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US4355120A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyimide foams

Assignee: I M L Corp A CORP OF
•
Filing: 1981-12-07
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Granted: 1982-10-19
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Expires: 2001-12-07
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Abstract

Abstract Copolyimide foams derived from a diester of 3,3',4,4'-benzophenonetetracarboxylic acid, an aromatic diamine, and a heterocyclic diamine. A molar concentration of the heterocyclic diamine approaching but not exceeding 0.42 is employed. This results in a flexible foam with a homogeneous cellular structure and a reduced compression set loss.

Inventors

  • 👤 John Gagliani
  • 👤 Raymond Lee
  • 👤 Usman A. K. Sorathia

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 18:04
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/02; C08J3/00; C08J3/28; C08L; C08L79/00; C08L79/04; C08L79/08; C08J2379/00; C08J2379/04; C08J2379/08

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 73 words
A polyimide foam precursor which is a resinoid obtained by combining at least one alkyl ester of 3,3',4,4'-benzophenonetetracarboxylic acid; a meta- or para-substituted aromatic diamine which is free of aliphatic moieties; and a heterocyclic diamine, said ester(s) and said diamines being present in concentrations such that the imide forming functionalities are substantially equimolar, and the molar ratio of heterocylic diamine to tetracarboxylic acid diester being in the range of about 0.4-0.42 to 1.0.
Claim 2
Dependent Claim 73 words
A polyimide foam precursor which is a resinoid obtained by combining at least one alkyl ester of 3,3',4,4'-benzophenonetetracarboxylic acid; a meta- or para-substituted aromatic diamine which is free of aliphatic moieties; and a heterocyclic diamine, said ester(s) and said diamines being present in concentrations such that the imide forming functionalities are substantially equimolar, and the molar ratio of heterocylic diamine to tetracarboxylic acid diester being in the range of about 0.4-0.42 to 1.0.
Claim 3
Dependent Claim 30 words
A polyimide foam precursor as defined in either of the preceding claims 1 or 2 which also contains from about 0.00625 to about 0.05 weight percent of an effective surfactant.
Claim 4
Dependent Claim 29 words
A polyimide foam precursor as defined in either of the preceding claims 1 or 2 in which the heterocyclic diamine is 2,6-diaminopyridine and the aromatic diamine is p,p'-methylene dianiline.

References Cited (Backward Citations)

US3726834A Cited
USRE30213E Cited
US4070312A Cited
US4241193A Cited
US4299787A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-10-18 1986-04-19 1986-10-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-10-18 1990-04-19 1990-10-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-10-18 1994-04-19 1994-10-19 $7700.00 Window Closed / Lapsed

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