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US4359246A Expired / Lapsed US ⏱️ 0.0 years remaining

In situ oil shale retort with non-uniformly distributed void fraction

Assignee: Occidental Oil Shale Inc
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Filing: 1980-08-11
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Granted: 1982-11-16
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Expires: 2000-08-11
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Abstract

Abstract A method is provided for flattening a non-planar combustion zone which is advancing through a fragmented permeable mass of formation particles in an in situ oil shale retort. To effect flattening of the non-planar combustion zone, a fragmented permeable mass of formation particles having generally horizontally extending layers of various void fraction is provided in the in situ retort. At least one layer has a substantially higher effective average void fraction than adjacent layers above and below this layer. When the advancing non-planar combustion zone enters the high void fraction layer, it spreads laterally across the layer. The resulting combustion zone is approximately flat in a plane transverse to its direction of advance when it exits the high void fraction layer.

Inventors

  • 👤 Thomas E. Ricketts

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 11:49
CPC Classifications
E; E21; E21B; E21B43/00; E21B43/16; E21B43/24; E21B43/243; E21B43/247; E21B43/248

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 161 words
A method for flattening a combustion zone in a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, the method comprising the steps of: (a) explosively expanding unfragmented formation for forming a fragmented permeable mass of formation particles comprising a first generally horizontally extending layer of formation particles extending substantially across the entire horizontal extent of the retort, the first layer having an effective average void fraction greater than the effective average void fraction of second generally horizontally extending adjacent layers of formation particles above and below such a first layer; (b) establishing a combustion zone in an upper region of the fragmented permeable mass above the first layer; (c) advancing the combustion zone downwardly through the fragmented permeable mass; and (d) spreading the combustion zone laterally across the first layer for forming an approximately flat combustion zone across substantially the entire horizontal extent of the retort.
Claim 2
Independent Claim 161 words
A method for flattening a combustion zone in a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, the method comprising the steps of: (a) explosively expanding unfragmented formation for forming a fragmented permeable mass of formation particles comprising a first generally horizontally extending layer of formation particles extending substantially across the entire horizontal extent of the retort, the first layer having an effective average void fraction greater than the effective average void fraction of second generally horizontally extending adjacent layers of formation particles above and below such a first layer; (b) establishing a combustion zone in an upper region of the fragmented permeable mass above the first layer; (c) advancing the combustion zone downwardly through the fragmented permeable mass; and (d) spreading the combustion zone laterally across the first layer for forming an approximately flat combustion zone across substantially the entire horizontal extent of the retort.
Claim 3
Dependent Claim 31 words
The method according to claim 1 comprising forming the first generally horizontally extending layer of formation particles at least about forty feet below the top surface of the fragmented permeable mass.
Claim 4
Dependent Claim 46 words
The method according to claim 1 comprising forming the first generally horizontally extending layer of formation particles with an effective average void fraction from about 2% to about 10% greater than the effective average void fraction of the second generally horizontally extending layers of formation particles.
Claim 5
Dependent Claim 22 words
The method according to claim 1 wherein the first generally horizontally extending layer is from about 10 to about 40 feet thick.
Claim 6
Independent Claim 315 words
A method for recovering liquid and gaseous products from a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, the fragmented permeable mass of formation particles comprising at least one generally vertical region having a void fraction greater than the void fraction in regions of the fragmented permeable mass laterally adjacent such a generally vertical region, comprising the steps of: (a) forming a first generally horizontal layer of formation particles below at least a portion of such a generally vertical region, the first generally horizontal layer extending across substantially the entire horizontal cross-section of the retort and having an effective average void fraction greater than the effective average void fraction of adjacent horizontal layers of formation particles above and below the first layer; (b) establishing a combustion zone in an upper region of the fragmented permeable mass above the first generally horizontal layer; (c) introducing oxygen-supplying gas into the fragmented permeable mass on the trailing side of the combustion zone for: (i) sustaining the combustion zone and advancing the combustion zone through the retort, heat conveyed by flowing gases establishing a retorting zone in the fragmented permeable mass on the advancing side of the combustion zone; and (ii) advancing the retorting zone through the fragmented permeable mass on the advancing side of the combustion zone whereby kerogen is decomposed in the retorting zone for providing liquid and gaseous products, the combustion zone advancing more rapidly through the generally vertical region than through regions of the fragmented permeable mass laterally adjacent such generally vertical region, resulting in the combustion zone having a non-planar shape; (d) spreading the combustion zone laterally across the first generally horizontal layer for approximately flattening the combustion zone; and (e) withdrawing such liquid and gaseous products from the fragmented mass on the advancing side of the retorting zone.
Claim 7
Independent Claim 315 words
A method for recovering liquid and gaseous products from a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, the fragmented permeable mass of formation particles comprising at least one generally vertical region having a void fraction greater than the void fraction in regions of the fragmented permeable mass laterally adjacent such a generally vertical region, comprising the steps of: (a) forming a first generally horizontal layer of formation particles below at least a portion of such a generally vertical region, the first generally horizontal layer extending across substantially the entire horizontal cross-section of the retort and having an effective average void fraction greater than the effective average void fraction of adjacent horizontal layers of formation particles above and below the first layer; (b) establishing a combustion zone in an upper region of the fragmented permeable mass above the first generally horizontal layer; (c) introducing oxygen-supplying gas into the fragmented permeable mass on the trailing side of the combustion zone for: (i) sustaining the combustion zone and advancing the combustion zone through the retort, heat conveyed by flowing gases establishing a retorting zone in the fragmented permeable mass on the advancing side of the combustion zone; and (ii) advancing the retorting zone through the fragmented permeable mass on the advancing side of the combustion zone whereby kerogen is decomposed in the retorting zone for providing liquid and gaseous products, the combustion zone advancing more rapidly through the generally vertical region than through regions of the fragmented permeable mass laterally adjacent such generally vertical region, resulting in the combustion zone having a non-planar shape; (d) spreading the combustion zone laterally across the first generally horizontal layer for approximately flattening the combustion zone; and (e) withdrawing such liquid and gaseous products from the fragmented mass on the advancing side of the retorting zone.
Claim 8
Dependent Claim 27 words
The method according to claim 5 wherein the first generally horizontal layer is at least about forty feet below the upper surface of the fragmented permeable mass.
Claim 9
Dependent Claim 45 words
The method according to claim 5 wherein the first generally horizontal layer has an effective average void fraction from about 2% to about 10% greater than the effective average void fraction of such adjacent horizontal layers of formation particles above and below the first layer.
Claim 10
Dependent Claim 108 words
An in situ oil shale retort in a subterranean formation containing oil shale, the retort containing a fragmented permeable mass of formation particles containing oil shale, said fragmented permeable mass comprising: an upper portion having a first effective average void fraction; a lower portion having a second effective average void fraction; and an intermediate layer between the upper and lower portions having an effective average void fraction sufficiently greater than the effective average void fraction of the upper and lower portions for spreading a combustion zone advancing downwardly through the fragmented mass for forming an approximately flat combustion zone across substantially the entire horizontal extent of the retort.
Claim 11
Dependent Claim 108 words
An in situ oil shale retort in a subterranean formation containing oil shale, the retort containing a fragmented permeable mass of formation particles containing oil shale, said fragmented permeable mass comprising: an upper portion having a first effective average void fraction; a lower portion having a second effective average void fraction; and an intermediate layer between the upper and lower portions having an effective average void fraction sufficiently greater than the effective average void fraction of the upper and lower portions for spreading a combustion zone advancing downwardly through the fragmented mass for forming an approximately flat combustion zone across substantially the entire horizontal extent of the retort.
Claim 12
Dependent Claim 114 words
An in situ oil shale retort in a subterranean formation containing oil shale, the retort containing a fragmented permeable mass of formation particles containing oil shale, said fragmented permeable mass comprising: an upper portion having a first effective average void fraction; a lower portion having a second effective average void fraction; and an intermediate layer between the upper and lower portions having an effective average void fraction which is from about 2% to about 10% greater than the effective average void fractions of the upper and lower portions for spreading a combustion zone advancing downwardly through the fragmented for forming an approximately flat combustion zone across substantially the entire horizontal extent of the retort.
Claim 13
Dependent Claim 114 words
An in situ oil shale retort in a subterranean formation containing oil shale, the retort containing a fragmented permeable mass of formation particles containing oil shale, said fragmented permeable mass comprising: an upper portion having a first effective average void fraction; a lower portion having a second effective average void fraction; and an intermediate layer between the upper and lower portions having an effective average void fraction which is from about 2% to about 10% greater than the effective average void fractions of the upper and lower portions for spreading a combustion zone advancing downwardly through the fragmented for forming an approximately flat combustion zone across substantially the entire horizontal extent of the retort.
