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US4368236A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicone resin coating compositions

Assignee: General Electric Co
•
Filing: 1981-07-16
•
Granted: 1983-01-11
•
Expires: 2001-07-16
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Abstract

Abstract An improved silicone resin abrasion resistant coating composition is provided, the coating composition having a pH in the range of from 6.8-7.8 and prepared by hydrolyzing an alkyltrialkoxysilane or aryltrialkoxysilane in an aqueous colloidal silica dispersion and adding thereto a small amount of an ultraviolet light absorbing compound, such as 2,4-dihydroxybenzophenone, to the hydrolysis product.

Inventors

  • 👤 Robert B. Frye

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 20:28
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; C09D183/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31551; Y10T428/31609; Y10T428/31612; Y10T428/31652; Y10T428/31663; Y10T428/31667

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 131 words
A solid substrate having at least one surface coated with an aqueous coating composition comprising in intimate admixture: (a) a dispersion of colloidal silica in a lower aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, wherein at least 70 weight percent of the silanol is CH 3 Si(OH) 3 ; and (b) a small amount of an ultraviolet light absorbing compound, said composition containing 10 to 50 weight percent solids, said solids consisting essentially of 10 to 70 weight percent colloidal silica and 30 to 90 weight percent of the partial condensate, and wherein said composition has a pH of from 6.8 to 7.8.
Claim 2
Dependent Claim 131 words
A solid substrate having at least one surface coated with an aqueous coating composition comprising in intimate admixture: (a) a dispersion of colloidal silica in a lower aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, wherein at least 70 weight percent of the silanol is CH 3 Si(OH) 3 ; and (b) a small amount of an ultraviolet light absorbing compound, said composition containing 10 to 50 weight percent solids, said solids consisting essentially of 10 to 70 weight percent colloidal silica and 30 to 90 weight percent of the partial condensate, and wherein said composition has a pH of from 6.8 to 7.8.
Claim 3
Dependent Claim 18 words
An article as defined in claim 1 wherein the solid substrate is comprised of a synthetic organic polymer.
Claim 4
Dependent Claim 14 words
An article as defined in claim 2 wherein said polymer is a transparent polymer.
Claim 5
Dependent Claim 13 words
An article as defined in claim 3 wherein said polymer is a polycarbonate.
Claim 6
Dependent Claim 12 words
An article as defined in claim 4 wherein said polycarbonate is transparent.
Claim 7
Dependent Claim 14 words
An article as defined in claim 4 wherein said polycarbonate is a poly(bisphenol-A carbonate).
Claim 8
Dependent Claim 22 words
An article as defined in claim 1 wherein the aqueous coating composition has been cured on said surface of said solid substrate.
Claim 9
Dependent Claim 27 words
An article as defined in claim 1 wherein said surface has been primed with a thermosetting acrylic emulsion prior to being coated with said aqueous coating composition.
Claim 10
Dependent Claim 25 words
An article as defined in claim 8 wherein said aqueous coating composition has been aged and contains a small amount of a polysiloxane polyether copolymer.
Claim 11
Dependent Claim 22 words
An article as defined in claim 9 wherein the ultraviolet light absorber in said aqueous coating composition is a substituted hydroxy benzophenone.
Claim 12
Dependent Claim 13 words
An article as defined in claim 10 wherein said substituted hydroxybenzophenone is 2,4-dihydroxybenzophenone.

References Cited (Backward Citations)

US3708225A Cited
US3976497A Cited
US3986997A Cited
US4177315A Cited
US4159206A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-10 1986-07-12 1987-01-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-10 1990-07-12 1991-01-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-10 1994-07-12 1995-01-11 $7700.00 Window Closed / Lapsed

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