← Back to Patent Explorer
US4363797A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyaspartic acid derivatives, their preparation and their use in cosmetic composition

Assignee: L'Oréal SA
•
Filing: 1979-12-06
•
Granted: 1982-12-14
•
Expires: 1999-12-06
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Novel polymers useful, in particular, in cosmetic compositions for application to the hair are described. These random polymers can be represented by the general formula: <IMAGE> (I) <IMAGE> in which: Z represents a mercapto radical or a sulphonic acid radical, which is free or is in the form of an alkali metal or an alkaline earth metal salt, x is an integer from 2 to 6, R represents a hydrogen atom or a lower alkyl radical, each R' independently represents a hydrogen atom, a lower hydroxyalkyl group, an alkyl group having 1 to 18 carbon atoms or an alkenyl group having at most 18 carbon atoms, each R'' independently represents a hydrogen atom, a lower hydroxyalkyl group or a lower alkyl group, or R' and R'', together with the nitrogen atom to which they are attached, form a 6-membered ring, which can contain, apart from the said nitrogen atom, an oxygen or nitrogen atom, M represents a hydrogen atom, an alkali metal atom or half an atom of an alkaline earth metal, D represents a <IMAGE> group, R, x, Z, R', R'' and M being as defined above, m is a positive integer corresponding to the number of units A in the polymer, p and q are each independently 0 or a positive integer corresponding to the number of units B and C, respectively, in the polymer, such that the sum m+p+q is from about 15 to about 500.

Inventors

  • 👤 Bernard Jacquet
  • 👤 Christos Papantoniou
  • 👤 Gerard Land
  • 👤 Serge Forestier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 03:49
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/06; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/73; A61K8/731; A61K8/84; A61K8/88; A61Q5/02; C; C08; C08G; C08G69/00; C08G69/42; C08G73/00; C08G73/06; C08G73/10; C08G73/1092

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 200 words
A random polymer represented by the formula ##STR13## wherein Z represents a mercapto radical or a sulphonic acid radical, said radical being free or in the form of an alkali metal or an alkaline earth metal salt, x is an integer from 2 to 6, R represents hydrogen or lower alkyl, each R' independently represents hydrogen, lower hydroxyalkyl, alkyl having 1 to 18 carbon atoms or alkenyl having at most 18 carbon atoms, each R' independently represents hydrogen, lower hydroxyalkyl or lower alkyl, or R' and R" together with the nitrogen atom to which they are attached form a 6-membered ring which can contain, apart from the said nitrogen atom, an oxygen or nitrogen atom, M represents hydrogen, alkali metal or half an atom of an alkaline earth metal, D represents ##STR14## or .sup.⊖ --OM.sup.⊕ wherein R, x, Z, R', R" and M have the meanings given above, m is a positive integer corresponding to the number of A units in the polymer, and p and q are each independently 0 or a positive integer corresponding to the number of B and C units, respectively, in the polymer, such that the sum m+p+q is from about 15 to about 500.
Claim 2
Dependent Claim 200 words
A random polymer represented by the formula ##STR13## wherein Z represents a mercapto radical or a sulphonic acid radical, said radical being free or in the form of an alkali metal or an alkaline earth metal salt, x is an integer from 2 to 6, R represents hydrogen or lower alkyl, each R' independently represents hydrogen, lower hydroxyalkyl, alkyl having 1 to 18 carbon atoms or alkenyl having at most 18 carbon atoms, each R' independently represents hydrogen, lower hydroxyalkyl or lower alkyl, or R' and R" together with the nitrogen atom to which they are attached form a 6-membered ring which can contain, apart from the said nitrogen atom, an oxygen or nitrogen atom, M represents hydrogen, alkali metal or half an atom of an alkaline earth metal, D represents ##STR14## or .sup.⊖ --OM.sup.⊕ wherein R, x, Z, R', R" and M have the meanings given above, m is a positive integer corresponding to the number of A units in the polymer, and p and q are each independently 0 or a positive integer corresponding to the number of B and C units, respectively, in the polymer, such that the sum m+p+q is from about 15 to about 500.
Claim 3
Dependent Claim 25 words
A polymer according to claim 1 in which the individual radicals R' and R" are such that there are up to 10 different B units.
Claim 4
Dependent Claim 25 words
A polymer according to claim 2 in which the individual radicals R' and R" are such that there are 1 to 3 different B units.
Claim 5
Dependent Claim 23 words
A polymer according to claim 1 in which Z is in the form of a sodium, potassium, magnesium, calcium, strontium or barium salt.
Claim 6
Dependent Claim 17 words
A polymer according to claim 1 in which R represents alkyl having 1 to 4 carbon atoms.
Claim 7
Dependent Claim 19 words
A polymer according to claim 1 in which R' or R" represents hydroxyalkyl having 2 to 4 carbon atoms.
Claim 8
Dependent Claim 19 words
A polymer according to claim 1 in which R' and R" together represent a pentamethylene, 3-oxa-pentamethylene or N-methyl-3-aza-pentamethylene group.
Claim 9
Dependent Claim 64 words
In a cosmetic composition suitable for application to human hair, said composition being in the form of a shampoo, a hair wave setting lotion, or a hair brushing lotion, wherein the improvement comprises improving the hold of the hair and imparting bulk and springiness thereto, said composition containing 0.1 to 10 percent by weight of at least one polymer as defined in claim 1.

References Cited (Backward Citations)

FR1344212A Cited
JPS4932065A Cited
US3846380A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-13 1986-06-14 1986-12-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-13 1990-06-14 1990-12-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-13 1994-06-14 1994-12-14 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag