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US4372882A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent composition containing low level of substituted polyamines

Assignee: Procter and Gamble Co
•
Filing: 1981-06-16
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Granted: 1983-02-08
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Expires: 2001-06-16
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Abstract

Abstract Detergent compositions containing low levels of substituted polyamines are disclosed. The polyamines are substituted by one long chain alkyl or alkenyl group and by at least two alkylene oxide radicals attached to different nitrogens. Preferred compositions produce a laundry liquor pH in the range from 8.5-12.0; and frequently contain water-soluble or water-insoluble detergent builders. These compositions exhibit a broad range of textile treatment benefits particularly enhanced soil release and cleaning properties.

Inventors

  • 👤 Robertus J. C. Koster
  • 👤 Volker Six
  • 👤 Peter Hale

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 04:46
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/0036; C11D1/00; C11D1/38; C11D1/40; C11D3/16; C11D3/26; C11D3/30

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 195 words
A method for preparing a granular detergent composition of enhanced soil release and cleaning properties, said composition comprising from about 2% to about 60% of a surface-active agent selected from the group consisting of anionic, nonionic, zwitterionic, and ampholytic detergents and mixtures thereof, and from 0.1% to 1.2% by weight of a polyamine having the formula ##STR3## wherein R is an alkyl or alkenyl group having 10 to 22 carbon atoms, the R 1 's, which are identical or different, are ethylene oxide or propylene oxide, R 2 is hydrogen, C 1 -C 4 alkyl or (R 1 ) y , where x, y, and z are numbers such that the sum (x+y+z) is in the range from 2 to about 25, n is a number from 1 to about 6, and m is a number from 1 to about 9, whereby a 1% aqueous solution of the composition has an alkaline pH (20° C.), said method comprising the steps of (a) spray drying a slurry including the surface-active agent and not the polyamine to produce a base powder, (b) spraying polyamine free of other detergent active ingredients onto a composition comprising the base powder.
Claim 2
Independent Claim 195 words
A method for preparing a granular detergent composition of enhanced soil release and cleaning properties, said composition comprising from about 2% to about 60% of a surface-active agent selected from the group consisting of anionic, nonionic, zwitterionic, and ampholytic detergents and mixtures thereof, and from 0.1% to 1.2% by weight of a polyamine having the formula ##STR3## wherein R is an alkyl or alkenyl group having 10 to 22 carbon atoms, the R 1 's, which are identical or different, are ethylene oxide or propylene oxide, R 2 is hydrogen, C 1 -C 4 alkyl or (R 1 ) y , where x, y, and z are numbers such that the sum (x+y+z) is in the range from 2 to about 25, n is a number from 1 to about 6, and m is a number from 1 to about 9, whereby a 1% aqueous solution of the composition has an alkaline pH (20° C.), said method comprising the steps of (a) spray drying a slurry including the surface-active agent and not the polyamine to produce a base powder, (b) spraying polyamine free of other detergent active ingredients onto a composition comprising the base powder.
Claim 3
Dependent Claim 75 words
A method as recited in claim 1, wherein the polyamine has the formula as set forth in claim 1 wherein R is hydrogenated C 16-18 alkyl, R 1 is ethylene oxide, R 2 is ethylene oxide, n is 3, m is 1 or 2 and x, y, and z are each at least 1 and their sum is from 3 to 12, and is present in the composition in a level from 0.25% to 0.75%.
Claim 4
Dependent Claim 9 words
The product produced by the process of claim 2.

References Cited (Backward Citations)

US3494870A Cited
GB1356827A Cited
US3897347A Cited
US4065257A Cited
DE2226871A1 Cited
GB1541688A Cited
US4179393A Cited
US4264480A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-02-07 1986-08-09 1987-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-02-07 1990-08-09 1991-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-02-07 1994-08-09 1995-02-08 $7700.00 Window Closed / Lapsed

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