US4365068A
Expired / Lapsed
US
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Crosslinkable bis-imidyl derivatives
Assignee: BASF Corp
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Filing: 1980-11-14
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Granted: 1982-12-21
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Expires: 2000-11-14
Abstract
Abstract New crosslinkable bis-imidyl derivatives are described which can be produced by reaction of imidylphthalic acid derivatives, such as maleimidyl-phthalic acid anhydrides, with monomeric, oligomeric or polymeric diamines. The new crosslinkable bis-imidyl derivatives can be used for producing crosslinked polymers which are distinguished, in particular, by their stability to oxidation and to heat.
Inventors
- 👤 Roland Darms
- 👤 Vratislav Kvita
- 👤 Gerd Greber
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 08:42
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/12
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
228 words
A crosslinkable compound of the formula ##STR25## wherein the X s independently of one another represent hydrogen or, if the radical ##STR26## is in the 4-position of the benzene ring, also --COR 2 , the R 2 s independently of one another represent hydroxyl, phenoxy; phenoxy substituted by one or two nitro groups, by one alkyl of 1 to 2 carbon atoms, by one alkoxy of 1 to 2 carbon atoms or by two or five halogen atoms; alkoxy of 1 to 18 carbon atoms or an O-M+ group, the R 1 s independently of one another have the same meaning as the R 2 s or two adjacent R 1 s together represent the --O-- grouping, the A s independently of one another represent a radical of the formula ##STR27## R 3 and R 4 independently of one another represent hydrogen, chlorine, bromine or methyl, M+ represents an alkali metal cation, a trialkylammonium cation having 3-24 carbon atoms, or the benzyltrimethylammonium or tetramethylammonium cation, Q represents --NH--, and Y represents a structural element of the formula ##STR28## wherein a represents a number from 1-100, Z represents alkylene of 2 to 10 carbon atoms, 1,3-phenylene, 1,4-phenylene, the 4,4'-diphenylmethane group, the 4,4'-diphenylsulfone group or the 4,4'-diphenyl ether group, and Z 1 represents a benzenetriyl group, in which the ##STR29## group is bound to ortho carbons of Z 1 .
Claim 2
Dependent Claim
228 words
A crosslinkable compound of the formula ##STR25## wherein the X s independently of one another represent hydrogen or, if the radical ##STR26## is in the 4-position of the benzene ring, also --COR 2 , the R 2 s independently of one another represent hydroxyl, phenoxy; phenoxy substituted by one or two nitro groups, by one alkyl of 1 to 2 carbon atoms, by one alkoxy of 1 to 2 carbon atoms or by two or five halogen atoms; alkoxy of 1 to 18 carbon atoms or an O-M+ group, the R 1 s independently of one another have the same meaning as the R 2 s or two adjacent R 1 s together represent the --O-- grouping, the A s independently of one another represent a radical of the formula ##STR27## R 3 and R 4 independently of one another represent hydrogen, chlorine, bromine or methyl, M+ represents an alkali metal cation, a trialkylammonium cation having 3-24 carbon atoms, or the benzyltrimethylammonium or tetramethylammonium cation, Q represents --NH--, and Y represents a structural element of the formula ##STR28## wherein a represents a number from 1-100, Z represents alkylene of 2 to 10 carbon atoms, 1,3-phenylene, 1,4-phenylene, the 4,4'-diphenylmethane group, the 4,4'-diphenylsulfone group or the 4,4'-diphenyl ether group, and Z 1 represents a benzenetriyl group, in which the ##STR29## group is bound to ortho carbons of Z 1 .
Claim 3
Dependent Claim
55 words
A crosslinkable compound according to claim 1 of formula Ia' wherein the two radicals ##STR30## independently of one another are in the 3- or 4-position of the benzene ring, X represents hydrogen or --COR 2 where R 2 is alkoxy of 1 to 4 carbon atoms, and A represents the radical of the formula ##STR31##
Claim 4
Dependent Claim
11 words
A crosslinkable compound according to claim 1 wherein A is --CH═CH--.
Claim 5
Dependent Claim
43 words
A crosslinkable compound according to claim 1 of formula Ib wherein the R 1 s each represent a hydroxyl group or each two adjacent R 1 s together form the --O-- grouping, and A represents the radical of the formula ##STR32## or --CH═CH--.
Claim 6
Dependent Claim
65 words
A crosslinkable compound according to claim 1 wherein A represents ##STR33## or --CH═CH--, X represents a --COOalkyl group having 1-4 carbon atoms in the alkyl moiety or hydrogen, the R 1 s each represent a hydroxyl group, or two adjacent R 1 s together represent the --O-- grouping, a represents an integer from 1-10, and Z represents the 4,4'-diphenylmethane group or the 4,4'-diphenyl ether group.
Claim 7
Dependent Claim
27 words
A crosslinkable compound according to claim 1 wherein X is hydrogen, A is --CH═CH--, a is 2, Z is the 4,4'-diphenylmethane group and Z 1 is 1,2,4-benenetriyl.
Claim 8
Dependent Claim
35 words
A crosslinkable compound according to claim 1 wherein X is hydrogen, A is --CH═CH--, Y represents a structure of formula IIb, a is 4, Z is the 4,4' diphenylmethane group and Z 1 is 1,2,4-benzenetriyl.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-12-20 | 1986-06-21 | 1986-12-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-12-20 | 1990-06-21 | 1990-12-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-12-20 | 1994-06-21 | 1994-12-21 | $7700.00 | Window Closed / Lapsed |