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US4362645A Expired / Lapsed US ⏱️ 0.0 years remaining

Temperature indicating compositions of matter

Assignee: PY MAH Corp
•
Filing: 1980-11-10
•
Granted: 1982-12-07
•
Expires: 2000-11-10
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Abstract

Abstract Novel and stable compositions of matter are disclosed which change color sharply upon a transition from a liquid state to a solid state or from a solid state to a liquid state, which change of state is at substantially a predetermined temperature corresponding to a temperature to be measured. The constituents of the novel compositions of matter comprise: 1. a solvent (I) consisting of a single substance or a mixture of substances and adapted to change from a solid state at substantially a predetermined temperature to a liquid state and 2. an indicator system (II) consisting of one or more substances different from (I), characterized in that (a) (II) is soluble in (I) when the latter is in the liquid phase, and (b) (II) changes color visible to the naked eye when (I) passes from the solid to the liquid phase or from the liquid to the solid phase. Thermometers containing said stable compositions of matter are also disclosed.

Inventors

  • 👤 Craig R. Hof
  • 👤 Roy A. Ulin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 00:10
CPC Classifications
G; G01; G01K; G01K11/00; G01K11/06; G01K13/00; G01K13/20

Claims Analysis

Total Claims: 142
Claim 1
Independent Claim 443 words
A composition of matter exhibiting a sharp color change upon transition from a liquid state to a solid state or from a solid state to a liquid state, capable of being supercooled for at least several minutes, and substantially free of impurities, to form a solid solution when the composition is in a solid state, consisting essentially of: (a) a solvent adapted to change from a solid state at substantially a predetermined temperature to a liquid state; and (b) an effective amount of an indicator material selected from the group consisting of pinacyanol iodide, thionin, methylene blue, cresol red, neutral red iodide, neutral red chloride, crystal violet, acridin orange, Orasol Orange RLN™, Orasol Navy Blue ™, Irgalith Red PR™, Fat Red BS™, Xylene Cyanol FF™, Rhodamine B™, Rhodamine 6G™, Irgalith Magenta TCB™, Irgalith Pink TYNC™, Toluidene Blue O™, Savinyl Green B™, Savinyl Blue RS™, purpurin, 3,3'-diethylthiadicarbocyanine iodide, cryptocyanine, Dicyanine A™, Merocyanine 540™, 4-(p-ethoxyphenylazo)-m-phenylene diamine hydrochloride, Yellow Orange S™, Chrysoidan G™, fuchsin, aurintricarboxylic acid (ammonium salt), Victoria Blue R™, Pyronin G™, gallein, Erythrosin Yellow Blend™, chlorophenol blue, bromophenol blue, bromocresol purple, Coriphosphine O™, acriflavine, acridine orange, rhoduline violet, Alizarin Cyanine 2R™, Alizarin Red S™, alcannin, Aurantia, Direct Green G™, Fast Salt Red 3GL™, Fast Salt Blue BB™, Fast Garnet Salt GBC™, Carta Yellow G 180 0/0™, murexide, Savinyl Blue GLS™, Irgalith Blue GLSM™, phthalocyanine, Di Amingreen B™, Alizarin Blue S™, Celliton Blue Extra™ , neocyanine, Janus Green™, dimethyl yellow, Fast Yellow™, methyl red sodium salt, Alizarin Yellow R™, Eriochrome Black T™, Chromotrope 2R™, Ponceau 6R™, Brilliant Ponceau G/R/2R™, chromolan yellow, Sudan Red B™, Bismark brown G™, Fat Black™, Resorcin Brown™, Benzofast Pink 2BL™, Oil Red EGN™, Euroglaucine, Fuchsin NB™, parafuchsin, Patent Blue™, Irgalith Blue TNC™, Phloxin B™, fluorescein sodium salt, Rhodamine B base™, Eosin Scarlet, Eosin Yellowish, Erythrosin extra bluish, 4,5-dibromofluorescein, ethyleosin, Phloxin™, Cyanovin B™, chlorocresol green, pinacyanol bromide, 2-(p-dimethylaminostyryl)-1-ethylpyridinium iodide, ethyl red, nigrosine, Savinyl Blue B™, Orasol Blue BLN™, Safranin O™, Azocarnum G™, Phenosafranine™, Azocarmine BX™, Solophenyl Brilliant Blue BL™, Nile Blue A™, gallocyanine, gallamine blue, celestine blue, methylene green Azure A/B/C™, Blue VIF Organol™, Alizarin, Nitrofast Green GSB™, quinalizarine, Oil Blue N™, Solvay purple, Ciba Blue™, Indigo Synthetic™, Chromophthal Bordeau RS™, Acid Alizarin Red B™, 5-amino-fluorescein, Rose Bengal™, Martius Yellow™, Chicago Blue 6B™, Alcian Blue 8GX™, cresyl violet, 4,4-bis(dimethylamino)-benzylhydrolzinc phthalocyanine, Sudan III™, Pyronin Y™, Toluylene Blue™, cresyl violet perchlorate, Mendola's Blue™, Phosphine Dye, Nitron™, cresyl violet acetate, Ceres Orange R™, 4-phenylazo-1-naphthyl-amine, 4-(4-dimethylamino-1-naphthylazo)-3-methoxybenzene sulfonic acid, Bindschedler's Green™, and p-(p-dimethylaminophenylazo)-benzoic acid dissolved in and inert towards said solvent and adapted to change color of the composition visible to the naked eye upon the change in state at substantially the predetermined temperature when so dissolved.
Claim 2
Dependent Claim 443 words
A composition of matter exhibiting a sharp color change upon transition from a liquid state to a solid state or from a solid state to a liquid state, capable of being supercooled for at least several minutes, and substantially free of impurities, to form a solid solution when the composition is in a solid state, consisting essentially of: (a) a solvent adapted to change from a solid state at substantially a predetermined temperature to a liquid state; and (b) an effective amount of an indicator material selected from the group consisting of pinacyanol iodide, thionin, methylene blue, cresol red, neutral red iodide, neutral red chloride, crystal violet, acridin orange, Orasol Orange RLN™, Orasol Navy Blue ™, Irgalith Red PR™, Fat Red BS™, Xylene Cyanol FF™, Rhodamine B™, Rhodamine 6G™, Irgalith Magenta TCB™, Irgalith Pink TYNC™, Toluidene Blue O™, Savinyl Green B™, Savinyl Blue RS™, purpurin, 3,3'-diethylthiadicarbocyanine iodide, cryptocyanine, Dicyanine A™, Merocyanine 540™, 4-(p-ethoxyphenylazo)-m-phenylene diamine hydrochloride, Yellow Orange S™, Chrysoidan G™, fuchsin, aurintricarboxylic acid (ammonium salt), Victoria Blue R™, Pyronin G™, gallein, Erythrosin Yellow Blend™, chlorophenol blue, bromophenol blue, bromocresol purple, Coriphosphine O™, acriflavine, acridine orange, rhoduline violet, Alizarin Cyanine 2R™, Alizarin Red S™, alcannin, Aurantia, Direct Green G™, Fast Salt Red 3GL™, Fast Salt Blue BB™, Fast Garnet Salt GBC™, Carta Yellow G 180 0/0™, murexide, Savinyl Blue GLS™, Irgalith Blue GLSM™, phthalocyanine, Di Amingreen B™, Alizarin Blue S™, Celliton Blue Extra™ , neocyanine, Janus Green™, dimethyl yellow, Fast Yellow™, methyl red sodium salt, Alizarin Yellow R™, Eriochrome Black T™, Chromotrope 2R™, Ponceau 6R™, Brilliant Ponceau G/R/2R™, chromolan yellow, Sudan Red B™, Bismark brown G™, Fat Black™, Resorcin Brown™, Benzofast Pink 2BL™, Oil Red EGN™, Euroglaucine, Fuchsin NB™, parafuchsin, Patent Blue™, Irgalith Blue TNC™, Phloxin B™, fluorescein sodium salt, Rhodamine B base™, Eosin Scarlet, Eosin Yellowish, Erythrosin extra bluish, 4,5-dibromofluorescein, ethyleosin, Phloxin™, Cyanovin B™, chlorocresol green, pinacyanol bromide, 2-(p-dimethylaminostyryl)-1-ethylpyridinium iodide, ethyl red, nigrosine, Savinyl Blue B™, Orasol Blue BLN™, Safranin O™, Azocarnum G™, Phenosafranine™, Azocarmine BX™, Solophenyl Brilliant Blue BL™, Nile Blue A™, gallocyanine, gallamine blue, celestine blue, methylene green Azure A/B/C™, Blue VIF Organol™, Alizarin, Nitrofast Green GSB™, quinalizarine, Oil Blue N™, Solvay purple, Ciba Blue™, Indigo Synthetic™, Chromophthal Bordeau RS™, Acid Alizarin Red B™, 5-amino-fluorescein, Rose Bengal™, Martius Yellow™, Chicago Blue 6B™, Alcian Blue 8GX™, cresyl violet, 4,4-bis(dimethylamino)-benzylhydrolzinc phthalocyanine, Sudan III™, Pyronin Y™, Toluylene Blue™, cresyl violet perchlorate, Mendola's Blue™, Phosphine Dye, Nitron™, cresyl violet acetate, Ceres Orange R™, 4-phenylazo-1-naphthyl-amine, 4-(4-dimethylamino-1-naphthylazo)-3-methoxybenzene sulfonic acid, Bindschedler's Green™, and p-(p-dimethylaminophenylazo)-benzoic acid dissolved in and inert towards said solvent and adapted to change color of the composition visible to the naked eye upon the change in state at substantially the predetermined temperature when so dissolved.
