US4362828A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hot melt adhesive compositions
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1981-11-20
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Granted: 1982-12-07
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Expires: 2001-11-20
Abstract
Abstract This invention relates to hot melt adhesive compositions which include a neutralized EPDM terpolymer which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric EPDM terpolymer, a neutralized sulfonated 1,2-syndiotactic polybutadiene resin which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated polybutadiene, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate having about 5 to about 6 carbon atoms the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated EPDM terpolymer.
Inventors
- 👤 Pawan K. Agarwal
- 👤 Warren A. Thaler
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 00:22
CPC Classifications
C; C08; C08C; C08C19/00; C08C19/20; C09; C09J; C09J123/00; C09J123/26; C09J123/32; C08L; C08L2666/00; C08L2666/02; C08L2666/04
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
115 words
A hot melt adhesive composition which comprises: (a) a neutralized sulfonated EPDM terpolymer having about 5 to about 50 meq. of neutralized sulfonated groups per 100 grams of said neutralized sulfonated EPDM terpolymer; (b) about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate per 100 parts by weight of said neutralized sulfonated EPDM terpolymer; and (c) about 25 to about 250 parts by weight of a neutralized sulfonated 1,2-syndiotactic polybutadiene resin per 100 parts of said sulfonated EPDM terpolymer, said sulfonated 1,2-syndiotactic polybutadiene resin having about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of said neutralized sulfonated 1,2-syndiotactic polybutadiene resin.
Claim 2
Dependent Claim
115 words
A hot melt adhesive composition which comprises: (a) a neutralized sulfonated EPDM terpolymer having about 5 to about 50 meq. of neutralized sulfonated groups per 100 grams of said neutralized sulfonated EPDM terpolymer; (b) about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate per 100 parts by weight of said neutralized sulfonated EPDM terpolymer; and (c) about 25 to about 250 parts by weight of a neutralized sulfonated 1,2-syndiotactic polybutadiene resin per 100 parts of said sulfonated EPDM terpolymer, said sulfonated 1,2-syndiotactic polybutadiene resin having about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of said neutralized sulfonated 1,2-syndiotactic polybutadiene resin.
Claim 3
Dependent Claim
53 words
A hot melt adhesive composition according to claim 2, wherein said sulfonated EPDM terpolymer is derived from an EPDM terpolymer having about 40 to about 65 weight percent of ethylene, of about 25 to about 53 weight percent of propylene and of about 2 to about 10 weight percent of a nonconjugated diene.
Claim 4
Dependent Claim
15 words
A hot melt adhesive composition according to claim 2, wherein said nonconjugated diene is 5-ethylidene-2-norbornene.
Claim 5
Dependent Claim
48 words
A hot melt adhesive composition according to claim 4, wherein said neutralized sulfonate groups of said sulfonated EPDM terpolymer are neutralized with a counterion selected from the group consisting of ammonium, aluminum, antimony, iron, lead and Groups IA, IIA, IB and IIB of the Periodic Table of Elements.
Claim 6
Dependent Claim
24 words
A hot melt adhesive composition according to claim 5, wherein said neutralized sulfonate groups of said sulfonated EPDM terpolymer are neutralized with zinc ions.
Claim 7
Dependent Claim
81 words
A hot melt adhesive according to claim 1 further including about 1 to about 50 parts by weight of an ionic preferential plasticizer per 100 parts by weight of said neutralized sulfonated EPDM terpolymer, wherein said preferential plasticizer is selected from the group consisting of carboxylic acids having about 8 to about 22 carbon atoms, metallic salts of said carboxylic acids, amides having an aliphatic group of about 8 to about 22 carbon atoms, amines, ureas and thioureas and mixtures thereof.
Claim 8
Dependent Claim
31 words
A hot melt adhesive composition according to claim 6, wherein said sulfonated neutralized EPDM terpolymer contains about 7 to about 20 meq. of neutralized sulfonated groups per 100 grams of polymer.
Claim 9
Dependent Claim
20 words
A hot melt adhesive according to claim 7, wherein said preferential plasticizer is said metallic salt of said carboxylic acid.
Claim 10
Dependent Claim
20 words
A hot melt adhesive composition according to claim 8, wherein said metallic salt of said carboxylic acid is zinc stearate.
Claim 11
Dependent Claim
84 words
A hot melt adhesive composition according to claim 1 or 6 further including about 1 to about 150 parts by weight of a filler per 100 parts by weight of said neutralized sulfonated EPDM terpolymer, said filler being selected from the group consisting of calcium carbonates, silicas, carbon blacks, clays and talcs and mixtures thereof and/or less than about 100 parts by weight of an oil having less than 2 weight percent polars per 100 parts by weight of said neutralized sulfonated EPDM terpolymer.
Claim 12
Dependent Claim
33 words
A hot melt adhesive composition according to claim 1 or 8 wherein said hydrocarbon resin has about 5 to 6 carbon atoms and consists of aliphatic dienes, mono- and diolefins and cyclic olefins.
References Cited (Backward Citations)
US4158688A
Cited
US4217259A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-12-06 | 1986-06-07 | 1986-12-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-12-06 | 1990-06-07 | 1990-12-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-12-06 | 1994-06-07 | 1994-12-07 | $7700.00 | Window Closed / Lapsed |