US4366300A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Composition and process for the protection of materials against spots or stains
Assignee: Produits Chimiques Ugine Kuhlmann
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Filing: 1981-05-21
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Granted: 1982-12-28
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Expires: 2001-05-21
Abstract
Abstract The invention relates to a composition for the protection of materials against contaminations, spots and stains. This liquid composition comprises by weight 0.1 to 1% of at least one fluorinated resin based on acrylic or methacrylic esters of fluorinated sulfonamido-alcohol, associated or not with non-fluorinated monomers, 0.4 to 10% of at least one adjuvant selected from aminoplast resins based on melamine, thermoplastic resins and waxes, and 89 to 99.5% of at least one organic solvent. Applied on materials such as walls, facades, monuments or sculptures in cement, bricks, concrete or stones and other construction elements, the composition according to the invention confers on the materials an excellent protection against natural or artificial contaminations.
Inventors
- 👤 Charles L. L. Delescluse
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:39
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/285; D06M15/295; C; C08; C08L; C08L33/00; C08L33/04; C08L33/14
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
133 words
A substantially non-aqueous liquid composition for the protection of materials against comtaminations from spots and stains, which consists by weight of: (A) 0.1 to 1% of at least one fluorinated resin based on an acrylic or methacrylic ester of a fluorinated sulfonamide-alcohol and containing from 0 to 80% non-fluorinated monomers, said fluorinated sulfonamide-alcohol having the formula: ##STR6## in which Rf represents a perfluoroalkyl radical, A represents a direct bond or an alkylene bridge, B represents an alkylene bridge and R represents a hydrogen atom or an alkyl, cycloalkyl, hydroxyalkyl or aryl radical; (B) 0.4 to 10% of at least one adjuvant selected from aminoplast resins based on melamine, polyvinyl resins, epoxy resins, polyester resins, styrene resins, alkyd-urethane resins, phenolic resins and waxes; and (C) 89 to 99.5% of at least one organic solvent.
Claim 2
Dependent Claim
133 words
A substantially non-aqueous liquid composition for the protection of materials against comtaminations from spots and stains, which consists by weight of: (A) 0.1 to 1% of at least one fluorinated resin based on an acrylic or methacrylic ester of a fluorinated sulfonamide-alcohol and containing from 0 to 80% non-fluorinated monomers, said fluorinated sulfonamide-alcohol having the formula: ##STR6## in which Rf represents a perfluoroalkyl radical, A represents a direct bond or an alkylene bridge, B represents an alkylene bridge and R represents a hydrogen atom or an alkyl, cycloalkyl, hydroxyalkyl or aryl radical; (B) 0.4 to 10% of at least one adjuvant selected from aminoplast resins based on melamine, polyvinyl resins, epoxy resins, polyester resins, styrene resins, alkyd-urethane resins, phenolic resins and waxes; and (C) 89 to 99.5% of at least one organic solvent.
Claim 3
Dependent Claim
53 words
Composition according to claim 1 in which the fluorinated resin (A) results from the polymerization of one or more acrylic or methacrylic esters of fluorinated alcohol of formula (I), accompanied by from 0 to 20% of other non-fluorinated monomers, in the presence of a homopolymer or copolymer of non-fluorinated alkyl acrylate or methacrylate.
Claim 4
Dependent Claim
55 words
Compositions according to claim 1 in which the fluorinated resin (A) results from the polymerization of one or more non-fluorinated alkyl acrylates or methacrylates, accompanied by from 0 to 20% of other non-fluorinated monomers, in the presence of a homopolymer or copolymer based on acrylate or methacrylate esters of the fluorinated alcohol of formula (I).
Claim 5
Dependent Claim
23 words
Composition according to claim 2 in which the alkyl radical of the non-fluorinated alkyl acrylates or methacrylates contains 1 to 20 carbon atoms.
Claim 6
Dependent Claim
23 words
Composition according to claim 3 in which the alkyl radical of the non-fluorinated alkyl acrylates or methacrylates contains 1 to 20 carbon atoms.