Claim 3
Dependent Claim 410 words
A composition of matter substantially free of impurities, consisting essentially of a solid solution of: (a) a binary mixture of ortho-chloronitrobenzene and ortho bromonitrobenzene having a proportion of ortho-chloronitrobenzene to ortho bromonitrobenzene of about 43.8:56.2 to about 4.0:96.0; and (b) an effective amount of an indicator material selected from the group consisting of pinacyanol iodide, thionin, methylene blue, cresol red, neutral red iodide, neutral red chloride, crystal violet, acridin orange, Orasol Orange RLN™, Orasol Navy Blue™, Irgalith Red PR™, Fat Red BS™, Xylene Cyanol FF™, Rhodamine B™, Rhodamine 6G™, Irgalith Magenta TCB™, Irgalith Pink TYNC™, Toluidene Blue O™, Savinyl Green B™, Savinyl Blue RS™, purpurin, 3,3'-diethylthiadicarbocyanine iodide, cryptocyanine, Dicyanine A™, Merocyanine 540™, 4-(p-ethoxyphenylazo)-m-phenylene diamine hydrochloride, Yellow Orange S™, chrysoidan G™, fuchsin, aurintricarboxylic acid (ammonium salt), Victoria Blue R™, Pyronin G™, gallein, Erythrosin Yellow Blend™, chlorophenol blue, bromophenol blue, bromocresol purple, Coriphosphine O™, acriflavine, acridine orange, rhoduline violet, Alizarin Cyanine 2R™, Alizarin Red S™, alcanninn, Aurantia, Direct Green G™, Fast Salt Red 3GL™, Fast Salt Blue BB™, Fast Garnet Salt GBC™, Carta Yellow G 180 0/0™, murexide, Savinyl Blue GLS™, Irgalith Blue GLSM™, phthalocyanine, Di Amingreen B™, Alizarin Blue S™, Celliton Blue Extra™ , neocyanine, Janus Green™, dimethyl yellow, Fast Yellow™, methyl red sodium salt, Alizarin Yellow R™, Eriochrome Black T™, Chromotrope 2R™, Ponceau 6R™, Brilliant Ponceau G/R/2R™, chromolan yellow, Sudan Red B™, Bismark Brown G™, Fat Black™, Resorcin Brown™, Benzofast Pink 2BL™, Oil Red EGN™, Euroglancine, Fuchsin NB™, parafuchsin, Patent Blue™, Irgalith Blue TNC™, Phloxin B™, fluorescein sodium salt, Rhodamine B base™, Eosin Scarlet, Eosin Yellowish, Erythrosin extra bluish, 4,5-dibromofluorescein, ethyleosin, Phloxin™, Cyanovin B™, chlorocresol green pinacyanol bromide, 2-(p-dimethylaminostyryl)-1-ethylpyridinium iodide, ethyl red, nigrosine, Savinyl Blue B™, Orasol Blue BLN™, Safranin O™, Azocarnum G™, Phenosafranine™, Azocarmine BX™, Solophenyl Brilliant Blue BL™, Nile Blue A™, gallocyanine, gallamine blue, celestine blue, methylene green, Azure A/B/C™, Blue VIF Organol™, Alizarin, Nitrofast Green GSB™, quinalizarine, Oil Blue N™, Solvay purple, Ciba Blue™, Indigo Synthetic™, Chromophthal Bordeau RS™, Acid Alizarin Red B™, 5-aminofluorescein, Rose Bengal™, Martius Yellow™, Chicago Blue 6B™, Alcian Blue 8GX™, cresyl violet, 4,4-bis(dimethylamino)-benzylhydrol, zinc phthalocyanine, Sudan III™, Pyronin Y™, Toluylene Blue™, cresyl violet perchlorate, Mendola's Blue™, Phosphine Dye, Nitron™, cresyl violet acetate, Ceres Orange R™, 4-phenylazo-1-naphthylamine 4-(4-dimethylamino-1-naphthylazo)-3-methoxybenzene sulfonic acid, Bindschedler's Green™, and p-(p-dimethylaminophenylazo)-benzoic acid dissolved in and inert towards said solvent mixture (a) and adapted to change color of the composition visible to the naked eye upon the change in state from a solid state to a liquid state at a predetermined temperature.
