Polyamide and functional fluid containing same

Claim 2

A polyamide derivative of a polyoxalkylene diamine wherein said polyamide has (a) a single terminal carboxylic acid group and a single terminal amine group in the same molecule, and (b) a degree of polymerization of from 2 to 10 or the salt of the polyamide which is the salt of (c) the terminal carboxylic acid group, (d) the terminal amine group, or (e) both the terminal carboxylic acid and terminal amine groups, wherein the polyamide has the following formula ##STR4## where R is a divalent aliphatic, aromatic, arylaliphatic, alkylaromatic, cycloaliphatic, heteroaliphatic having oxygen or sulfur heterochain atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and from 5 to 6 ring atoms or bicyclic radical or the halogenated derivatives of said divalent radical, R' is a divalent polyoxyalkylene homopolymer or copolymer radical and n is 2 to 10, said polyamide and its salts having an average molecular weight not greater than about 50,000.

Claim 3

A polyamide according to claim 1 the salt of the polyamide which is the salt of the terminal carboxylic acid group.

Claim 4

A polyamide or salt thereof according to claim 1 wherein R is a divalent aliphatic hydrocarbon radical having from 2 to 12 carbon atoms.

Claim 5

A polyamide or salt thereof according to claim 1 wherein R is a phenylene or naphthylene radical.

Claim 6

A polyamide or salt thereof according to claim 1 wherein R is a divalent C 4 to C 6 cycloaliphatic radical.

Claim 7

A polyamide or salt thereof according to claim 1 wherein R is a divalent heteroaliphatic radical having one to two oxygen or sulfur heterochain atoms and from 2 to 6 carbon atoms.

Claim 8

A polyamide or salt thereof according to claim 1 wherein R is a divalent heterocyclic radical having one to two oxygen, sulfur or nitrogen hetero ring atoms and from 5 to 6 ring atoms.

Claim 9

A polyamide or salt thereof according to claim 1 wherein R is a divalent radical residue obtained by the removal of both carboxylic acid groups from a dimerized ethylenically unsaturated C 8 to C 26 fatty acid.

Claim 10

A polyamide or salt thereof according to claim 3, 4, 5, 6, 7 or 8 wherein R' is a divalent polyoxyalkylene homopolymer radical having an average molecular weight in the range from 72 to 4000.

Claim 11

A polyamide or salt thereof according to claim 3, 4, 5, 6, 7 or 8 wherein R' is a divalent polyoxyalkylene copolymer radical having an average molecular weight in the range from 86 to 4000.

Claim 12

The alkali metal, ammonium or organic amine salt of the carboxylic acid group of the polyamide according to claim 8.

Claim 13

The organic amine salt according to claim 11 wherein the organic amine is an alkanol amine.

Claim 14

The salt according to claim 12 wherein the alkanolamine is a mono, di or ti (C 2 to C 4 alkanol) amine.

Claim 15

The salt formed by the terminal amine group of the polyamide according to claim 1.

Claim 16

An aqueous functional fluid composition comprising (a) water, and (b) a lubricant compound selected from the group consisting of a water soluble or dispersible polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization from 2 to 10, a water soluble or dispersible salt of a water soluble or dispersible polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization of from 2 to 10 or a water soluble or dispersible salt of a water insoluble polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization of from 2 to 10, wherein the polyamide derivative has the formula ##STR5## where R is a divalent aliphatic, aromatic, arylaliphatic, alkylaromatic, cycloaliphatic, heteroaliphatic having oxygen or sulfur heterochain atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and 5 to 6 ring atoms or bicyclic radical or the halogenated derivative of said radical, R' is a divalent polyoxyalkylene homopolymer or copolymer radical and n is 2 to 10, said polyamide and water soluble or dispersible salts thereof having an average molecular weight of not greater than 50,000, the water soluble or dispersible salt being formed by the terminal carboxylic acid group, terminal amine group or both the terminal carboxylic acid and terminal amine groups of the polyamide.

