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US4372933A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of isocyanic acid

Assignee: Ashland LLC
•
Filing: 1982-04-29
•
Granted: 1983-02-08
•
Expires: 2002-04-29
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Abstract

Abstract Isocyanic acid is formed directly from nitric oxide, carbon monoxide and hydrogen by contacting a supported iridium or rhodium metal catalyst at an elevated temperature with a feed stream of said reactants.

Inventors

  • 👤 Jai H. Kyung
  • 👤 Joseph G. Holehouse

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:58
CPC Classifications
C; C01; C01C; C01C3/00; C01C3/14

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 89 words
A process for preparing isocyanic acid which comprises reacting a mixture of nitric oxide, carbon monoxide and hydrogen at a temperature of from about 200° to 400° C. in the presence of iridium or rhodium metal catalyst supported on a particulate carrier selected from the group consisting of silica, γ-alumina, zirconium oxide and silicon carbide, said carrier further characterized in having a surface area, expressed as M 2 /g, of not in excess of one, the contact time between said mixture and said catalyst being less than 1 second.
Claim 2
Dependent Claim 89 words
A process for preparing isocyanic acid which comprises reacting a mixture of nitric oxide, carbon monoxide and hydrogen at a temperature of from about 200° to 400° C. in the presence of iridium or rhodium metal catalyst supported on a particulate carrier selected from the group consisting of silica, γ-alumina, zirconium oxide and silicon carbide, said carrier further characterized in having a surface area, expressed as M 2 /g, of not in excess of one, the contact time between said mixture and said catalyst being less than 1 second.
Claim 3
Dependent Claim 13 words
The process in accordance with claim 1 wherein said particulate carrier is silica.
Claim 4
Dependent Claim 13 words
The process in accordance with claim 1 wherein said particulate carrier is γ-alumina.
Claim 5
Dependent Claim 14 words
The process in accordance with claim 1 wherein said particulate carrier is zirconium oxide.
Claim 6
Dependent Claim 14 words
The process in accordance with claim 1 wherein said particulate carrier is silicon carbide.
Claim 7
Dependent Claim 17 words
The process in accordance with claim 2, 3, 4 or 5 wherein the catalyst metal is iridium.
Claim 8
Dependent Claim 17 words
The process in accordance with claim 2, 3, 4 or 5 wherein the catalyst metal is rhodium.

References Cited (Backward Citations)

US4174377A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-02-07 1986-08-09 1987-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-02-07 1990-08-09 1991-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-02-07 1994-08-09 1995-02-08 $7700.00 Window Closed / Lapsed

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