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US4368233A Expired / Lapsed US ⏱️ 0.0 years remaining

Coated woven and non-woven polyolefin articles

Assignee: BP Corp North America Inc
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Filing: 1980-10-06
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Granted: 1983-01-11
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Expires: 2000-10-06
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Abstract

Abstract Extrusion coating compositions for woven and non-woven polyolefin substrates are disclosed which employ an ethylene-propylene-diene terpolymer rubber, a high density polyethylene, an ethylene-propylene block copolymer and an ethylene-isobutylacrylate copolymer. Optionally, ultraviolet stabilizers, flame retardants and pigments can be added to each. Also disclosed are woven and non-woven polyolefin substrates which are coated with the above-cited extrusion coating compositions.

Inventors

  • 👤 Edward Barkis
  • 👤 Robert R. Crummer
  • 👤 James M. Joyner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 04:13
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/693; C; C09; C09D; C09D123/00; C09D123/02; C09D123/16; Y; Y10; Y10T; Y10T442/00; Y10T442/30; Y10T442/3854; Y10T442/3886; Y10T442/60; Y10T442/674; Y10T442/678

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 577 words
A coated article comprising a substrate selected from the group consisting of woven and nonwoven polyolefin substrates and a coating composition selected from the group consisting of: (1) a composition with a shear independent melt viscosity at 190° C. of above about 2.9×10 6 centipoise comprising: (a) about 50-90% by weight of a terpolymer containing reacted ethylene, propylene, and a diene, said terpolymer having a flow rate in the range of about 0.5-1.0 g/10 min., wherein the diene is in a low concentration up to a maximum concentration in percent by weight of about 3% and is a monomer selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, cyclooctadiene-1,5, dicyclopentadiene cyclododecatriene-1,5,9, cyclododecadiene-1,7, cycloheptadiene-1,4, cyclohexadiene-1,4, norbornadiene, methylene-norbornene, methyltetrahydroindene, dimethyl-tetrahydroindene, 6-methylheptadiene-1,5, hexadiene-1,4, 6-methyl-4,7,8,9-tetrahydroindene, and ethylidene-norbornene, and wherein the reacted ethylene and propylene are in a ratio by weight of about 3:1; (b) about 50-10% by weight of a high density polyethylene having a flow rate of about 0.2-30 g/10 min., an unannealed density in the range of about 0.956-0.965, and a weight average molecular weight in a range of about 50,000-200,000; (c) about 0.5-5% by weight of an opacifier; (d) about 0.5-15% by weight of a fire retardant composition comprising at least one polyhalogenated organic compound and antimony trioxide; (e) about 0.5-3% by weight of an ultraviolet light stabilizer for polyolefins; (2) a composition having a shear independent melt viscosity at 190° C. of above about 660,000 centipoise comprising: (a) about 30-50% by weight of an ethylene-isobutylacrylate copolymer having a flow rate in the range of about 50-90 g/10 min., a density at 23° C. in the range of about 0.920-0.930, and comprising about 30% by weight of reacted isobutylacrylate; (b) about 10-40% by weight of a terpolymer containing reacted ethylene, propylene, and a diene, said terpolymer having a flow rate in the range of about 0.5-1.0 g/10 min., wherein the diene is in a low concentration up to a maximum concentration in percent by weight of about 3% and is a monomer selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, cyclooctadiene-1,5, dicyclopentadiene, cyclododecatriene-1,5,9, cyclododecadiene-1,7, cycloheptadiene-1,4, cyclohexadiene-1,4, norbornadiene, methylene-norbornene, methyltetrahydroindene, dimethyl-tetrahydroindene, 6-methylheptadiene-1,5, hexadiene-1,4, 6-methyl-4,7,8,9-tetrahydroindene, and ethylidene-norbornene, and wherein the reacted ethylene and propylene are in a ratio by weight of about 3:1; (c) about 10-40% by weight of a high density polyethylene having a flow rate in the range of about 0.2-30 g/10 min., an unannealed density in the range of about 0.956-0.965, and a weight average molecular weight in a range of about 50,000-200,000; (d) about 0.5-5% by weight of an opacifier; (e) about 0.5-15% by weight of a fire retardant composition comprising at least one polyhalogenated organic compound and antimony trioxide; (f) about 0.5--3% by weight of an ultraviolet light stabilizer; and (3) a composition having a shear independent melt viscosity at 190° C. of above about 380,000 centipoise comprising: (a) about 30-75% by weight of an olefin polymer blend containing about 40-99% by weight of an ethylene-propylene block copolymer comprising at least about 80% by weight of polymerized propylene said copolymer having a flow rate of about 15-100 dg/min. and about 1-60% by weight of polyethylene having a melt index recovery of at least about 50 and a density greater than about 0.912; and (b) about 70-25% by weight of an ethylene-isobutylacrylate copolymer having a flow rate in the range of about 50-90 g/10 min., a density at 23° C. in the range of about 0.920-0.930, and comprising about 30% by weight of reacted isobutylacrylate.
