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US4362846A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyamide moulding compounds having high impact strength

Assignee: Bayer AG
•
Filing: 1981-04-16
•
Granted: 1982-12-07
•
Expires: 2001-04-16
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Abstract

Abstract Polymer blends consisting of from 60-99 % by weight of polyamide and of from 1-40 % by weight of a graft product of polyethylene or copolymers of ethylene with grafted units of (meth)acrylic acid and/or (meth)acrylic acid derivatives and/or maleic acid which graft products have been prepared by a special grafting process.

Inventors

  • 👤 Helmut Korber
  • 👤 Peter Tacke
  • 👤 Friedrich Fahnler
  • 👤 Dieter Neuray
  • 👤 Frieder Heydenreich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 17:53
CPC Classifications
C; C08; C08L; C08L77/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 286 words
A polymer blend consisting of I. from 60 to 99% by weight of a polyamide; II. from 1 to 40% by weight of a graft product consisting of (a) from 70 to 99% by weight of a graft substrate of polyethylene and/or a copolymer of ethylene and a vinyl ester containing up to 50% by weight of the vinyl ester, and (b) from 1 to 30% by weight of grafted units of (α) from 0 to 100% by weight, based on the total weight of grafted units, of (meth) acrylic acid, (β) from 0 to 100% by weight, based on the total weight of grafted units, of an ester of (meth) acrylic acid formed from an alcohol having from 1 to 8 carbon atoms, (γ) from 0 to 30% by weight, based on the total weight of grafted units, of acrylamide and (δ) from 0 to 30% by weight, based on the total weight of grafted units, of maleic acid anhydride, the sum total of grafted units (α) and (δ) being 100% by weight of the total grafted units of said graft product and said products having been prepared by a process of graft polymerization which comprises bringing a solvent free melted polymer used as a graft substrate into contact with oxygen or an oxygen-containing gas at a pressure of from 1 to 150 bar and at a temperature of from 80° to 300° C. under conditions of vigorous mixing for a maximum of 10 minutes, adding immediately thereafter the monomers which are to be grafted under conditions of vigorous mixing in the absence of oxygen and oxygen-containing gas, and removing the residual monomers after polymerization; and III. from 0 to 20% by weight of polyethylene.
Claim 2
Dependent Claim 286 words
A polymer blend consisting of I. from 60 to 99% by weight of a polyamide; II. from 1 to 40% by weight of a graft product consisting of (a) from 70 to 99% by weight of a graft substrate of polyethylene and/or a copolymer of ethylene and a vinyl ester containing up to 50% by weight of the vinyl ester, and (b) from 1 to 30% by weight of grafted units of (α) from 0 to 100% by weight, based on the total weight of grafted units, of (meth) acrylic acid, (β) from 0 to 100% by weight, based on the total weight of grafted units, of an ester of (meth) acrylic acid formed from an alcohol having from 1 to 8 carbon atoms, (γ) from 0 to 30% by weight, based on the total weight of grafted units, of acrylamide and (δ) from 0 to 30% by weight, based on the total weight of grafted units, of maleic acid anhydride, the sum total of grafted units (α) and (δ) being 100% by weight of the total grafted units of said graft product and said products having been prepared by a process of graft polymerization which comprises bringing a solvent free melted polymer used as a graft substrate into contact with oxygen or an oxygen-containing gas at a pressure of from 1 to 150 bar and at a temperature of from 80° to 300° C. under conditions of vigorous mixing for a maximum of 10 minutes, adding immediately thereafter the monomers which are to be grafted under conditions of vigorous mixing in the absence of oxygen and oxygen-containing gas, and removing the residual monomers after polymerization; and III. from 0 to 20% by weight of polyethylene.
Claim 3
Dependent Claim 16 words
A blend as claimed in claim 1 which contains from 70 to 95% weight of polyamide.
Claim 4
Dependent Claim 19 words
A blend as claimed in claim 1 which contains from 5 to 30% by weight of graft product II.
Claim 5
Dependent Claim 17 words
A blend as claimed in claim 1 which contains from 0 to 10% by weight of polyethylene.
Claim 6
Dependent Claim 31 words
A blend as claimed in claim 1 wherein component II contains from 75 to 95% by weight of the graft substrate, and from 5 to 25% by weight of grafted units.
Claim 7
Dependent Claim 26 words
A blend as claimed in claim 1 wherein the ester of (meth) acrylic acid is formed from an alcohol having from 2 to 4 carbon atoms.
Claim 8
Dependent Claim 21 words
A blend as claimed in claim 1 wherein the grafted units are derived from acrylic acid, n-butyl acrylate and tert. butylacrylate.
Claim 9
Dependent Claim 16 words
A blend as claimed in claim 1 wherein the polyamide is polyamide-6, polyamide-6,6 or mixtures thereof.
Claim 10
Dependent Claim 14 words
A blend as claimed in claim 1 wherein the vinyl ester is vinyl acetate.
Claim 11
Dependent Claim 13 words
A moulded article when produced from a blend as claimed in claim 1.

References Cited (Backward Citations)

US3373222A Cited
US3484403A Cited
JPS4920280A Cited
GB1403797A Cited
DE2703416A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-06 1986-06-07 1986-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-06 1990-06-07 1990-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-06 1994-06-07 1994-12-07 $7700.00 Window Closed / Lapsed

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