Claim 14
Independent Claim 227 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, comprising the steps of: (a) excavating a generally horizontally extending void in the subterranean formation, leaving a zone of unfragmented formation above the void; (b) forming at least two arrays of spaced apart substantially vertical columnar explosive charges in the zone of unfragmented formation, a first array nearest the void and a second array more remote from the void, the second array having a powder factor higher than the powder factor of the first array; and (c) detonating the first array of explosive charges for explosively expanding a lower portion of the unfragmented formation toward the void, forming a first horizontally extending layer of a fragmented permeable mass of formation particles in the in situ oil shale retort, while leaving a first void space between the first layer of formation particles and the remaining portion of the zone of unfragmented formation and, after a time delay, detonating the second array of explosive charges for explosively expanding an intermediate portion of the unfragmented formation toward the void, forming a second horizontally extending layer of the fragmented permeable mass of formation particles above such a first layer, the second layer having a higher effective average void fraction than the first layer.
Claim 15
Independent Claim 227 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, comprising the steps of: (a) excavating a generally horizontally extending void in the subterranean formation, leaving a zone of unfragmented formation above the void; (b) forming at least two arrays of spaced apart substantially vertical columnar explosive charges in the zone of unfragmented formation, a first array nearest the void and a second array more remote from the void, the second array having a powder factor higher than the powder factor of the first array; and (c) detonating the first array of explosive charges for explosively expanding a lower portion of the unfragmented formation toward the void, forming a first horizontally extending layer of a fragmented permeable mass of formation particles in the in situ oil shale retort, while leaving a first void space between the first layer of formation particles and the remaining portion of the zone of unfragmented formation and, after a time delay, detonating the second array of explosive charges for explosively expanding an intermediate portion of the unfragmented formation toward the void, forming a second horizontally extending layer of the fragmented permeable mass of formation particles above such a first layer, the second layer having a higher effective average void fraction than the first layer.
Claim 16
Dependent Claim 21 words
The method according to claim 10 wherein the first and second arrays of explosive charges are detonated in a single round.
Claim 17
Dependent Claim 137 words
The method according to claim 10 additionally comprising: (a) forming a third array of explosive charges in the zone of unfragmented formation more remote from the void than the second array, the third array having a powder factor lower than the powder factor of the second array; (b) leaving a second void space between the second layer of formation particles and the remaining portion of the zone of unfragmented formation; and (c) detonating the third array of explosive charges after detonation of the second array of explosive charges for explosively expanding an upper portion of the zone of unfragmented formation toward the second void space forming a third horizontally extending layer of the fragmented permeable mass of formation particles above the second layer, the third layer having a lower effective average void fraction than the second layer.
Claim 18
Dependent Claim 51 words
The method according to claim 12 wherein the arrays of explosive charges are detonated in a single round with time delays between detonation of the arrays, the time delay between detonation of the first and second arrays being longer than the time delay between detonation of the second and third arrays.
Claim 19
Independent Claim 263 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, comprising the steps of: (a) excavating a generally horizontally extending void in the subterranean formation, leaving a zone of unfragmented formation above the void; (b) explosively expanding the zone of unfragmented formation toward the void in a plurality of generally horizontal portions comprising the steps of: (i) expanding a first portion of the zone of unfragmented formation adjacent the void toward the void, wherein the volume of the void divided by the volume of the first portion plus the volume of the void defines a first available void ratio for forming a first horizontally extending layer of the fragmented mass of formation particles having a first effective average void fraction and leaving a first void space between the top of the first layer of formation particles and the bottom of a second portion of the zone of unfragmented formation; and (ii) expanding the second portion of the zone of unfragmented formation toward the first void space, wherein the volume of the first void space divided by the volume of the second portion plus the volume of the first void space defines a second available void ratio, the second available void ratio being greater than the first available void ratio for forming a second horizontally extending layer of the fragmented mass of formation particles having a second effective average void fraction, the second effective average void fraction being higher than the first effective average void fraction.
Claim 20
Independent Claim 263 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, comprising the steps of: (a) excavating a generally horizontally extending void in the subterranean formation, leaving a zone of unfragmented formation above the void; (b) explosively expanding the zone of unfragmented formation toward the void in a plurality of generally horizontal portions comprising the steps of: (i) expanding a first portion of the zone of unfragmented formation adjacent the void toward the void, wherein the volume of the void divided by the volume of the first portion plus the volume of the void defines a first available void ratio for forming a first horizontally extending layer of the fragmented mass of formation particles having a first effective average void fraction and leaving a first void space between the top of the first layer of formation particles and the bottom of a second portion of the zone of unfragmented formation; and (ii) expanding the second portion of the zone of unfragmented formation toward the first void space, wherein the volume of the first void space divided by the volume of the second portion plus the volume of the first void space defines a second available void ratio, the second available void ratio being greater than the first available void ratio for forming a second horizontally extending layer of the fragmented mass of formation particles having a second effective average void fraction, the second effective average void fraction being higher than the first effective average void fraction.
Claim 21
Dependent Claim 123 words
The method according to claim 14 comprising leaving a second void space between the top of the second layer of formation particles and the bottom of a third portion of the zone of unfragmented formation and expanding the third portion toward the second void space, wherein the volume of the second void space divided by the volume of the third portion plus the volume of the second void space defines a third available void ratio, the third available void ratio being less than the second available void ratio for forming a third horizontally extending layer of the fragmented mass of formation particles having a third effective average void fraction, the third effective average void fraction being less than the second average void fraction.
Claim 22
Dependent Claim 21 words
The method according to claim 14 comprising explosively expanding the zone of unfragmented formation toward the void in a single round.
Claim 23
Dependent Claim 69 words
The method according to claim 16 wherein a time delay between explosive expansion of the third portion of the zone of unfragmented formation and explosive expansion of the second portion of the zone of unfragmented formation is shorter than a time delay between the explosive expansion of the first portion of the zone of unfragmented formation and explosive expansion of the second portion of the zone of unfragmented formation.
Claim 24
Independent Claim 403 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, comprising the steps of: (a) excavating at least an upper and a lower generally horizontally extending void in the subterranean formation, leaving an upper zone of unfragmented formation above the upper void, an intermediate zone of unfragmented formation comprising an upper portion and a lower portion between the upper and lower voids, and a lower zone of unfragmented formation below the lower void; (b) loading the upper and lower zones of unfragmented formation with explosive for expanding the upper zone of unfragmented formation downwardly toward the upper void and for expanding the lower zone of unfragmented formation upwardly toward the lower void; (c) loading the upper portion of the intermediate zone of unfragmented formation with explosive for expanding the upper portion upwardly toward the upper void and loading the lower portion of the intermediate zone of unfragmented formation with explosive for expanding the lower portion downwardly toward the lower void, the powder factor in one of the portions being higher than the powder factor in the other portion; (d) detonating the explosive in a single round comprising the steps of: (i) detonating the explosive in the upper zone for expanding the upper zone downwardly toward the upper void; (ii) detonating explosive in the intermediate zone for expanding the upper portion of the intermediate zone upwardly toward the upper void and expanding the lower portion of the intermediate zone downwardly toward the lower void; and (iii) detonating explosive in the lower zone for expanding the lower zone upwardly toward the lower void, the unfragmented formation expanded forming horizontal layers of formation particles comprising the fragmented permeable mass of formation particles in the retort, a first layer of formation particles formed from the upper zone of unfragmented formation, a second layer of formation particles formed from the upper portion of the intermediate zone of unfragmented formation, a third layer of formation particles formed from the lower portion of the intermediate zone of unfragmented formation, and a fourth layer of formation particles formed from the lower zone of unfragmented formation, the effective average void fraction of the layer of formation particles formed from the portion of the intermediate zone with a higher powder factor being higher than the effective average void fraction of adjacent layers of formation particles.
Claim 25
Independent Claim 403 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale, comprising the steps of: (a) excavating at least an upper and a lower generally horizontally extending void in the subterranean formation, leaving an upper zone of unfragmented formation above the upper void, an intermediate zone of unfragmented formation comprising an upper portion and a lower portion between the upper and lower voids, and a lower zone of unfragmented formation below the lower void; (b) loading the upper and lower zones of unfragmented formation with explosive for expanding the upper zone of unfragmented formation downwardly toward the upper void and for expanding the lower zone of unfragmented formation upwardly toward the lower void; (c) loading the upper portion of the intermediate zone of unfragmented formation with explosive for expanding the upper portion upwardly toward the upper void and loading the lower portion of the intermediate zone of unfragmented formation with explosive for expanding the lower portion downwardly toward the lower void, the powder factor in one of the portions being higher than the powder factor in the other portion; (d) detonating the explosive in a single round comprising the steps of: (i) detonating the explosive in the upper zone for expanding the upper zone downwardly toward the upper void; (ii) detonating explosive in the intermediate zone for expanding the upper portion of the intermediate zone upwardly toward the upper void and expanding the lower portion of the intermediate zone downwardly toward the lower void; and (iii) detonating explosive in the lower zone for expanding the lower zone upwardly toward the lower void, the unfragmented formation expanded forming horizontal layers of formation particles comprising the fragmented permeable mass of formation particles in the retort, a first layer of formation particles formed from the upper zone of unfragmented formation, a second layer of formation particles formed from the upper portion of the intermediate zone of unfragmented formation, a third layer of formation particles formed from the lower portion of the intermediate zone of unfragmented formation, and a fourth layer of formation particles formed from the lower zone of unfragmented formation, the effective average void fraction of the layer of formation particles formed from the portion of the intermediate zone with a higher powder factor being higher than the effective average void fraction of adjacent layers of formation particles.
