US4359419A
Expired / Lapsed
US
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Bleed-fast cationic dye stuffs
Assignee: Kimberly Clark Tissue Co
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Filing: 1979-10-26
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Granted: 1982-11-16
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Expires: 1999-10-26
Abstract
Abstract Bleed-fast, dyed cellulosics particularly absorbent papers have been obtained with a particular class of water-soluble, cationic dyes reacted with a water-soluble dialdehyde, preferably glyoxal or glutaraldehyde. An aqueous printing fluid containing the water-soluble cationic dye and the dialdehyde, upon drying, produces a water-resistant dyestuff having improved bleed fastness upon cellulosic fibers.
Inventors
- 👤 Alex Pociluyko
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 21:54
CPC Classifications
C; C09; C09B; C09B67/00; C09B67/0071; C09B67/0075; C09B67/0076; D; D06; D06P; D06P3/00; D06P3/58; D06P3/60; D06P3/6016; D21; D21H; D21H21/00; D21H21/14; D21H21/28; Y; Y10; Y10S; Y10S8/00; Y10S8/916; Y10S8/919; Y10T; Y10T428/00; Y10T428/249921
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
263 words
The reaction product of a dialdehyde selected from the group consisting of glyoxal and glutaraldehyde and a cationic, water-soluble dyestuff of the formulae: ##STR4## wherein R 0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R 1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or (lower-alkylene)-NR 0 Y or R 1 and R 2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR5## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; k is a small integer whose value is dependent on the nature of A such that it has a range from one to two; R 8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 9 is lower-alkyl, hydroxy-lower-alkyl or NH 2 ; R 10 is lower-alkyl or lower-alkenyl; A 1 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A 1 such that it has a range from one to two; R 8' is lower alkyl; R 9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R 9' and R 10' together with the nitrogen atom are morpholino; A 2 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A 2 such that it has a range from one to two; and An is an anion.
Claim 2
Dependent Claim
263 words
The reaction product of a dialdehyde selected from the group consisting of glyoxal and glutaraldehyde and a cationic, water-soluble dyestuff of the formulae: ##STR4## wherein R 0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R 1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or (lower-alkylene)-NR 0 Y or R 1 and R 2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR5## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; k is a small integer whose value is dependent on the nature of A such that it has a range from one to two; R 8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 9 is lower-alkyl, hydroxy-lower-alkyl or NH 2 ; R 10 is lower-alkyl or lower-alkenyl; A 1 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A 1 such that it has a range from one to two; R 8' is lower alkyl; R 9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R 9' and R 10' together with the nitrogen atom are morpholino; A 2 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A 2 such that it has a range from one to two; and An is an anion.
Claim 3
Dependent Claim
115 words
The reaction product of claim 1, wherein the water-soluble dyestuff is of the formula: ##STR6## wherein R 0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R 1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or (lower-alkylene)-NR 0 Y or R 1 and R 2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR7## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; k is a small integer whose value is dependent on the nature of A such that it has a range from one to two; An is an anion.
Claim 4
Dependent Claim
84 words
The reaction product of claim 2, wherein the water-soluble dyestuff is of the formula: ##STR8## wherein R 8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 9 is lower-alkyl, hydroxy-lower-alkyl or NH 2 ; R 10 is lower-alkyl or lower-alkenyl; A 1 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A 1 such that it has a range from one to two; An is an anion.
Claim 5
Dependent Claim
95 words
The reaction product of claim 1 wherein the water-soluble dyestuff is of the formula: ##STR9## wherein R 8' is lower alkyl; R 9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R 10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R 9' and R 10' together with the nitrogen atom are morpholino; A 2 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A 2 such that it has a range from one to two; and An is an anion.
Claim 6
Dependent Claim
66 words
The reaction product of claims 1, 2, 3, or 4 wherein the bleed fastness of the reaction product as indicated by a Bleed Transference Value is about 0 on a cellulosic web when tested with water and wherein the functional group of the water-soluble dyestuff is a lower alkylene amine of the formula --(CH 2 ) n NH 2 wherein n is from 1 to 5.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-11-15 | 1986-05-17 | 1986-11-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-11-15 | 1990-05-17 | 1990-11-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-11-15 | 1994-05-17 | 1994-11-16 | $7700.00 | Window Closed / Lapsed |