Claim 7
Dependent Claim
88 words
Composition according to claim 1, 2, 3, 4 or 5 in which the fluorinated alcohol corresponds to the formula: ##STR7## in which Rf represents a straight or branched perfluoroalkyl radical containing 1 to 20 carbon atoms and R represents a hydrogen atom, an alkyl radical containing 1 to 10 carbon atoms, a cycloalkyl radical containing 5 to 12 carbon atoms, an hydroxyalkyl radical containing 2 to 4 carbon atoms, an unsubstituted aryl radical, or an aryl radical substituted by an alkyl radical containing 1 to 6 carbon atoms.
Claim 8
Dependent Claim
20 words
Composition according to claim 1, 2, 3, 4 or 5 in which adjuvant (B) is the hexamethyl ether of hexamethylolmelamine.
Claim 9
Dependent Claim
15 words
Composition according to claim 6 in which adjuvant (B) is the hexamethyl ether of hexamethylolmelamine.
Claim 10
Dependent Claim
35 words
Composition according to claim 1, 2, 3, 4 or 5 wherein adjuvant (B) is a thermoplastic resin selected from the polyvinyl resins, epoxy resins, polyester resins, styrene resins, acrylic resins, alkyd-urethane resins and phenolic resins.
Claim 11
Dependent Claim
35 words
Composition according to claim 8 wherein one more adjuvant (B) is present which is a thermoplastic resin selected from the polyvinyl resins, epoxy resins, polyester resins, styrene resins, acrylic resins, alkyd-urethane resins and phenolic resins.
Claim 12
Dependent Claim
24 words
Composition according to claim 1, 2, 3, 4 or 5 wherein adjuvant (B) is a wax selected from the paraffins, paraffin oils and stearins.
Claim 13
Dependent Claim
24 words
Composition according to claim 8 wherein one more adjuvant (B) is present which is a wax selected from the paraffins, paraffin oils and stearins.
Claim 14
Dependent Claim
23 words
Composition according to claim 1, 2, 3, 4 or 5 which comprises in addition an organic catalyst miscible or dispersible in organic medium.
Claim 15
Dependent Claim
18 words
Composition according to claim 8 which comprises in addition an organic catalyst miscible or dispersible in organic medium.
Claim 16
Dependent Claim
31 words
Composition according to claim 1, 2, 3, 4 or 5 in which organic solvent (C) is selected from chlorinated solvents, chlorofluorinated solvents, ketones, esters, aliphatic or aromatic hydrocarbons and mixtures thereof.
Claim 17
Dependent Claim
48 words
Process for the protection of materials against contamination and spots or stains in which a composition according to claim 1, 2, 3, 4 or 5 is applied to the materials at the rate of 100 to 500 ml of composition per m 2 of surface to be protected.
Claim 18
Dependent Claim
43 words
Process for the protection of materials against contamination and spots or stains in which a composition according to claim 10 is applied to the materials at the rate of 100 to 500 ml of composition per m 2 of surface to be protected.
Claim 19
Dependent Claim
43 words
Process for the protection of materials against contamination and spots or stains in which a composition acccording to claim 12 is applied to the materials at the rate of 100 to 500 ml of composition per m 2 of surface to be protected.
Claim 20
Dependent Claim
43 words
Process for the protection of materials against contamination and spots or stains in which a composition according to claim 14 is applied to the materials at the rate of 100 to 500 ml of composition per m 2 of surface to be protected.
Claim 21
Dependent Claim
22 words
The process according to claim 16 in which said composition is applied at the rate of 120 to 350 ml/m 2 .
References Cited (Backward Citations)
US2687963A
Cited
US2687964A
Cited
US3346612A
Cited
US3459696A
Cited
US3385812A
Cited
GB1433524A
Cited
FR2313987A1
Cited
US4125673A
Cited
SU626106A1
Cited
US4256494A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-12-27 | 1986-06-28 | 1986-12-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-12-27 | 1990-06-28 | 1990-12-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-12-27 | 1994-06-28 | 1994-12-28 | $7700.00 | Window Closed / Lapsed |