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US4367262A Expired / Lapsed US ⏱️ 0.0 years remaining

Solid substrate coated with silicone resin coating composition

Assignee: General Electric Co
•
Filing: 1981-04-20
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Granted: 1983-01-04
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Expires: 2001-04-20
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Abstract

Abstract A silicone resin coating composition which, when applied to a solid substrate, provides a thick abrasion resistant coating thereto, is disclosed herein. The coating composition has a basic pH in the range of from 7.1-7.8 and is prepared by hydrolyzing an alkyltrialkoxysilane or aryltrialkoxysilane in an aqueous colloidal silica dispersion. A thickening agent is added to the resultant hydrolysis product.

Inventors

  • 👤 Howard A. Vaughn, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:08
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/259; Y10T428/31504; Y10T428/31507; Y10T428/31652; Y10T428/31663; Y10T428/31667; Y10T428/31721; Y10T428/31725; Y10T428/3175; Y10T428/31786; Y10T428/31855; Y10T428/3188; Y10T428/31884; Y10T428/31891; Y10T428/31909; Y10T428/31928

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 171 words
A solid substrate having at least one surface coated with an improved aqueous coating composition comprising a dispersion of colloidal silica having a particle size of from 5 to 150 millimicrons in diameter in a lower-aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein the lower-aliphatic alcohol-water solvent contains from about 20 to 75 weight percent of said lower-aliphatic alcohol component and wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, at least 70 weight percent of the silanol being CH 3 Si(OH) 3 , said composition containing 10 to 50 weight percent solids consisting essentially of 10 to 70 weight percent colloidal silica and 30 to 90 weight percent of the partial condensate, the composition further containing from about 0.1 to about 1 percent by weight of a thickening agent selected from the group consisting of hydroxypropyl guar gum and hydroxypropyl cellulose, said composition having a pH of 7.1 to about 7.8.
Claim 2
Dependent Claim 171 words
A solid substrate having at least one surface coated with an improved aqueous coating composition comprising a dispersion of colloidal silica having a particle size of from 5 to 150 millimicrons in diameter in a lower-aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein the lower-aliphatic alcohol-water solvent contains from about 20 to 75 weight percent of said lower-aliphatic alcohol component and wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, at least 70 weight percent of the silanol being CH 3 Si(OH) 3 , said composition containing 10 to 50 weight percent solids consisting essentially of 10 to 70 weight percent colloidal silica and 30 to 90 weight percent of the partial condensate, the composition further containing from about 0.1 to about 1 percent by weight of a thickening agent selected from the group consisting of hydroxypropyl guar gum and hydroxypropyl cellulose, said composition having a pH of 7.1 to about 7.8.
Claim 3
Dependent Claim 18 words
An article as defined in claim 1 wherein the solid substrate is comprised of a synthetic organic polymer.
Claim 4
Dependent Claim 14 words
An article as defined in claim 2 wherein said polymer is a transparent polymer.
Claim 5
Dependent Claim 13 words
An article as defined in claim 3 wherein said polymer is a polycarbonate.
Claim 6
Dependent Claim 12 words
An article as defined in claim 4 wherein said polycarbonate is transparent.
Claim 7
Dependent Claim 14 words
An article as defined in claim 4 wherein said polycarbonate is a poly(bisphenol-A carbonate).
Claim 8
Dependent Claim 13 words
An article as defined in claim 2 wherein said polymer is a polymethylmethacrylate.
Claim 9
Dependent Claim 12 words
An article as defined in claim 7 wherein said polymethylmethacrylate is transparent.
Claim 10
Dependent Claim 22 words
An article as defined in claim 1 wherein the aqueous coating composition has been cured on said surface of said solid substrate.
Claim 11
Dependent Claim 31 words
An article as defined in claim 1 wherein said surface of said solid substrate has been primed with a primer composition prior to having been coated with said aqueous coating composition.
Claim 12
Dependent Claim 18 words
An article as defined in claim 10 wherein said primer composition is comprised of a thermosetting acrylic emulsion.
Claim 13
Dependent Claim 37 words
An article as defined in claim 10 wherein said primer composition is comprised of an ethanol-isobutanol solution containing 1.5 weight percent of gamma-aminopropyltriethoxysilane and 1.5 weight percent of a preformed reaction product of gamma-aminopropyltriethoxysilane and maleic anhydride.

References Cited (Backward Citations)

US3708225A Cited
US3976497A Cited
US4309319A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-03 1986-07-05 1987-01-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-03 1990-07-05 1991-01-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-03 1994-07-05 1995-01-04 $7700.00 Window Closed / Lapsed

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