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US4365068A Expired / Lapsed US ⏱️ 0.0 years remaining

Crosslinkable bis-imidyl derivatives

Assignee: BASF Corp
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Filing: 1980-11-14
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Granted: 1982-12-21
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Expires: 2000-11-14
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Abstract

Abstract New crosslinkable bis-imidyl derivatives are described which can be produced by reaction of imidylphthalic acid derivatives, such as maleimidyl-phthalic acid anhydrides, with monomeric, oligomeric or polymeric diamines. The new crosslinkable bis-imidyl derivatives can be used for producing crosslinked polymers which are distinguished, in particular, by their stability to oxidation and to heat.

Inventors

  • 👤 Roland Darms
  • 👤 Vratislav Kvita
  • 👤 Gerd Greber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 08:42
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 228 words
A crosslinkable compound of the formula ##STR25## wherein the X s independently of one another represent hydrogen or, if the radical ##STR26## is in the 4-position of the benzene ring, also --COR 2 , the R 2 s independently of one another represent hydroxyl, phenoxy; phenoxy substituted by one or two nitro groups, by one alkyl of 1 to 2 carbon atoms, by one alkoxy of 1 to 2 carbon atoms or by two or five halogen atoms; alkoxy of 1 to 18 carbon atoms or an O-M+ group, the R 1 s independently of one another have the same meaning as the R 2 s or two adjacent R 1 s together represent the --O-- grouping, the A s independently of one another represent a radical of the formula ##STR27## R 3 and R 4 independently of one another represent hydrogen, chlorine, bromine or methyl, M+ represents an alkali metal cation, a trialkylammonium cation having 3-24 carbon atoms, or the benzyltrimethylammonium or tetramethylammonium cation, Q represents --NH--, and Y represents a structural element of the formula ##STR28## wherein a represents a number from 1-100, Z represents alkylene of 2 to 10 carbon atoms, 1,3-phenylene, 1,4-phenylene, the 4,4'-diphenylmethane group, the 4,4'-diphenylsulfone group or the 4,4'-diphenyl ether group, and Z 1 represents a benzenetriyl group, in which the ##STR29## group is bound to ortho carbons of Z 1 .
Claim 2
Dependent Claim 228 words
A crosslinkable compound of the formula ##STR25## wherein the X s independently of one another represent hydrogen or, if the radical ##STR26## is in the 4-position of the benzene ring, also --COR 2 , the R 2 s independently of one another represent hydroxyl, phenoxy; phenoxy substituted by one or two nitro groups, by one alkyl of 1 to 2 carbon atoms, by one alkoxy of 1 to 2 carbon atoms or by two or five halogen atoms; alkoxy of 1 to 18 carbon atoms or an O-M+ group, the R 1 s independently of one another have the same meaning as the R 2 s or two adjacent R 1 s together represent the --O-- grouping, the A s independently of one another represent a radical of the formula ##STR27## R 3 and R 4 independently of one another represent hydrogen, chlorine, bromine or methyl, M+ represents an alkali metal cation, a trialkylammonium cation having 3-24 carbon atoms, or the benzyltrimethylammonium or tetramethylammonium cation, Q represents --NH--, and Y represents a structural element of the formula ##STR28## wherein a represents a number from 1-100, Z represents alkylene of 2 to 10 carbon atoms, 1,3-phenylene, 1,4-phenylene, the 4,4'-diphenylmethane group, the 4,4'-diphenylsulfone group or the 4,4'-diphenyl ether group, and Z 1 represents a benzenetriyl group, in which the ##STR29## group is bound to ortho carbons of Z 1 .
Claim 3
Dependent Claim 55 words
A crosslinkable compound according to claim 1 of formula Ia' wherein the two radicals ##STR30## independently of one another are in the 3- or 4-position of the benzene ring, X represents hydrogen or --COR 2 where R 2 is alkoxy of 1 to 4 carbon atoms, and A represents the radical of the formula ##STR31##
Claim 4
Dependent Claim 11 words
A crosslinkable compound according to claim 1 wherein A is --CH═CH--.
Claim 5
Dependent Claim 43 words
A crosslinkable compound according to claim 1 of formula Ib wherein the R 1 s each represent a hydroxyl group or each two adjacent R 1 s together form the --O-- grouping, and A represents the radical of the formula ##STR32## or --CH═CH--.
Claim 6
Dependent Claim 65 words
A crosslinkable compound according to claim 1 wherein A represents ##STR33## or --CH═CH--, X represents a --COOalkyl group having 1-4 carbon atoms in the alkyl moiety or hydrogen, the R 1 s each represent a hydroxyl group, or two adjacent R 1 s together represent the --O-- grouping, a represents an integer from 1-10, and Z represents the 4,4'-diphenylmethane group or the 4,4'-diphenyl ether group.
Claim 7
Dependent Claim 27 words
A crosslinkable compound according to claim 1 wherein X is hydrogen, A is --CH═CH--, a is 2, Z is the 4,4'-diphenylmethane group and Z 1 is 1,2,4-benenetriyl.
Claim 8
Dependent Claim 35 words
A crosslinkable compound according to claim 1 wherein X is hydrogen, A is --CH═CH--, Y represents a structure of formula IIb, a is 4, Z is the 4,4' diphenylmethane group and Z 1 is 1,2,4-benzenetriyl.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-20 1986-06-21 1986-12-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-20 1990-06-21 1990-12-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-20 1994-06-21 1994-12-21 $7700.00 Window Closed / Lapsed

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