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US4368299A Expired / Lapsed US ⏱️ 0.0 years remaining

Epoxy resin compositions

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1981-07-23
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Granted: 1983-01-11
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Expires: 2001-07-23
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Abstract

Abstract A composition comprising an epoxy resin having at least two epoxy groups in the molecule and a hardener selected from the group consisting of (1) a resorcinol novolak having an unreacted resorcinol content of 10% by weight or less, (2) a mixed novolak of a resorcinol novolak and a monohydric phenol novolak having a total unreacted resorcinol and monohydric phenol content of 8% by weight or less, and (3) a resorcinol/monohydric phenol polycondensation novolak having a polycondensed resorcinol content of 30 mole % or more and a total unreacted resorcinol and monohydric phenol content of 8% by weight or less. The composition is useful for moldings, laminates, paints, and adhesives with excellent thermal resistance, durability and electrical characteristics.

Inventors

  • 👤 Katsuyoshi Watanabe
  • 👤 Makoto Andoh
  • 👤 Yasuhisa Saito
  • 👤 Yasuteru Maeda
  • 👤 Yoshiya Fukuyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:48
CPC Classifications
C; C08; C08G; C08G8/00; C08G8/04; C08G8/08; C08G8/24; C08G8/20; C08G8/22; C08L; C08L63/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 158 words
A composition comprising an epoxy resin having at least two epoxy groups in the molecule and a hardener selected from the group consisting of (1) a resorcinol novolak having an unreacted resorcinol content of 10% by weight or less, (2) a mixed novolak of a resorcinol novolak and a monohydric phenol novolak having a total unreacted resorcinol and monohydric phenol content of 8% by weight or less wherein the mixed novolak has a resorcinol novolak content of 10% by weight or more, and (3) a resorcinol/monohydric phenol polycondensation novolak having a polycondensed resorcinol content of 30 mole % or more and a total unreacted resorcinol and monohydric phenol content of 8% by weight or less, wherein the weight ratio of the epoxy resin to the hardener is such that a ratio of the number of phenolic hydroxyl groups present in the hardener to that of the epoxy groups present in the epoxy resin ranges from 0.5:1 to 1.5:1.
Claim 2
Dependent Claim 158 words
A composition comprising an epoxy resin having at least two epoxy groups in the molecule and a hardener selected from the group consisting of (1) a resorcinol novolak having an unreacted resorcinol content of 10% by weight or less, (2) a mixed novolak of a resorcinol novolak and a monohydric phenol novolak having a total unreacted resorcinol and monohydric phenol content of 8% by weight or less wherein the mixed novolak has a resorcinol novolak content of 10% by weight or more, and (3) a resorcinol/monohydric phenol polycondensation novolak having a polycondensed resorcinol content of 30 mole % or more and a total unreacted resorcinol and monohydric phenol content of 8% by weight or less, wherein the weight ratio of the epoxy resin to the hardener is such that a ratio of the number of phenolic hydroxyl groups present in the hardener to that of the epoxy groups present in the epoxy resin ranges from 0.5:1 to 1.5:1.
Claim 3
Dependent Claim 36 words
The composition according to claim 1, wherein the epoxy resin is one member selected from the group consisting of polyglycidyl ether type epoxy resins, epoxy novolak resins, epoxidized olefins, epoxidized polybutadiene and glycidylamine type epoxy resins.
Claim 4
Dependent Claim 31 words
The composition according to claim 1, wherein the resorcinol novolak is produced by reacting resorcinol with an aldehyde in the presence or absence of a catalyst and then removing unreacted resorcinol.
Claim 5
Dependent Claim 34 words
The composition according to claim 1, wherein the monohydric novolak is produced by reacting a monohydric phenol with an aldehyde in the presence or absence of a catalyst, and then removing unreacted monohydric phenol.
Claim 6
Dependent Claim 44 words
The composition according to claim 1, wherein the polycondensation novolak is produced by reacting a monohydric phenol and 30 mol % or more of resorcinol with an aldehyde in the presence or absence of a catalyst, and then removing unreacted monohydric phenol and resorcinol.
Claim 7
Dependent Claim 35 words
The composition according to claims 4 or 5, wherein the monohydric phenol is phenol, o-, m- or p-cresol, 2,3-, 2,5- or 3,5-xylenol, o-, m- or p-chlorophenol, 3-methyl-5 or 6-isobutylphenol, p-tert-butylphenol, p-tert-octylphenol or a mixture thereof.
Claim 8
Dependent Claim 31 words
The composition according to claim 1, wherein the composition further contains at least one member selected from the group consisting of other hardeners, curing accelerators, fillers, release agents, and coloring agents.

References Cited (Backward Citations)

NL88517C Cited
GB798174A Cited
SU120324A1 Cited
SU120323A1 Cited
DE1444140A1 Cited
US3493630A Cited
US3472915A Cited
US3563850A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-10 1986-07-12 1987-01-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-10 1990-07-12 1991-01-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-10 1994-07-12 1995-01-11 $7700.00 Window Closed / Lapsed

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