← Back to Patent Explorer
US4366131A Expired / Lapsed US ⏱️ 0.0 years remaining

Highly reactive iron oxide agents and apparatus for hydrogen sulfide scavenging

Assignee: GAS SWEETENER ASSOCIATES Inc A Corp
•
Filing: 1981-01-19
•
Granted: 1982-12-28
•
Expires: 2001-01-19
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Substantially dry iron oxide particles having a high surface area, a high kinetic "K" value and composed of a crystalline phase of Fe 3 O 4 together with an amorphous Fe 2 O 3 moiety or portion and having a surface area of at least 4 m 2 / g are useful for scavenging hydrogen sulfide from other gases containing it. A cartridge type device is provided containing such particles intermixed with inert particulate matter, e.g. sand, useful as a means for scavenging hydrogen sulfide from such other gases.

Inventors

  • 👤 Irwin Fox

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 09:11
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 105 words
A method of scavenging hydrogen sulfide from a gas containing the same which comprises (a) contacting said gas with substantially dry particles of a hydrogen sulfide-reactive iron oxide having a surface area of at least 4.0 m 2 / g , a kinetic "K" value in excess of 1000 and composed substantially of a crystalline phase of Fe 3 O 4 and an amorphous Fe 2 O 3 moiety, (b) continuing said contacting until the hydrogen sulfide has reacted with said particles and its concentration in said gas has been reduced to a predetermined level, and (c) separating the gas so scavenged from said particles.
Claim 2
Independent Claim 105 words
A method of scavenging hydrogen sulfide from a gas containing the same which comprises (a) contacting said gas with substantially dry particles of a hydrogen sulfide-reactive iron oxide having a surface area of at least 4.0 m 2 / g , a kinetic "K" value in excess of 1000 and composed substantially of a crystalline phase of Fe 3 O 4 and an amorphous Fe 2 O 3 moiety, (b) continuing said contacting until the hydrogen sulfide has reacted with said particles and its concentration in said gas has been reduced to a predetermined level, and (c) separating the gas so scavenged from said particles.
Claim 3
Dependent Claim 21 words
A method in accordance with that of claim 1, in which the gas to be contacted is substantially free of oxygen.
Claim 4
Dependent Claim 59 words
A method in accordance with that of claim 1, in which the gas to be contacted is substantially a hydrocarbon gas containing hydrogen sulfide and said gas is contacted with a substantially uniform mixture of from about 50 to 80% by weight of said iron oxide particles and from about 50 to 20% by weight of inert solid particles.
Claim 5
Dependent Claim 56 words
A method in accordance with that of claim 1, together with an intermediate step between step (a) and step (b) thereof, comprising in the course of such contacting, causing the gas to pass upward through said particles and the particles to separate from each other and fluidize in the gas, whereby to achieve more intimate contacting.

References Cited (Backward Citations)

US3117844A Cited
FR2248871A1 Cited
US4246244A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-27 1986-06-28 1986-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-27 1990-06-28 1990-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-27 1994-06-28 1994-12-28 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag