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US4366047A Expired / Lapsed US ⏱️ 0.0 years remaining

Combination hydrorefining, heat-treating and hydrocracking process

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1981-06-02
•
Granted: 1982-12-28
•
Expires: 2001-06-02
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Abstract

Abstract A process for upgrading a heavy hydrocarbonaceous oil is provided in which the oil is hydrorefined, heat-treated and hydrocracked to increase the selectivity of the hydrocracked product to components boiling in the range of 350° to 675° F.

Inventors

  • 👤 William E. Winter
  • 👤 Bong H. Chang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 20:18
CPC Classifications
C; C10; C10G; C10G65/00; C10G65/02; C10G65/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 162 words
A process for upgrading a heavy hydrocarbonaceous oil feed, which comprises the steps of: (a) contacting said oil feed with added hydrogen in the presence of a hydrorefining catalyst at hydrorefining conditions, in a hydrorefining zone; (b) heat-treating at least a portion of the entire effluent of said hydrorefining zone, said portion including normally liquid hydrocarbons and hydrogen, in a heat-treating zone, in the absence of a catalyst at conditions such as to avoid any significant cracking of said normally liquid hydrocarbons, said conditions including a temperature in the range of about 500° to about 720° F., for a period of time ranging from about 0.25 hour to about 6 hours; (c) passing at least a portion of the entire heat-treated effluent, including hydrogen and normally liquid hydrocarbons, to a hydrocracking zone; (d) subjecting said portion of heat-treated effluent to hydrocracking conditions in the presence of a hydrocracking catalyst in said hydrocracking zone, and (e) recovering a hydrocracked normally liquid hydrocarbonaceous product.
Claim 2
Dependent Claim 162 words
A process for upgrading a heavy hydrocarbonaceous oil feed, which comprises the steps of: (a) contacting said oil feed with added hydrogen in the presence of a hydrorefining catalyst at hydrorefining conditions, in a hydrorefining zone; (b) heat-treating at least a portion of the entire effluent of said hydrorefining zone, said portion including normally liquid hydrocarbons and hydrogen, in a heat-treating zone, in the absence of a catalyst at conditions such as to avoid any significant cracking of said normally liquid hydrocarbons, said conditions including a temperature in the range of about 500° to about 720° F., for a period of time ranging from about 0.25 hour to about 6 hours; (c) passing at least a portion of the entire heat-treated effluent, including hydrogen and normally liquid hydrocarbons, to a hydrocracking zone; (d) subjecting said portion of heat-treated effluent to hydrocracking conditions in the presence of a hydrocracking catalyst in said hydrocracking zone, and (e) recovering a hydrocracked normally liquid hydrocarbonaceous product.
Claim 3
Dependent Claim 26 words
The process of claim 1 wherein said heavy hydrocarbonaceous oil feed of step (a) has an atmospheric pressure boiling point of at least about 650° F.
Claim 4
Dependent Claim 25 words
The process of claim 1 wherein said heavy hydrocarbonaceous oil feed of step (a) has at least 10 weight percent constituents boiling above 900° F.
Claim 5
Dependent Claim 23 words
The process of claim 1 wherein said heat-treating conditions of step (b) include a temperature ranging from about 500° to about 690° F.
Claim 6
Dependent Claim 26 words
The process of claim 1 wherein said heat-treating of step (b) is conducted for a period of time ranging from about 0.5 to about 3 hours.
Claim 7
Dependent Claim 34 words
The process of claim 1 wherein said hydrorefining conditions in step (a) include a temperature ranging from about 600° to about 900° F. and a pressure ranging from about 50 to about 3500 psig.
Claim 8
Dependent Claim 34 words
The process of claim 1 wherein said hydrocracking conditions of step (d) include a temperature ranging from about 400° to about 900° F. and a pressure ranging from about 500 to about 3500 psig.

References Cited (Backward Citations)

US2889263A Cited
US3055823A Cited
US3509044A Cited
US3730875A Cited
US4298457A Cited
US4292168A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-27 1986-06-28 1986-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-27 1990-06-28 1990-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-27 1994-06-28 1994-12-28 $7700.00 Window Closed / Lapsed

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