
Dependent Claim
64 words
The composition of claim 1, wherein A is a radical of the formula ##EQU5## in which R 3 is a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, R 4 is an ionic radical linked to a silicon atom consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from ##STR25## and e is a number of from 0 to 2.
Claim 5
Dependent Claim
155 words
The composition of claim 1, wherein A is a nonionic silicon containing radical of the formula ##STR26## in which R 2 and R 3 are each monovalent hydrocarbon radicals having from 1 to 18 carbon atoms, R 5 is a nonionic divalent radical selected from the group consisting of R 6 and a radical consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR27## with the proviso that when R is the radical ##STR28## then R 5 is R 6 , wherein R 6 is a radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical having up to 50 carbon atoms in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having up to 10 carbon atoms and e is a number of from 0 to 2.
Claim 6
Dependent Claim
149 words
The composition of claim 1, wherein A is a radical of the formula ##EQU6## in which R 3 is a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, R 5 is a nonionic divalent radical selected from the group consisting of R 6 and a radical consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR29## with the proviso that when R is the radical ##STR30## then R 5 is R 6 , wherein R 6 is a radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical having up to 50 carbon atoms in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having up to 10 carbon atoms and e is a number of from 0 to 2.
Claim 7
Dependent Claim
20 words
The composition of claim 1, wherein R is an ammonium ion and A is a group of the formula ##STR31##
Claim 8
Dependent Claim
20 words
The composition of claim 1, wherein R is an ammonium ion and A is a group of the formula ##STR32##
Claim 9
Dependent Claim
53 words
The composition of claim 1, wherein the silanol terminated organopolysiloxane is present in an amount of from 0.25 to 99.75 percent by weight and the silylated polyether is present in an amount of from 99.75 to 0.25 percent by weight based on the weight of the silanol terminated organopolysiloxane and the silylated polyether.
Claim 10
Dependent Claim
27 words
The composition of claim 1, wherein the silanol terminated organopolysiloxane is a silanol terminated diorganopolysiloxane having a viscosity of from 15 to 1,000,000 cs. at 25° C.
Claim 11
Dependent Claim
530 words
A process for preparing a composition for treating textile materials which comprises reacting a silanol terminated organopolysiloxane with a silylated polyether having the general formula ##STR33## in which at least one R is selected from the group consisting of an --NH radical, an ammonium radical and a radical selected from the group consisting of ##STR34## wherein the radicals are linked to the polyether through a group selected from the class consisting of an ester, amine, amide and ammonium radicals and the remaining R's are selected from the group consisting of hydroxyl, hydrocarbonoxy radicals having up to 18 carbon atoms and a radical of the formula ##STR35## R 1 is a divalent hydrocarbon radical selected from the group consisting of (--CH 2 ) y , --CH═CH-- and a cyclic radical selected from the group consisting of C 6 H 4 , C 6 H 8 , C 6 H 10 and C 10 H 6 ; A is a silicon containing radical selected from the group consisting of cationic and anionic radicals of the formula ##EQU7## and nonionic radicals of the formula ##EQU8## in which R 2 and R 3 are monovalent hydrocarbon radicals having from 1 to 18 carbon atoms, R 4 is an ionic radical linked to a silicon atom consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR36## R 5 is a nonionic radical consisting of R 6 and a radical consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR37## with the proviso that when R is the radical ##STR38## then R 5 is R 6 , wherein R 6 is a radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical having up to 50 carbon atoms in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having up to 10 carbon atoms in which the unsatisfied valences of the R 6 radical are linked to a silicon atom and the unsatisfied valences of A are satisfied by R and when A is a divalent radical, the ratio of A to R is 1:2 and when R is cationic, then A must be anionic and when R is anionic, then A must be cationic and when R is nonionic, then A must be nonionic, a is a number of from 0 to 4, b, c and d are each numbers of from 0 to 1 and the sum of b, c and d must be at least 1 and when b, c or d are 0, then R is selected from the group consisting of a hydroxyl, a hydrocarbonoxy radical and a radical of the formula ##STR39## e is a number of from 0 to 2, f is 0 or 1 and when f is 0, then R 5 is a divalent hydrocarbonoxy radical linked to the silicon atom through a carbon-carbon bond, n is 2, 3 or 4, x is a number of at least 1 and up to 600 and y is a number of from 0 to 10.
Claim 12
Dependent Claim
530 words
A process for preparing a composition for treating textile materials which comprises reacting a silanol terminated organopolysiloxane with a silylated polyether having the general formula ##STR33## in which at least one R is selected from the group consisting of an --NH radical, an ammonium radical and a radical selected from the group consisting of ##STR34## wherein the radicals are linked to the polyether through a group selected from the class consisting of an ester, amine, amide and ammonium radicals and the remaining R's are selected from the group consisting of hydroxyl, hydrocarbonoxy radicals having up to 18 carbon atoms and a radical of the formula ##STR35## R 1 is a divalent hydrocarbon radical selected from the group consisting of (--CH 2 ) y , --CH═CH-- and a cyclic radical selected from the group consisting of C 6 H 4 , C 6 H 8 , C 6 H 10 and C 10 H 6 ; A is a silicon containing radical selected from the group consisting of cationic and anionic radicals of the formula ##EQU7## and nonionic radicals of the formula ##EQU8## in which R 2 and R 3 are monovalent hydrocarbon radicals having from 1 to 18 carbon atoms, R 4 is an ionic radical linked to a silicon atom consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR36## R 5 is a nonionic radical consisting of R 6 and a radical consisting of carbon, hydrogen, oxygen and nitrogen atoms which is selected from the group consisting of ##STR37## with the proviso that when R is the radical ##STR38## then R 5 is R 6 , wherein R 6 is a radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical having up to 50 carbon atoms in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having up to 10 carbon atoms in which the unsatisfied valences of the R 6 radical are linked to a silicon atom and the unsatisfied valences of A are satisfied by R and when A is a divalent radical, the ratio of A to R is 1:2 and when R is cationic, then A must be anionic and when R is anionic, then A must be cationic and when R is nonionic, then A must be nonionic, a is a number of from 0 to 4, b, c and d are each numbers of from 0 to 1 and the sum of b, c and d must be at least 1 and when b, c or d are 0, then R is selected from the group consisting of a hydroxyl, a hydrocarbonoxy radical and a radical of the formula ##STR39## e is a number of from 0 to 2, f is 0 or 1 and when f is 0, then R 5 is a divalent hydrocarbonoxy radical linked to the silicon atom through a carbon-carbon bond, n is 2, 3 or 4, x is a number of at least 1 and up to 600 and y is a number of from 0 to 10.
Claim 13
Dependent Claim
20 words
The process of claim 10, wherein the silanol terminated organopolysiloxane and the silylated polyether are heated to an elevated temperature.
Claim 14
Dependent Claim
9 words
The composition obtained from the process of claim 11.
Claim 15
Dependent Claim
29 words
A process for treating a textile material which comprises coating a textile material with the composition of claim 1 and thereafter curing the coated material at an elevated temperature.
Claim 16
Dependent Claim
22 words
The process of claim 13, wherein the composition of claim 1 is dissolved in a diluent prior to coating the textile material.
Claim 17
Dependent Claim
40 words
The process of claim 14, wherein the composition of claim 1 is dissolved in a diluent to form a solution containing from 0.25 to 99.75 percent by weight of the composition based on the weight of the composition and diluent.
Claim 18
Dependent Claim
10 words
The process of claim 14, wherein the diluent is water.
Claim 19
Dependent Claim
17 words
The process of claim 13, wherein the textile material is coated with the composition of claim 12.
Claim 20
Dependent Claim
22 words
The process of claim 17, wherein the composition of claim 12 is dissolved in a diluent prior to coating the textile material.
Claim 21
Dependent Claim
12 words
The process of claim 13, wherein the textile material is a polyester.
Claim 22
Dependent Claim
12 words
The process of claim 17, wherein the textile material is a polyester.
Claim 23
Dependent Claim
7 words
The coated textile material of claim 13.
Claim 24
Dependent Claim
7 words
The coated textile material of claim 17.
Claim 25
Dependent Claim
7 words
The coated textile material of claim 19.
Claim 26
Dependent Claim
7 words
The coated textile material of claim 20.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-03-07 | 1986-09-06 | 1987-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-03-07 | 1990-09-06 | 1991-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-03-07 | 1994-09-06 | 1995-03-08 | $7700.00 | Window Closed / Lapsed |