Claim 26
Dependent Claim 70 words
The method according to claim 18 wherein the volume of the upper zone of unfragmented formation plus the volume of the upper portion of the intermediate zone of unfragmented formation is about equal to the volume of the lower zone of unfragmented formation plus the lower portion of the intermediate zone of unfragmented formation and the volume of the first void is different from the volume of the second void.
Claim 27
Dependent Claim 49 words
The method according to claim 18 wherein the volume of the first and second voids is about equal and the volume of the upper portion of the intermediate zone of unfragmented formation is about equal to the volume of the lower portion of the intermediate zone of unfragmented formation.
Claim 28
Independent Claim 375 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale comprising the steps of: (a) excavating at least an upper and a lower generally horizontally extending void in the subterranean formation, leaving an upper zone of unfragmented formation above the upper void, an intermediate zone of unfragmented formation between the upper and lower voids, and a lower zone of unfragmented formation below the lower void; (b) forming an array of substantially vertical columnar explosive charges in the upper zone of unfragmented formation; (c) forming an array of substantially vertical columnar explosive charges in the lower zone of unfragmented formation; (d) forming first and second vertically spaced apart arrays of substantially vertical columnar explosive charges in the intermediate zone of unfragmented formation, the first array for expanding a first portion of the intermediate zone of unfragmented formation toward one of the voids and the second array for expanding a second portion of the intermediate zone of unfragmented formation upwardly toward the upper void and downwardly toward the lower void, the first portion being smaller than the second portion; (e) detonating explosive charges in a single round comprising the steps of: (i) detonating the array of explosive charges in the upper zone for explosively expanding the upper zone of unfragmented formation downwardly toward the upper void; (ii) detonating the array of explosive charges in the lower zone for explosively expanding the lower zone of unfragmented formation upwardly toward the lower void; and (iii) detonating the first array of explosive charges in the intermediate zone for expanding the first portion of the intermediate zone toward one of the voids and thereafter detonating the second array of explosive charges in the intermediate zone for explosively expanding the second portion of the intermediate zone upwardly toward the upper void and downwardly toward the lower void, the unfragmented formation expanded forming horizontal layers of formation particles comprising the fragmented permeable mass of formation particles in the retort, the effective average void fraction of the layer of formation particles formed by expansion of the first portion of the intermediate zone of unfragmented formation being higher than the effective average void fraction of adjacent layers.
Claim 29
Independent Claim 375 words
A method for forming a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale comprising the steps of: (a) excavating at least an upper and a lower generally horizontally extending void in the subterranean formation, leaving an upper zone of unfragmented formation above the upper void, an intermediate zone of unfragmented formation between the upper and lower voids, and a lower zone of unfragmented formation below the lower void; (b) forming an array of substantially vertical columnar explosive charges in the upper zone of unfragmented formation; (c) forming an array of substantially vertical columnar explosive charges in the lower zone of unfragmented formation; (d) forming first and second vertically spaced apart arrays of substantially vertical columnar explosive charges in the intermediate zone of unfragmented formation, the first array for expanding a first portion of the intermediate zone of unfragmented formation toward one of the voids and the second array for expanding a second portion of the intermediate zone of unfragmented formation upwardly toward the upper void and downwardly toward the lower void, the first portion being smaller than the second portion; (e) detonating explosive charges in a single round comprising the steps of: (i) detonating the array of explosive charges in the upper zone for explosively expanding the upper zone of unfragmented formation downwardly toward the upper void; (ii) detonating the array of explosive charges in the lower zone for explosively expanding the lower zone of unfragmented formation upwardly toward the lower void; and (iii) detonating the first array of explosive charges in the intermediate zone for expanding the first portion of the intermediate zone toward one of the voids and thereafter detonating the second array of explosive charges in the intermediate zone for explosively expanding the second portion of the intermediate zone upwardly toward the upper void and downwardly toward the lower void, the unfragmented formation expanded forming horizontal layers of formation particles comprising the fragmented permeable mass of formation particles in the retort, the effective average void fraction of the layer of formation particles formed by expansion of the first portion of the intermediate zone of unfragmented formation being higher than the effective average void fraction of adjacent layers.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-11-15 1986-05-17 1986-11-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-11-15 1990-05-17 1990-11-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-11-15 1994-05-17 1994-11-16 $7700.00 Window Closed / Lapsed

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