Claim 2
Dependent Claim 577 words
A coated article comprising a substrate selected from the group consisting of woven and nonwoven polyolefin substrates and a coating composition selected from the group consisting of: (1) a composition with a shear independent melt viscosity at 190° C. of above about 2.9×10 6 centipoise comprising: (a) about 50-90% by weight of a terpolymer containing reacted ethylene, propylene, and a diene, said terpolymer having a flow rate in the range of about 0.5-1.0 g/10 min., wherein the diene is in a low concentration up to a maximum concentration in percent by weight of about 3% and is a monomer selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, cyclooctadiene-1,5, dicyclopentadiene cyclododecatriene-1,5,9, cyclododecadiene-1,7, cycloheptadiene-1,4, cyclohexadiene-1,4, norbornadiene, methylene-norbornene, methyltetrahydroindene, dimethyl-tetrahydroindene, 6-methylheptadiene-1,5, hexadiene-1,4, 6-methyl-4,7,8,9-tetrahydroindene, and ethylidene-norbornene, and wherein the reacted ethylene and propylene are in a ratio by weight of about 3:1; (b) about 50-10% by weight of a high density polyethylene having a flow rate of about 0.2-30 g/10 min., an unannealed density in the range of about 0.956-0.965, and a weight average molecular weight in a range of about 50,000-200,000; (c) about 0.5-5% by weight of an opacifier; (d) about 0.5-15% by weight of a fire retardant composition comprising at least one polyhalogenated organic compound and antimony trioxide; (e) about 0.5-3% by weight of an ultraviolet light stabilizer for polyolefins; (2) a composition having a shear independent melt viscosity at 190° C. of above about 660,000 centipoise comprising: (a) about 30-50% by weight of an ethylene-isobutylacrylate copolymer having a flow rate in the range of about 50-90 g/10 min., a density at 23° C. in the range of about 0.920-0.930, and comprising about 30% by weight of reacted isobutylacrylate; (b) about 10-40% by weight of a terpolymer containing reacted ethylene, propylene, and a diene, said terpolymer having a flow rate in the range of about 0.5-1.0 g/10 min., wherein the diene is in a low concentration up to a maximum concentration in percent by weight of about 3% and is a monomer selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, cyclooctadiene-1,5, dicyclopentadiene, cyclododecatriene-1,5,9, cyclododecadiene-1,7, cycloheptadiene-1,4, cyclohexadiene-1,4, norbornadiene, methylene-norbornene, methyltetrahydroindene, dimethyl-tetrahydroindene, 6-methylheptadiene-1,5, hexadiene-1,4, 6-methyl-4,7,8,9-tetrahydroindene, and ethylidene-norbornene, and wherein the reacted ethylene and propylene are in a ratio by weight of about 3:1; (c) about 10-40% by weight of a high density polyethylene having a flow rate in the range of about 0.2-30 g/10 min., an unannealed density in the range of about 0.956-0.965, and a weight average molecular weight in a range of about 50,000-200,000; (d) about 0.5-5% by weight of an opacifier; (e) about 0.5-15% by weight of a fire retardant composition comprising at least one polyhalogenated organic compound and antimony trioxide; (f) about 0.5--3% by weight of an ultraviolet light stabilizer; and (3) a composition having a shear independent melt viscosity at 190° C. of above about 380,000 centipoise comprising: (a) about 30-75% by weight of an olefin polymer blend containing about 40-99% by weight of an ethylene-propylene block copolymer comprising at least about 80% by weight of polymerized propylene said copolymer having a flow rate of about 15-100 dg/min. and about 1-60% by weight of polyethylene having a melt index recovery of at least about 50 and a density greater than about 0.912; and (b) about 70-25% by weight of an ethylene-isobutylacrylate copolymer having a flow rate in the range of about 50-90 g/10 min., a density at 23° C. in the range of about 0.920-0.930, and comprising about 30% by weight of reacted isobutylacrylate.
Claim 3
Dependent Claim 203 words
