← Back to Patent Explorer
US4369304A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable resin composition of (1) polyfunctional cyanate ester, (2) acrylic or methacrylic ester and (3) maleimide

Assignee: Mitsubishi Gas Chemical Co Inc
•
Filing: 1980-08-05
•
Granted: 1983-01-18
•
Expires: 2000-08-05
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A curable resin composition comprising a mixture and/or a preliminary reaction product of (a) polyfunctional cyanate ester, prepolymer of the cyanate ester, or coprepolymer of the cyanate ester and an amine, (b) acrylic esters, methacrylic esters, prepolymers of acrylic esters, prepolymers methacrylic esters, coprepolymers of acrylic esters and methacrylic esters and mixtures thereof, and (c) a polyfunctional maleimide, prepolymer of the maleimide or coprepolymer of the maleimide and an amine are disclosed. Cured resin having excellent impact-resistance, adhesive power, heat-resistance and chemical-resistance can be prepared from the compositions.

Inventors

  • 👤 Morio Gaku
  • 👤 Nobuyuki Ikeguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 23:20
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G73/00; C08G73/06; C08G73/10; C08G73/12; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31721

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 291 words
A curable resin composition comprising: (a) at least one cyanate ester compound selected from the group consisting of: (1) of polyfunctional aromatic cyanate ester monomer having the formula: R--O--C.tbd.N).sub.m wherein m is 2 to 5 and R is an aromatic organic group, the cyanate groups being bonded to an aromatic ring of said aromatic organic group, (2) a homoprepolymer of one or more polyfunctional aromatic cyanate ester monomers of (1), and (3) a coprepolymer of (1) and an amine; and (b) at least one acrylic ester or methacrylic ester compound, said acrylic ester or methacrylic ester being represented by the formula ##STR6## wherein X is hydrogen or methyl, and R is a straight or branched chain cycloalkyl having 3 to 12 carbon atoms, an aromatic hydrocarbon having 6 to 16 carbon atoms, a straight or branched chain halogen-substituted cycloalkyl having 3 to 12 carbon atoms, or a halogen-substituted aromatic hydrocarbon having 6 to 16 carbon atoms, said compound being selected from the group consisting of the acrylic esters, homoprepolymers of acrylic esters, homoprepolymers of methacrylic esters, coprepolymers of acrylic esters and methacrylic esters and mixtures thereof; and (c) at least one compound selected from the group consisting of: (1) a polyfunctional maleimide, (2) a homoprepolymer of one or more polyfunctional maleimides, and (3) a coprepolymer of (1) and an amine, said composition including a mixture of components (a), (b) and (c), a preliminary reaction product of components (a), (b) and (c), the combination of said mixture and said preliminary reaction product, the combination of (a) and the preliminary reaction product of (b) and (c), the combination of (b) and the preliminary reaction product of (a) and (c), or the combination of (c) and the preliminary reaction product of (a) and (b).
Claim 2
Dependent Claim 291 words
A curable resin composition comprising: (a) at least one cyanate ester compound selected from the group consisting of: (1) of polyfunctional aromatic cyanate ester monomer having the formula: R--O--C.tbd.N).sub.m wherein m is 2 to 5 and R is an aromatic organic group, the cyanate groups being bonded to an aromatic ring of said aromatic organic group, (2) a homoprepolymer of one or more polyfunctional aromatic cyanate ester monomers of (1), and (3) a coprepolymer of (1) and an amine; and (b) at least one acrylic ester or methacrylic ester compound, said acrylic ester or methacrylic ester being represented by the formula ##STR6## wherein X is hydrogen or methyl, and R is a straight or branched chain cycloalkyl having 3 to 12 carbon atoms, an aromatic hydrocarbon having 6 to 16 carbon atoms, a straight or branched chain halogen-substituted cycloalkyl having 3 to 12 carbon atoms, or a halogen-substituted aromatic hydrocarbon having 6 to 16 carbon atoms, said compound being selected from the group consisting of the acrylic esters, homoprepolymers of acrylic esters, homoprepolymers of methacrylic esters, coprepolymers of acrylic esters and methacrylic esters and mixtures thereof; and (c) at least one compound selected from the group consisting of: (1) a polyfunctional maleimide, (2) a homoprepolymer of one or more polyfunctional maleimides, and (3) a coprepolymer of (1) and an amine, said composition including a mixture of components (a), (b) and (c), a preliminary reaction product of components (a), (b) and (c), the combination of said mixture and said preliminary reaction product, the combination of (a) and the preliminary reaction product of (b) and (c), the combination of (b) and the preliminary reaction product of (a) and (c), or the combination of (c) and the preliminary reaction product of (a) and (b).
Claim 3
Dependent Claim 68 words
The composition as defined in claim 1 wherein the cyanate ester is selected from the group consisting of 1,3-, or 1,4-dicyanatobenzene; 1,3,5-tricyanatobenzene; 1,3-, 1,4-, 1,6-, 1,8-, 2,6- or 2,7-dicyanatonaphthalene; 1,3,6-tricyanatonaphthalene; 4,4'-dicyanatobiphenyl; bis(4-cyanatophenyl)methane; 2,2-bis(4-cyanatophenyl)propane, 2,2-bis(3,5-dichloro-4-cyanatophenyl)propane, 2,2-bis(3,5-dibromo-4-dicyanatophenyl)propane; bis(4-cyanatophenyl)ether; bis(4-cyanatophenyl)thioether; bis(4-cyanatophenyl)sulfone; tris(4-cyanatophenyl)phosphite; tris(4-cyanatophenyl)phosphate; bis(3-chloro-4-cyanatophenyl)methane; cyanated novolak produced by reacting a novolak with cyanogen halide, cyanated bisphenol polycarbonate oligomer produced by reacting a bishpenol polycarbonate oligomer with cyanogen halide; and mixtures thereof.
Claim 4
Dependent Claim 27 words
The composition as defined in claim 1 wherein the ratio by weight of components (a)+(c) to component (b) is in the range of from 99:1 to 1:99.

References Cited (Backward Citations)

US3553244A Cited
US3740348A Cited
US3755402A Cited
GB1060933A Cited
US3448079A Cited
US3562214A Cited
US4110364A Cited
US4022755A Cited
US4026913A Cited
US4330669A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-17 1986-07-19 1987-01-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-17 1990-07-19 1991-01-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-17 1994-07-19 1995-01-18 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag