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US4359398A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal compositions with novel tris-azo dichroic dyes

Assignee: Ametek Inc
•
Filing: 1980-12-22
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Granted: 1982-11-16
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Expires: 2000-12-22
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Abstract

Abstract Novel tris-azo dyes and a liquid crystal composition containing the tris-azo dyes. The tris-azo dyes are of the general formula: ##STR1## wherein R 1 and R 2 are various aromatic groups including aromatic amines, substituted aromatic amines, hydroxy-substituted aromatic groups and substituted hydroxy-containing aromatic groups. When the tris-azo dichroic dyes are used as a guest dye in a host liquid crystal material, they form a novel liquid crystal composition for use in liquid crystal displays.

Inventors

  • 👤 Herbert S. Cole, Jr.
  • 👤 Siegfried Aftergut

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:26
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/60; C09K19/601; C09B; C09B35/00; C09B35/35

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 121 words
A liquid crystal composition for use in a liquid crystal display, comprising host liquid crystal material and at least one guest dichroic dye having a maximum absorption greater than about 580 nm and having an order parameter of at least 0.70 as dissolved in said liquid material of the general formula, ##STR47## where R 1 and R 2 are selected from aromatic amine groups of the formula ##STR48## R 7 is selected from the class consisting of hydrogen, C.sub.(1-6) alkyl, aryl, arylalkyl and alkyl amine, R 8 is selected from the class consisting of hydrogen, C.sub.(1-6) alkyl, alkyl amine, alkoxy and halogen, and R 9 and R 10 are selected from the class consisting of hydrogen, C.sub.(1-3) alkyl, alkoxy and halogen.
Claim 2
Dependent Claim 121 words
A liquid crystal composition for use in a liquid crystal display, comprising host liquid crystal material and at least one guest dichroic dye having a maximum absorption greater than about 580 nm and having an order parameter of at least 0.70 as dissolved in said liquid material of the general formula, ##STR47## where R 1 and R 2 are selected from aromatic amine groups of the formula ##STR48## R 7 is selected from the class consisting of hydrogen, C.sub.(1-6) alkyl, aryl, arylalkyl and alkyl amine, R 8 is selected from the class consisting of hydrogen, C.sub.(1-6) alkyl, alkyl amine, alkoxy and halogen, and R 9 and R 10 are selected from the class consisting of hydrogen, C.sub.(1-3) alkyl, alkoxy and halogen.
Claim 3
Dependent Claim 21 words
The liquid crystal composition of claim 1, wherein the host material is a nematic liquid crystal or a cholesteric liquid crystal.
Claim 4
Dependent Claim 35 words
The liquid crystal composition of claim 2, wherein about 0.05% by weight to about 1.0% by weight (based upon the weight of the liquid crystal) of dichroic dye is dissolved in the host liquid crystal.
Claim 5
Dependent Claim 13 words
The liquid crystal composition of claim 2, wherein R 1 =R 2 .
Claim 6
Dependent Claim 24 words
The liquid crystal composition of claim 4, wherein R 7 is hydrogen, methyl or ethyl, and R 8 is methyl, ethyl, aminoethyl or phenyl.
Claim 7
Dependent Claim 14 words
The liquid crystal composition of claim 4, wherein said guest dichroic dye is 4,4'-bis(4-N-ethylaminonaphthylazo)-2,5-dimethylazobenzene.
Claim 8
Dependent Claim 28 words
The liquid crystal composition of claim 4, wherein said host liquid crystal material contains at least one other guest dichroic dyes so as to realize a given color.
Claim 9
Dependent Claim 24 words
The liquid crystal composition of claim 7, wherein said guest dichroic dye and other dichroic dyes are in proportion to realize a black display.

References Cited (Backward Citations)

US4145114A Cited
US4128497A Cited
US4128496A Cited
US4122027A Cited
US4141627A Cited
US4153343A Cited
US4116861A Cited
US4137143A Cited
JPS55127485A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-11-15 1986-05-17 1986-11-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-11-15 1990-05-17 1990-11-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-11-15 1994-05-17 1994-11-16 $7700.00 Window Closed / Lapsed

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