US4369048A
Expired / Lapsed
US
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Method for treating gaseous effluents emitted from a nuclear reactor
Assignee: Individual
•
Filing: 1980-01-28
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Granted: 1983-01-18
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Expires: 2000-01-28
Abstract
Abstract A method is disclosed herein for treating the gaseous effluents emitted from a nuclear reactor, said method being adaptable for treating either gaseous effluents produced during normal reactor operations or combustible and fission product gases released as the result of a nuclear reactor system failure. The treatment comprises sequential direction of the gaseous mixture through a multiplicity of adsorbent beds, each of said beds being preferentially adsorptive towards at least one component of said gaseous mixture, whereby to effect the desired separation by substantially either thermal-swing, cryogenic, or rapid cycle adsorption techniques.
Inventors
- 👤 Dallas T. Pence
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 12:25
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01D53/04; B01D53/047; B01D53/0473; B01D53/0462; C; C01; C01B; C01B23/00; C01B3/00; C01B3/50; C01B3/56; G; G21; G21F; G21F9/00; G21F9/02; B01D2253/00; B01D2253/10; B01D2253/106; B01D2253/108; B01D2257/00; B01D2257/10; B01D2257/104; B01D2257/108; B01D2257/11; B01D2257/20; B01D2257/202; B01D2257/50; B01D2257/504; B01D2257/80; B01D2259/00; B01D2259/40; B01D2259/40083; B01D2259/40086; B01D2259/40088; B01D2259/4009; B01D2259/41; B01D2259/416; B01D2259/45; B01D2259/4525; B01D2259/4583; B01D53/0407; B01D53/0423; C01B2203/00; C01B2203/04; C01B2203/042; C01B2203/043; C01B2203/0465; C01B2203/0475; C01B2203/0495; Y; Y02; Y02C; Y02C20/00; Y02C20/40; Y02P; Y02P20/00; Y02P20/151; Y10; Y10S; Y10S55/00; Y10S55/09; Y10S62/00; Y10S62/923; Y10S62/925
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
75 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising hydrogen in gaseous admixture with krypton and xenon, a method for separating the hydrogen component of said gaseous effluent, comprising the step of directing said effluent through a column having absorbent material disposed therethrough and while maintaining said effluent at no greater than about ambient temperature and at about ambient pressure, said absorbent material comprising a synthetic mordenite zeolite.
Claim 2
Dependent Claim
75 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising hydrogen in gaseous admixture with krypton and xenon, a method for separating the hydrogen component of said gaseous effluent, comprising the step of directing said effluent through a column having absorbent material disposed therethrough and while maintaining said effluent at no greater than about ambient temperature and at about ambient pressure, said absorbent material comprising a synthetic mordenite zeolite.
Claim 3
Dependent Claim
27 words
A method as set forth in claim 1 wherein said effluent further comprises oxygen whereby to effect the simultaneous separation from said effluent of hydrogen and oxygen.
Claim 4
Dependent Claim
74 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising oxygen in gaseous admixture with krypton and xenon, a method for separating the oxygen component of said gaseous effluent, comprising the step of directing said effluent through a column having absorbent material disposed therethrough and while maintaining said effluent at not greater than about ambient temperature and at about ambient pressure, said adsorbent comprising a synthetic mordenite zeolite.
Claim 5
Dependent Claim
74 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising oxygen in gaseous admixture with krypton and xenon, a method for separating the oxygen component of said gaseous effluent, comprising the step of directing said effluent through a column having absorbent material disposed therethrough and while maintaining said effluent at not greater than about ambient temperature and at about ambient pressure, said adsorbent comprising a synthetic mordenite zeolite.
Claim 6
Dependent Claim
17 words
A method as set forth in claim 3 wherein said adsorbent material comprises hydrogen-form synthetic mordenite zeolite.
Claim 7
Independent Claim
179 words
A method for treating gaseous effluents emitted from a nuclear reactor, comprising sequentially: (a) directing said effluents through an adsorbent bed adsorptive to water vapor and carbon dioxide, but not to xenon and krypton, forward purging said bed with purge gas in the direction of effluents flow, raising the temperature of said bed sufficiently to desorb the absorbed water vapor and carbon dioxide, and back purging said bed with heated purge gas whereby to remove from the bed the desorbed water vapor and carbon dioxide; (b) removing iodine from the resulting water-and-carbon dioxide-free effluent; and (c) directing the resulting effluent at not greater than about ambient temperature and at about ambient pressure through an absorbent bed comprising synthetic mordenite zeolite having an affinity for absorbing xenon and krypton which is greater than its affinity for adsorbing hydrogen and oxygen, forward purging said bed with purge gas in the direction of effluent flow to remove residual hydrogen and oxygen from said bed, and then back purging said bed with purge gas whereby to remove xenon and krypton from said bed.
Claim 8
Independent Claim
179 words
A method for treating gaseous effluents emitted from a nuclear reactor, comprising sequentially: (a) directing said effluents through an adsorbent bed adsorptive to water vapor and carbon dioxide, but not to xenon and krypton, forward purging said bed with purge gas in the direction of effluents flow, raising the temperature of said bed sufficiently to desorb the absorbed water vapor and carbon dioxide, and back purging said bed with heated purge gas whereby to remove from the bed the desorbed water vapor and carbon dioxide; (b) removing iodine from the resulting water-and-carbon dioxide-free effluent; and (c) directing the resulting effluent at not greater than about ambient temperature and at about ambient pressure through an absorbent bed comprising synthetic mordenite zeolite having an affinity for absorbing xenon and krypton which is greater than its affinity for adsorbing hydrogen and oxygen, forward purging said bed with purge gas in the direction of effluent flow to remove residual hydrogen and oxygen from said bed, and then back purging said bed with purge gas whereby to remove xenon and krypton from said bed.
