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US4361487A Expired / Lapsed US ⏱️ 0.0 years remaining

Control of hydrogen sulfide emission from geothermal steam plants with hydrogen peroxide and sodium vanadate

Assignee: FMC Corp
•
Filing: 1981-02-09
•
Granted: 1982-11-30
•
Expires: 2001-02-09
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Abstract

Abstract Removing hydrogen sulfide from geothermal steam condensate is described whereby the hydrogen sulfide that is present in the condensate from a geothermal steam plant is oxidized with a peroxygen compound such as hydrogen peroxide in the presence of catalytic quantities of sodium vanadate under neutral to alkaline conditions.

Inventors

  • 👤 William A. Hills
  • 👤 Richard A. Brown

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 23:22
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/72; C02F1/722; C02F1/725

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 39 words
A process for removing hydrogen sulfide from the condensate of spent steam in a geothermal power plant which comprises oxidizing said hydrogen sulfide with a peroxygen compound in the presence of a vanadate catalyst under neutral to alkaline conditions.
Claim 2
Dependent Claim 39 words
A process for removing hydrogen sulfide from the condensate of spent steam in a geothermal power plant which comprises oxidizing said hydrogen sulfide with a peroxygen compound in the presence of a vanadate catalyst under neutral to alkaline conditions.
Claim 3
Dependent Claim 24 words
The process of claim 1 wherein the oxidation reaction is conducted with the pH of the steam condensate between about 7.0 and about 9.0.
Claim 4
Dependent Claim 17 words
The process of claim 2 wherein the oxidation reaction is conducted at a pH of about 9.0.
Claim 5
Dependent Claim 22 words
The process of claim 1 wherein said catalyst is present in the amount of about 0.5 to about 2.0 parts per million.
Claim 6
Dependent Claim 18 words
The process of claim 4 wherein said catalyst is present in amounts of about 1 part per million.
Claim 7
Dependent Claim 16 words
The process of claim 1 wherein the temperature of the steam condensate is about 50° C.
Claim 8
Dependent Claim 12 words
The process of claim 1 wherein the peroxygen compound is hydrogen peroxide.
Claim 9
Dependent Claim 14 words
The process of claim 7 wherein the hydrogen peroxide is aqueous 30% hydrogen peroxide.
Claim 10
Dependent Claim 29 words
The process of claim 2 wherein the pH of the steam condensate is adjusted to a pH between about 7.0 and about 9.0 through the addition of sodium hydroxide.
Claim 11
Dependent Claim 29 words
The process of claim 2 wherein the pH of the steam condensate is adjusted to a pH between about 7.0 and about 9.0 through the addition of potassium hydroxide.

References Cited (Backward Citations)

GB280165A Cited
GB421970A Cited
US3097926A Cited
US3471254A Cited
US3716620A Cited
US3969479A Cited
US3941875A Cited
US3972989A Cited
US4192854A Cited
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US4259300A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-11-29 1986-05-31 1986-11-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-11-29 1990-05-31 1990-11-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-11-29 1994-05-31 1994-11-30 $7700.00 Window Closed / Lapsed

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