US4358181A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Gradient index optical waveguide and method of making
Assignee: Corning Glass Works
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Filing: 1980-07-24
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Granted: 1982-11-09
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Expires: 2000-07-24
Abstract
Abstract In the method of making a preform for a high numerical aperture gradient index optical waveguide, the concentration of two dopant constituents is changed during fabrication. Concentration of the first dopant, GeO 2 , is changed radially as the preform is built up in order to produce the desired radial refractive index gradient. The concentration of the second dopant, B 2 O 3 , is changed radially to compensate for the radial change in thermal expansion coefficient caused by the varying GeO 2 concentration. B 2 O 3 is added to the cladding layer to make the thermal expansion coefficient of the cladding equal to or greater than the composite thermal expansion coefficient of the core. The magnitude of residual tension at the inner surface caused by thermal expansion gradients is reduced and premature cracking of the preform is eliminated.
Inventors
- 👤 Suresh T. Gulati
- 👤 George W. Scherer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 13:13
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/02; G02B6/028; G02B6/0281; C; C03; C03B; C03B37/00; C03B37/01; C03B37/012; C03B37/014; C03B37/01413; C03B2201/00; C03B2201/06; C03B2201/08; C03B2201/10; C03B2201/30; C03B2201/31; C03B2203/00; C03B2203/10; C03B2203/22; C03B2203/225; C03B2203/26; C03B2207/00; C03B2207/80; C03B2207/85; C03B2207/86
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
206 words
The method of making an optical waveguide having a radial gradient index of refraction in the core thereof, comprising: forming a glass tubular member having at least three constituents including a silicon compound and dopants, a first of said constituents being a dopant which produces glass having a changing refractive index and thermal expansion coefficient with variations in concentration, a second of said constituents being a dopant producing changing thermal expansion coefficient with variations in concentration; radially changing the concentration of said first of said constituents while forming to produce a radially varying index of refraction; changing the concentration of said second of said constituents radially while forming to maintain the thermal expansion coefficient substantially constant throughout said radial gradient of said tubular member; coating said tubular member with a layer of cladding glass having an index of refraction less than that of the core formed by the preceding steps; and adding to the composition of said cladding layer a constituent producing substantially no increase in the index of refraction and which increases the thermal expansion coefficient of said cladding to approximately the composite thermal expansion coefficient of said core so that residual stresses in said core caused by a different expansion coefficient cladding become compressive.
Claim 2
Independent Claim
206 words
The method of making an optical waveguide having a radial gradient index of refraction in the core thereof, comprising: forming a glass tubular member having at least three constituents including a silicon compound and dopants, a first of said constituents being a dopant which produces glass having a changing refractive index and thermal expansion coefficient with variations in concentration, a second of said constituents being a dopant producing changing thermal expansion coefficient with variations in concentration; radially changing the concentration of said first of said constituents while forming to produce a radially varying index of refraction; changing the concentration of said second of said constituents radially while forming to maintain the thermal expansion coefficient substantially constant throughout said radial gradient of said tubular member; coating said tubular member with a layer of cladding glass having an index of refraction less than that of the core formed by the preceding steps; and adding to the composition of said cladding layer a constituent producing substantially no increase in the index of refraction and which increases the thermal expansion coefficient of said cladding to approximately the composite thermal expansion coefficient of said core so that residual stresses in said core caused by a different expansion coefficient cladding become compressive.
Claim 3
Dependent Claim
127 words
The method recited in claim 1 wherein the step of forming a glass tubular member is performed by outside vapor phase oxidation including the steps of: providing a substantially cylindrical starting member; rotating said cylindrical starting member about the longitudinal axis thereof; entraining in a gaseous medium predetermined amounts of each of said constituents in vapor form; oxidizing said vapor in a flame to form a soot having a specified composition; and applying said soot to the exterior peripheral surface of said cylindrical starting member; and wherein the steps of radially changing the concentration of said constituents includes: varying the amount of vapor entrained in said gaseous medium of at least two of said constituents to radially change the concentrations of said first and said second constituents.
Claim 4
Dependent Claim
14 words
The method recited in claim 1 wherein said first constituent is GeO 2 .
Claim 5
Dependent Claim
16 words
The method recited in claim 1 wherein said second constituent is B 2 O 3 .
Claim 6
Dependent Claim
23 words
The method recited in claim 1 wherein the constituent added to the composition of said cladding layer is B 2 O 3 .
Claim 7
Dependent Claim
57 words
The method recited in claim 1 wherein said composite thermal coefficient of expansion is given by: ##EQU9## where α s is said composite thermal expansion coefficient, α i is the thermal expansion coefficient at the inner radius of said tubular member and α o is the thermal expansion coefficient at the outer radius of said tubular member.
Claim 8
Dependent Claim
15 words
The method recited in claim 1 wherein said radially varying index of refraction is parabolic.
Claim 9
Dependent Claim
18 words
The method recited in claim 1 wherein the concentrations of said first and second constituents are changed parabolically.
Claim 10
Dependent Claim
10 words
An optical waveguide made by the method of claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-11-08 | 1986-05-10 | 1986-11-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-11-08 | 1990-05-10 | 1990-11-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-11-08 | 1994-05-10 | 1994-11-09 | $7700.00 | Window Closed / Lapsed |