Claim 9
Dependent Claim
11 words
The method of claim 5 wherein the purge gas is nitrogen.
Claim 10
Dependent Claim
34 words
The method of claim 5 which includes the additional step of directing the effluent resulting from step (c) through an adsorbent bed which comprises silver-exchanged mordenite zeolite whereby to adsorb xenon and krypton thereon.
Claim 11
Dependent Claim
65 words
The method of claim 5 containing the additional steps of directing the effluent from step (c) to a second adsorbent bed comprising synthetic mordenite zeolite whereby to concentrate the xenon and krypton thereon, then removing the xenon and krypton therefrom, and then directing that resulting effluent to an adsorbent bed comprising silver-exchanged synthetic mordenite zeolite, said additional steps being carried out a substantially ambient pressure.
Claim 12
Dependent Claim
65 words
The method of claim 5 containing the additional steps of directing the effluent from step (c) to an adsorbent bed of silver-exchanged mordenite zeolite whereby the xenon is absorbed and remains on the bed, while a substantial part of the krypton passes through the bed, then forward purging the bed with a purge gas whereby to remove remaining krypton from said bed at ambient temperature.
Claim 13
Dependent Claim
38 words
The method of claim 9 containing the added steps of directing the krypton which has been removed from said bed to an adsorbent bed of synthetic mordenite zeolite at less than ambient temperature to concentrate the krypton thereon.
Claim 14
Dependent Claim
69 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising hydrogen in gaseous admixture with krypton and xenon, a method for separating the hydrogen component of said gaseous effluent, comprising the step of directing said effluent through a column having hydrogen-form synthetic mordenite zeolite disposed therethrough and while maintaining said effluent at no greater than about ambient temperature and at about ambient pressure.
Claim 15
Dependent Claim
69 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising hydrogen in gaseous admixture with krypton and xenon, a method for separating the hydrogen component of said gaseous effluent, comprising the step of directing said effluent through a column having hydrogen-form synthetic mordenite zeolite disposed therethrough and while maintaining said effluent at no greater than about ambient temperature and at about ambient pressure.
Claim 16
Dependent Claim
81 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising hydrogen and oxygen in gaseous admixture with krypton and xenon, a method for simultaneously separating the oxygen and hydrogen components from said gaseous effluent, comprising the step of directing said effluent through a column having adsorbent material disposed therethrough and while maintaining said effluent at no greater than at about ambient temperature and at about ambient pressure, said adsorbent material comprising hydrogen-form synthetic mordenite zeolite.
Claim 17
Dependent Claim
81 words
In a process for treating the gaseous effluent emitted from a nuclear reactor, said effluent comprising hydrogen and oxygen in gaseous admixture with krypton and xenon, a method for simultaneously separating the oxygen and hydrogen components from said gaseous effluent, comprising the step of directing said effluent through a column having adsorbent material disposed therethrough and while maintaining said effluent at no greater than at about ambient temperature and at about ambient pressure, said adsorbent material comprising hydrogen-form synthetic mordenite zeolite.
Claim 18
Independent Claim
180 words
A method for treating gaseous effluents emitted from a nuclear reactor, comprising sequentially: (a) directing said effluents through an adsorbent bed adsorptive to water vapor and carbon dioxide, but not to xenon and krypton, forward purging said bed with purge gas in the direction of effluents flow, raising the temperature of said bed sufficiently to desorb the absorbed water vapor and carbon dioxide, and back purging said bed with heated purge gas whereby to remove from the bed the desorbed water vapor and carbon dioxide; (b) removing iodine from the resulting water-and-carbon dioxide-free effluent; and (c) directing the resulting effluent at not greater than about ambient temperature and at about ambient pressure through an adsorbent bed comprising hydrogen-form synthetic mordenite zeolite having an affinity for adsorbing xenon and krypton which is greater than its affinity for adsorbing hydrogen and oxygen, forward purging said bed with purge gas in the direction of effluent flow to remove residual hydrogen and oxygen from said bed, and then back purging said bed with purge gas whereby to remove xenon and krypton from said bed.
Claim 19
Independent Claim
180 words
A method for treating gaseous effluents emitted from a nuclear reactor, comprising sequentially: (a) directing said effluents through an adsorbent bed adsorptive to water vapor and carbon dioxide, but not to xenon and krypton, forward purging said bed with purge gas in the direction of effluents flow, raising the temperature of said bed sufficiently to desorb the absorbed water vapor and carbon dioxide, and back purging said bed with heated purge gas whereby to remove from the bed the desorbed water vapor and carbon dioxide; (b) removing iodine from the resulting water-and-carbon dioxide-free effluent; and (c) directing the resulting effluent at not greater than about ambient temperature and at about ambient pressure through an adsorbent bed comprising hydrogen-form synthetic mordenite zeolite having an affinity for adsorbing xenon and krypton which is greater than its affinity for adsorbing hydrogen and oxygen, forward purging said bed with purge gas in the direction of effluent flow to remove residual hydrogen and oxygen from said bed, and then back purging said bed with purge gas whereby to remove xenon and krypton from said bed.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-01-17 | 1986-07-19 | 1987-01-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-01-17 | 1990-07-19 | 1991-01-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-01-17 | 1994-07-19 | 1995-01-18 | $7700.00 | Window Closed / Lapsed |