Claim 4
Dependent Claim 410 words
A composition of matter substantially free of impurities, consisting essentially of a solid solution of: (a) a binary mixture of ortho-chloronitrobenzene and ortho bromonitrobenzene having a proportion of ortho-chloronitrobenzene to ortho bromonitrobenzene of about 43.8:56.2 to about 4.0:96.0; and (b) an effective amount of an indicator material selected from the group consisting of pinacyanol iodide, thionin, methylene blue, cresol red, neutral red iodide, neutral red chloride, crystal violet, acridin orange, Orasol Orange RLN™, Orasol Navy Blue™, Irgalith Red PR™, Fat Red BS™, Xylene Cyanol FF™, Rhodamine B™, Rhodamine 6G™, Irgalith Magenta TCB™, Irgalith Pink TYNC™, Toluidene Blue O™, Savinyl Green B™, Savinyl Blue RS™, purpurin, 3,3'-diethylthiadicarbocyanine iodide, cryptocyanine, Dicyanine A™, Merocyanine 540™, 4-(p-ethoxyphenylazo)-m-phenylene diamine hydrochloride, Yellow Orange S™, chrysoidan G™, fuchsin, aurintricarboxylic acid (ammonium salt), Victoria Blue R™, Pyronin G™, gallein, Erythrosin Yellow Blend™, chlorophenol blue, bromophenol blue, bromocresol purple, Coriphosphine O™, acriflavine, acridine orange, rhoduline violet, Alizarin Cyanine 2R™, Alizarin Red S™, alcanninn, Aurantia, Direct Green G™, Fast Salt Red 3GL™, Fast Salt Blue BB™, Fast Garnet Salt GBC™, Carta Yellow G 180 0/0™, murexide, Savinyl Blue GLS™, Irgalith Blue GLSM™, phthalocyanine, Di Amingreen B™, Alizarin Blue S™, Celliton Blue Extra™ , neocyanine, Janus Green™, dimethyl yellow, Fast Yellow™, methyl red sodium salt, Alizarin Yellow R™, Eriochrome Black T™, Chromotrope 2R™, Ponceau 6R™, Brilliant Ponceau G/R/2R™, chromolan yellow, Sudan Red B™, Bismark Brown G™, Fat Black™, Resorcin Brown™, Benzofast Pink 2BL™, Oil Red EGN™, Euroglancine, Fuchsin NB™, parafuchsin, Patent Blue™, Irgalith Blue TNC™, Phloxin B™, fluorescein sodium salt, Rhodamine B base™, Eosin Scarlet, Eosin Yellowish, Erythrosin extra bluish, 4,5-dibromofluorescein, ethyleosin, Phloxin™, Cyanovin B™, chlorocresol green pinacyanol bromide, 2-(p-dimethylaminostyryl)-1-ethylpyridinium iodide, ethyl red, nigrosine, Savinyl Blue B™, Orasol Blue BLN™, Safranin O™, Azocarnum G™, Phenosafranine™, Azocarmine BX™, Solophenyl Brilliant Blue BL™, Nile Blue A™, gallocyanine, gallamine blue, celestine blue, methylene green, Azure A/B/C™, Blue VIF Organol™, Alizarin, Nitrofast Green GSB™, quinalizarine, Oil Blue N™, Solvay purple, Ciba Blue™, Indigo Synthetic™, Chromophthal Bordeau RS™, Acid Alizarin Red B™, 5-aminofluorescein, Rose Bengal™, Martius Yellow™, Chicago Blue 6B™, Alcian Blue 8GX™, cresyl violet, 4,4-bis(dimethylamino)-benzylhydrol, zinc phthalocyanine, Sudan III™, Pyronin Y™, Toluylene Blue™, cresyl violet perchlorate, Mendola's Blue™, Phosphine Dye, Nitron™, cresyl violet acetate, Ceres Orange R™, 4-phenylazo-1-naphthylamine 4-(4-dimethylamino-1-naphthylazo)-3-methoxybenzene sulfonic acid, Bindschedler's Green™, and p-(p-dimethylaminophenylazo)-benzoic acid dissolved in and inert towards said solvent mixture (a) and adapted to change color of the composition visible to the naked eye upon the change in state from a solid state to a liquid state at a predetermined temperature.
