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US4360682A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilizing caprolactones with dihydroxybenzenes

Assignee: Bayer AG
•
Filing: 1980-05-12
•
Granted: 1982-11-23
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Expires: 2000-05-12
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Abstract

Abstract Caprolactones such as epsilon -caprolactone are stabilized against discoloration with dihydroxybenzenes such as hydroquinone or compounds of the formula <IMAGE> in which R1 is alkyl of 1 to 8 carbon atoms, and R2 is hydrogen or alkyl of 1 to 8 carbon atoms. Even the presence of air is not detrimental.

Inventors

  • 👤 Herbert Klenk
  • 👤 Rolf Wirthwein
  • 👤 Helmut Waldmann
  • 👤 Hermann Seifert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 07:53
CPC Classifications
C; C07; C07D; C07D315/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 35 words
A composition consisting essentially of caprolactone and a color stabilizing amount of a dihydroxybenzene of the formula ##STR3## in which R 1 is alkyl of 1 to 8 carbon atoms, and R 2 is hydrogen.
Claim 2
Dependent Claim 35 words
A composition consisting essentially of caprolactone and a color stabilizing amount of a dihydroxybenzene of the formula ##STR3## in which R 1 is alkyl of 1 to 8 carbon atoms, and R 2 is hydrogen.
Claim 3
Dependent Claim 18 words
A stabilized composition according to claim 1, wherein the dihydroxybenzene is present in about 50 to 500 ppm.
Claim 4
Dependent Claim 18 words
A stabilized composition according to claim 1, wherein the dihydroxybenzene is present in about 100 to 500 ppm.
Claim 5
Dependent Claim 23 words
A composition according to claim 1 wherein R 1 is alkyl of 1 to 8 carbon atoms branched at the alpha carbon atom.
Claim 6
Dependent Claim 13 words
A composition according to claim 1 wherein R 1 is a tert.-alkyl group.
Claim 7
Dependent Claim 17 words
A composition according to claim 1 wherein R 1 is an alkyl group of 3-8 carbon atoms.
Claim 8
Dependent Claim 15 words
A composition according to claim 1 wherein said caprolactone is stabilized with tertiary butyl hydroquinone.
Claim 9
Dependent Claim 14 words
A composition according to claim 1 wherein said caprolactone is stabilized with 4-tert.-butyl catechol.
Claim 10
Dependent Claim 50 words
A process for stabilizing caprolactone comprising adding thereto a color stabilizing effective amount of a composition consisting essentially of a dihydroxybenzene in the presence of air, said dihydroxybenzene being one of the formula ##STR4## wherein R 1 is alkyl of 1 to 8 carbon atoms, and R 2 is hydrogen.
Claim 11
Dependent Claim 50 words
A process for stabilizing caprolactone comprising adding thereto a color stabilizing effective amount of a composition consisting essentially of a dihydroxybenzene in the presence of air, said dihydroxybenzene being one of the formula ##STR4## wherein R 1 is alkyl of 1 to 8 carbon atoms, and R 2 is hydrogen.

References Cited (Backward Citations)

US2831817A Cited
US3227730A Cited
US3274216A Cited
US3426051A Cited
DE2160405A1 Cited
DE2215909C3 Cited
US3953531A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-11-22 1986-05-24 1986-11-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-11-22 1990-05-24 1990-11-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-11-22 1994-05-24 1994-11-23 $7700.00 Window Closed / Lapsed

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