Claim 17

An aqueous functional fluid composition comprising (a) water, and (b) a lubricant compound selected from the group consisting of a water soluble or dispersible polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization from 2 to 10, a water soluble or dispersible salt of a water soluble or dispersible polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization of from 2 to 10 or a water soluble or dispersible salt of a water insoluble polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization of from 2 to 10, wherein the polyamide derivative has the formula ##STR5## where R is a divalent aliphatic, aromatic, arylaliphatic, alkylaromatic, cycloaliphatic, heteroaliphatic having oxygen or sulfur heterochain atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and 5 to 6 ring atoms or bicyclic radical or the halogenated derivative of said radical, R' is a divalent polyoxyalkylene homopolymer or copolymer radical and n is 2 to 10, said polyamide and water soluble or dispersible salts thereof having an average molecular weight of not greater than 50,000, the water soluble or dispersible salt being formed by the terminal carboxylic acid group, terminal amine group or both the terminal carboxylic acid and terminal amine groups of the polyamide.

Claim 18

An aqueous functional fluid composition according to claim 15 wherein the water soluble or dispersible salt of the water soluble or dispersible polyamide is a salt of the terminal carboxylic acid group of the polyamide and the water soluble or dispersible salt of the water insoluble polyamide is the salt of the terminal carboxylic acid group of the polyamide.

Claim 19

An aqueous functional fluid composition according to claim 15 wherein R is a C 2 to C 12 alkylene, C 2 to C 10 alkenylene, phenylene, C 4 to C 6 cycloaliphatic, mono to di(C 1 to C 4 alkyl) substituted phenylene, phenyl substituted C 2 to C 10 alkylene, phenylene di(C 1 to C 3 alkylene), heteroaliphatic having one to two oxygen or sulfur heterochain atoms and 2 to 10 carbon atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and from 5 to 6 atoms in the ring divalent radical or a divalent radical residue obtained by removal of both carboxylic acid groups from a dimerized ethylenically unsaturated C 8 to C 26 fatty acid.

Claim 20

An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is the water soluble or dispersible polyamide.

Claim 21

An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is the water soluble or dispersible salt of the water soluble or dispersible polyamide.

Claim 22

An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is the water soluble or dispersible salt of the water insoluble polyamide.

Claim 23

An aqueous functional fluid composition according to claim 19 or 20 wherein the lubricant is the salt of the polyamide and said salt is a salt of the terminal carboxylic acid group of the polyamide.

Claim 24

An aqueous functional fluid composition according to claim 21 wherein the salt is an alkali metal, ammonium or organic amine salt.

Claim 25

An aqueous functional fluid composition according to claim 22 wherein the organic amine is a mono, di or tri (alkanol) amine having 2 to 4 carbon atoms in the alkanol group.

Claim 26

An aqueous functional fluid composition according to claim 23 wherein the organic amine is the trialkanolamine.

Claim 27

An aqueous functional fluid composition in accordance with claim 18, 19 or 20 wherein R' is a divalent polyoxyalkylene homopolymer radical having an average molecular weight in the range of from 72 to 4000.

Claim 28

An aqueous functional fluid composition according to claim 18, 19 or 20 wherein R' is a divalent polyoxyalkylene copolymer radical having an average molecular weight of from 86 to 4000.

Claim 29

An aqueous functional fluid composition according to claim 23 wherein R is a C 2 to C 10 alkylene or C 2 to C 10 alkenylene radical.

Claim 30

An aqueous functional fluid composition according to claim 23 wherein R is a phenylene radical.

Claim 31

An aqueous functional fluid composition according to claim 23 wherein R is a divalent radical residue obtained by removal of both carboxylic acid groups from a dimerized ethylenically unsaturated C 8 to C 26 fatty acid.

Claim 32

An aqueous functional fluid composition according to claim 19 or 20 wherein the salt is a salt of the terminal amine group of the polyamide.

Claim 33

An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is present in an amount in the range of from 0.01% to 99% by weight based on the total weight of the composition.

Claim 34

An aqueous functional fluid composition according to claim 31 wherein the amount of lubricant compound is in the range of from 0.01% to 20% by weight.

Claim 35

A metal working process comprising the step of working metal in the presence of the aqueous functional fluid composition according to claim 15.