Claim 5
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is pinacyanol iodide.
Claim 6
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is thionin.
Claim 7
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is methylene blue.
Claim 8
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is cresol red.
Claim 9
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is neutral red iodide.
Claim 10
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is neutral red chloride.
Claim 11
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is crystal violet.
Claim 12
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is acridin orange.
Claim 13
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Orasol Orange RLN™.
Claim 14
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Orasol Navy Blue™.
Claim 15
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Irgalith Red PR™.
Claim 16
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Fat Red BS™.
Claim 17
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Xylene Cyanol FF™.
Claim 18
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Rhodamine B™.
Claim 19
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Rhodamine 6G™.
Claim 20
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Irgalith Magenta TCB™.
Claim 21
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Irgalith Pink TYNC™.
Claim 22
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Toluidene Blue O™.
Claim 23
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Savinyl Green B™.
Claim 24
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Savinyl Blue RS™.
Claim 25
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is purpurin.
Claim 26
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is 3,3'-diethylthiadicarbocyanine iodide.
Claim 27
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is cryptocyanine.
Claim 28
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Dicyanine A™.
Claim 29
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Merocyanine 540™.
Claim 30
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is 4-(p-ethoxyphenylazo)-m-phenylene diamine hydrochloride.
Claim 31
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Yellow Orange S™.
Claim 32
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Chrysoidan G™.
Claim 33
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is fuchsin.
Claim 34
Dependent Claim 17 words
The composition of claim 1 or claim 2 wherein said indicator material is aurintricarboxylic acid (ammonium salt).
Claim 35
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Victoria Blue R™.
Claim 36
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Pyronin G™.
Claim 37
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is gallein.
Claim 38
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Erythrosin Yellow Blend™.
Claim 39
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is chlorophenol blue.
Claim 40
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is bromophenol blue.
Claim 41
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is bromocresol purple.
Claim 42
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Coriphosphine O™.
Claim 43
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is acriflavine.
Claim 44
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is acridine orange.
Claim 45
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is rhoduline violet.
Claim 46
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Alizarin Cyanine 2R™.
Claim 47
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Alizarin Red S™.
Claim 48
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is alcannin.
Claim 49
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is Aurantia.
Claim 50
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Direct Green G™.
Claim 51
Dependent Claim 18 words
The composition of claim 1 or claim 2 wherein said indicator material is Fast Salt Red 3 GL™.
Claim 52
Dependent Claim 17 words
The composition of claim 1 or claim 2 wherein said indicator material is Fast Salt Blue BB™.
Claim 53
Dependent Claim 17 words
The composition of claim 1 or claim 2 wherein said indicator material is Fast Garnet Salt GBC™.
Claim 54
Dependent Claim 15 words
The composition of claim 2 wherein said indicator material is Carta Yellow G 180 0/0™.
Claim 55
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is murexide.
Claim 56
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Savinyl Blue GLS™.
Claim 57
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Irgalith Blue GLSM™.
Claim 58
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is phthalocyanine.
Claim 59
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is DiAmingreen B™.
Claim 60
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Alizarin Blue S™.
Claim 61
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Celliton Blue Extra™.
Claim 62
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is neocyanine.
Claim 63
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Janus Green™.
Claim 64
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is dimethyl yellow.
Claim 65
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Fast Yellow™.
Claim 66
Dependent Claim 17 words
The composition of claim 1 or claim 2 wherein said indicator material is methyl red sodium salt.
