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US4367295A Expired / Lapsed US ⏱️ 0.0 years remaining

Intumescent compositions obtained by reacting polyisocyanates with phosphorus-containing products, polyesters and cyanuric acid and/or cyanuric acid derivatives

Assignee: Bayer AG
•
Filing: 1981-06-23
•
Granted: 1983-01-04
•
Expires: 2001-06-23
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Abstract

Abstract The present invention relates to intumescent compositions, which may be foamed, and which are obtained by reacting: (1) polyisocyanates with (2) phosphorus-containing condensation products having at least one hydroxyl group obtainable by condensing (i) primary or secondary aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic monoamines and/or polyamines, which mono- or polyamines may contain OH-groups; (ii) carbonyl compounds; and, (iii) dialkyl phosphites, and (3) polyesters containing hydroxyl groups and having OH-numbers of from 140 to 300, obtained by reacting polycarboxylic acids containing from 2 to 10 carbon atoms with at least 2 polyols selected from two different groups of the following three: (a) hydroxyl compounds containing more than three OH groups and having molecular weights of up to 200, (b) hydroxyl compounds containing three OH groups and having molecular weights of up to 150, (c) hydroxyl compounds containing two OH-groups and having molecular weights of up to 80, with the proviso that at least one polyol is selected from group (a), and (4) cyanuric acid and/or cyanuric acid derivatives and (5) optionally water and/or other organic compounds containing isocyanate-reactive hydrogen atoms.

Inventors

  • 👤 Wulf von Bonin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 17:49
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3819; C08G18/3842; C08G18/3851; C08G18/3838; C08G18/3878; C08G18/3889; C08G18/40; C08G18/48; C08G18/50; C08G18/5075; C08G18/509; C09; C09D; C09D5/00; C09D5/18; C09D5/185; C09K; C09K21/00; C09K21/06; C09K21/12; C09K21/14

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 174 words
Intumescent compositions, which may be foamed, and which are obtained by reacting: (1) polyisocyanates with (2) phosphorus-containing condensation products having at least one hydroxy group obtainable by condensing (i) primary or secondary aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic monoamines and/or polyamines, which mono- or polyamines may contain OH-groups; (ii) carbonyl compounds; and, (iii) dialkyl phosphites, and (3) polyesters containing hydroxyl groups and having OH-numbers of from 140 to 300, obtained by reacting polycarboxylic acids containing from 2 to 10 carbon atoms with at least 2 polyols selected from two different groups of the following three: (a) hydroxyl compounds containing more than three OH groups and having molecular weights of up to 200, (b) hydroxyl compounds containing three OH groups and having molecular weights of up to 150, (c) hydroxyl compounds containing two OH-groups and having molecular weights of up to 80, with the proviso that at least one polyol is selected from group (a), and (4) cyanuric acid and/or cyanuric acid derivatives and (5) optionally water and/or other organic compounds containing isocyanate-reactive hydrogen atoms.
Claim 2
Dependent Claim 174 words
Intumescent compositions, which may be foamed, and which are obtained by reacting: (1) polyisocyanates with (2) phosphorus-containing condensation products having at least one hydroxy group obtainable by condensing (i) primary or secondary aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic monoamines and/or polyamines, which mono- or polyamines may contain OH-groups; (ii) carbonyl compounds; and, (iii) dialkyl phosphites, and (3) polyesters containing hydroxyl groups and having OH-numbers of from 140 to 300, obtained by reacting polycarboxylic acids containing from 2 to 10 carbon atoms with at least 2 polyols selected from two different groups of the following three: (a) hydroxyl compounds containing more than three OH groups and having molecular weights of up to 200, (b) hydroxyl compounds containing three OH groups and having molecular weights of up to 150, (c) hydroxyl compounds containing two OH-groups and having molecular weights of up to 80, with the proviso that at least one polyol is selected from group (a), and (4) cyanuric acid and/or cyanuric acid derivatives and (5) optionally water and/or other organic compounds containing isocyanate-reactive hydrogen atoms.
Claim 3
Dependent Claim 13 words
The composition of claim 1 wherein, following condensation, said component (2) is alkoxylated.
Claim 4
Dependent Claim 79 words
The compositions of claim 1 obtained by reacting from 10 to 35 parts, by weight, of a polyisocyanate with 100 parts, by weight, of a mixture comprising from 5 to 50%, by weight, of phosphorus-containing condensation products, from 30 to 70%, by weight of polyesters, from 7 to 40%, by weight of cyanuric acid and/or derivatives, from 0 to 10%, by weight, of water, and from 0 to 25%, by weight, of other organic compounds containing isocyanate-reactive hydrogen atoms.
Claim 5
Dependent Claim 20 words
The composition as of claim 1, characterized in that said polyisocyanate is of the type obtained by phosgenating aniline/formaldehyde condensates.
Claim 6
Dependent Claim 39 words
The composition of claim 1, characterized in that the phosphorus compound corresponds to the following formula: (RO).sub.2 PO--CH.sub.2 --N--(CHX--CHX--OH).sub.2, wherein R represents C 1 -C 8 alkyl or C 1 -C 8 hydroxyalkyl; and X represents H or methyl.
Claim 7
Dependent Claim 25 words
The composition of claim 1, characterized in that a highly branched polyester of adipic acid, pentaerythritol, glycerol and ethylene glycol is used as the polyesters.
Claim 8
Dependent Claim 16 words
The composition of claim 1, characterized in that melamine is used as the cyanuric acid derivative.

References Cited (Backward Citations)

CA863416A Cited
US3235517A Cited
US3396129A Cited
US4258141A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-03 1986-07-05 1987-01-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-03 1990-07-05 1991-01-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-03 1994-07-05 1995-01-04 $7700.00 Window Closed / Lapsed

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