The coated article of claim 1 wherein said coating composition is a composition with a shear independent melt viscosity at 190° C. of above about 2.9×10 6 centipoise comprising: (a) about 50-90% by weight of a terpolymer containing reacted ethylene, propylene, and a diene, said terpolymer having a flow rate in the range of about 0.5-1.0 g/10 min., wherein the diene is in a low concentration up to a maximum concentration in percent by weight of about 3% and is a monomer selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, cyclooctadiene-1,5, dicyclopentadiene, cyclododecatriene-1,5,9, cyclododecadiene-1,7, cycloheptadiene-1,4, cyclohexadiene-1,4, norbornadiene, methylene-norbornene, methyl-tetrahydroindene, dimethyltetrahydroindene, 6-methyl-heptadiene-1,5, hexadiene-1,4, 6-methyl-4,7,8,9-tetrahydroindene, and ethylidene-norbornene, and wherein the reacted ethylene and propylene are in a ratio by weight of about 3:1; (b) about 50-10% by weight of a high density polyethylene having a flow rate of about 0.2-30 g/10 min., an unannealed density in the range of about 0.956-0.965, and a weight average molecular weight in a range of about 50,000-200,000; (c) about 0.5-5% by weight of an opacifier; (d) about 0.5-15% by weight of a fire retardant composition comprising at least one polyhalogenated organic compound and antimony trioxide; and (e) about 0.5-3% by weight of an ultraviolet light stabilizer for polyolefins.
Claim 4
Dependent Claim 13 words
The coated article of claim 2 wherein said polyolefin substrate is woven polypropylene.
Claim 5
Dependent Claim 13 words
The coated article of claim 2 wherein said polyolefin substrate is nonwoven polypropylene.
Claim 6
Dependent Claim 244 words
The coated article of claim 1 wherein said coating composition is a composition having a shear independent melt viscosity at 190° C. of above about 660,000 centipoise comprising: (a) about 30-50% by weight of an ethylene-isobutylacrylate copolymer having a flow rate in the range of about 50-90 g/10 min., a density at 23° C. in the range of about 0.920-0.930, and comprising about 30% by weight of reacted isobutylacrylate; (b) about 10-40% by weight of a terpolymer containing reacted ethylene, propylene, and a diene, said terpolymer having a flow rate in the range of about 0.5-1.0 g/10 min., wherein the diene is in a low concentration up to a maximum concentration in percent by weight of about 3% and is a monomer selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, cyclooctadiene-1,5, dicyclopentadiene, cyclododecatriene-1,5,9, cyclododecadiene-1,7, cycloheptadiene-1,4, cyclohexadiene-1,4, norbornadiene, methylene-norbornene, methyl-tetrahydroindene, dimethyl-tetrahydroindene, 6-methyl-heptadiene-1,5, hexadiene-1,4, 6-methyl-4,7,8,9-tetrahydroindene, and ethylidene-norbornene, and wherein the reacted ethylene and propylene are in a ratio by weight of about 3:1; (c) about 10-40% by weight of a high density polyethylene having a flow rate in the range of about 0.2-30 g/10 min., an unannealed density in the range of about 0.956-0.965, and a weight average molecular weight in a range of about 50,000-200,000; (d) about 0.5-5% by weight of an opacifier; (e) about 0.5-15% by weight of a fire retardant composition comprising at least one polyhalogenated organic compound and antimony trioxide; and (f) about 0.5-3% by weight of an ultraviolet light stabilizer.
Claim 7
Dependent Claim 13 words
The coated article of claim 5 wherein said polyolefin substrate is woven polypropylene.
Claim 8
Dependent Claim 13 words
The coated article of claim 5 wherein said polyolefin substrate is nonwoven polypropylene.
Claim 9
Dependent Claim 134 words
The coated article of claim 1 wherein said coating composition is a composition having a shear independent melt viscosity at 190° C. of above about 380,000 centipoise comprising: (a) about 30-75% by weight of an olefin polymer blend containing about 40-99% by weight of an ethylene-propylene block copolymer comprising at least about 80% by weight of polymerized propylene said copolymer having a flow rate of about 15-100 dg/min. and about 1-60% by weight of polyethylene having a melt index recovery of at least about 50 and a density greater than about 0.912, and (b) about 70-25% by weight of an ethylene-isobutylacrylate copolymer having a flow rate in the range of about 50-90 g/10 min., a density at 23° C. in the range of about 0.920-0.930, and comprising about 30% by weight of reacted isobutylacrylate.
Claim 10
Dependent Claim 13 words
The coated article of claim 8 wherein said polyolefin substrate is woven polypropylene.
Claim 11
Dependent Claim 13 words
The coated article of claim 8 wherein said polyolefin substrate is nonwoven polypropylene.

References Cited (Backward Citations)

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US3058863A Cited
AU229472B2 Cited
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US3513057A Cited
US3470055A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-10 1986-07-12 1987-01-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-10 1990-07-12 1991-01-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-10 1994-07-12 1995-01-11 $7700.00 Window Closed / Lapsed

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