Claim 67
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Alizarin Yellow R™.
Claim 68
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Eriochrome Black T™.
Claim 69
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Chromoscope 2R™.
Claim 70
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Ponceau 6R™.
Claim 71
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Brilliant Ponceau G/R/2R™.
Claim 72
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is chromolan yellow.
Claim 73
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Sudan Red B™.
Claim 74
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Bismark brown G™.
Claim 75
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Fat Black™.
Claim 76
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Resorcin Brown™.
Claim 77
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Benzofast Pink 2BL™.
Claim 78
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Oil Red EGN™.
Claim 79
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is Euroglaucine.
Claim 80
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Fuchsin NB™.
Claim 81
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is parafuchsin.
Claim 82
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Patent Blue™.
Claim 83
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Irgalith Blue TNC™.
Claim 84
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Phloxin B™.
Claim 85
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is fluorescein sodium salt.
Claim 86
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Rhodamine B base™.
Claim 87
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Eosin Scarlet.
Claim 88
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Eosin Yellowish.
Claim 89
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Erythrosin extra bluish.
Claim 90
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is 4,5-dibromofluorescein.
Claim 91
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is ethyleosin.
Claim 92
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is Phloxin™.
Claim 93
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Cyanovin B™.
Claim 94
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is chlorocresol green.
Claim 95
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is pinacyanol bromide.
Claim 96
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is 2-(p-dimethylaminostyryl)-1-ethyl pyridinium iodide.
Claim 97
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is ethyl red.
Claim 98
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is nigrosine.
Claim 99
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Savinyl Blue B™.
Claim 100
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Orasol Blue BLN™.
Claim 101
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Safranin O™.
Claim 102
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Azocarnum G™.
Claim 103
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is Phenosafranine™.
Claim 104
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Azocarmine BX™.
Claim 105
Dependent Claim 17 words
The composition of claim 1 or claim 2 wherein said indicator material is Solophenyl Brilliant Blue BL™.
Claim 106
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Nile Blue A™.
Claim 107
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is gallocyanine.
Claim 108
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is gallamine blue.
Claim 109
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is celestin blue.
Claim 110
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is methylene green.
Claim 111
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Azure A/B/C™.
Claim 112
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Blue VIF Organol™.
Claim 113
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is Alizarin.
Claim 114
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Nitrofast Green GSB™.
Claim 115
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is quinalizarine.
Claim 116
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Oil Blue N™.
Claim 117
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Solvay purple.
Claim 118
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Ciba Blue™.
Claim 119
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Indigo Synthetic™.
Claim 120
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is cresol red.
Claim 121
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is chromophthal Bordeau RS™.
Claim 122
Dependent Claim 17 words
The composition of claim 1 or claim 2 wherein said indicator material is Acid Alizarin Red B™.
Claim 123
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is 5-aminofluorescein.
Claim 124
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Rose Bengal™.
Claim 125
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Martius Yellow™.
Claim 126
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Chicago Blue 6B™.
Claim 127
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Alcian Blue 8GX™.
Claim 128
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is cresyl violet.
Claim 129
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is 4,4-bis(dimethylamino)-benzylhydrol.
Claim 130
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Zinc phthalocyanine.
Claim 131
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Sudan III™.
Claim 132
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Pyronin Y™.
Claim 133
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Toluylene Blue™.
Claim 134
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is cresyl violet perchlorate.
Claim 135
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Mendola's Blue™.
Claim 136
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is Nitron™.
Claim 137
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is cresyl violet acetate.
Claim 138
Dependent Claim 16 words
The composition of claim 1 or claim 2 wherein said indicator material is Ceres Orange R™.
Claim 139
Dependent Claim 14 words
The composition of claim 1 or claim 2 wherein said indicator material is 4-phenylazo-1-naphthyl-amine.
Claim 140
Dependent Claim 18 words
The composition of claim 1 or claim 2 wherein said indicator material is 4-(4-dimethylamino-1-naphthylazo) 3-methoxy benzene sulfonic acid.
Claim 141
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is Bindschedler's Green™.
Claim 142
Dependent Claim 15 words
The composition of claim 1 or claim 2 wherein said indicator material is p-(p-dimethylaminophenylazo)-benzoic acid.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-06 1986-06-07 1986-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-06 1990-06-07 1990-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-06 1994-06-07 1994-12-07 $7700.00 Window Closed / Lapsed

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