US4354898A
Expired / Lapsed
US
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Method of preferentially etching optically flat mirror facets in InGaAsP/InP heterostructures
Assignee: AT&T Inc
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Filing: 1981-06-24
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Granted: 1982-10-19
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Expires: 2001-06-24
Abstract
Abstract Highly reproducible, optically flat mirror facets are created by contacting a predetermined area of the InGaAsP/InP heterostructure system with a chemical etchant for a time period sufficient to expose a substantially vertical crystallographic surface throughout the entire heterostructure system. Contact of the exposed surface with HCl causes a preferred crystallographic plane to be exposed as an optically flat mirror facet.
Inventors
- 👤 Larry A. Coldren
- 👤 Kazuhito Furuya
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:47
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/60; H10P50/64; H10P50/642; H10P50/646; H10P50/648
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
107 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: contacting a predetermined area on a given surface of the semiconductor body with a chemical etchant solution of HCl:HNO 3 =(1:α) for a time period sufficient to expose a crystallographic surface through the alternating layers of the semiconductor body substantially perpendicular to the given surface, α is in the range 1<α≦5, and contacting the exposed crystallographic surface with HCl for a time period sufficient to expose a preferred crystallographic plane as an optically flat mirror facet of the semiconductor heterostructure body.
Claim 2
Independent Claim
107 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: contacting a predetermined area on a given surface of the semiconductor body with a chemical etchant solution of HCl:HNO 3 =(1:α) for a time period sufficient to expose a crystallographic surface through the alternating layers of the semiconductor body substantially perpendicular to the given surface, α is in the range 1<α≦5, and contacting the exposed crystallographic surface with HCl for a time period sufficient to expose a preferred crystallographic plane as an optically flat mirror facet of the semiconductor heterostructure body.
Claim 3
Independent Claim
133 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: processing a predetermined area on a given surface of the semiconductor body with a material selective chemical etchant for a time period sufficient to expose a portion of a crystallographic surface corresponding to an InGaAsP layer and an abutting InP layer, contacting the exposed crystallographic surface with HCl for a time period sufficient to expose a preferred crystallographic plane corresponding to an exposed InP layer abutting the InGaAsP layer, as an optically flat mirror facet of the semiconductor heterostructure body, the preferred plane being substantially coplanar with the exposed portion of the InGaAsP crystallographic surface, and iterating in sequence the processing step followed by the contacting step.
Claim 4
Independent Claim
133 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: processing a predetermined area on a given surface of the semiconductor body with a material selective chemical etchant for a time period sufficient to expose a portion of a crystallographic surface corresponding to an InGaAsP layer and an abutting InP layer, contacting the exposed crystallographic surface with HCl for a time period sufficient to expose a preferred crystallographic plane corresponding to an exposed InP layer abutting the InGaAsP layer, as an optically flat mirror facet of the semiconductor heterostructure body, the preferred plane being substantially coplanar with the exposed portion of the InGaAsP crystallographic surface, and iterating in sequence the processing step followed by the contacting step.
Claim 5
Dependent Claim
14 words
The method as defined in claim 2 wherein the chemical etchant is AB etchant.
Claim 6
Dependent Claim
23 words
The method as defined in claim 2 wherein the chemical etchant is H 2 SO 4 :H 2 O 2 :H 2 O=(10:1:1).
Claim 7
Dependent Claim
22 words
The method as defined in claim 2 wherein the chemical etchant is a solution of KOH:K 3 Fe(CN) 6 :H 2 O.
Claim 8
Independent Claim
148 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: processing a predetermined area on a given surface of the semiconductor body with a first chemical etchant for a time period sufficient to expose a first crystallographic surface through the alternating layers of the semiconductor body at a substantially definite slope to the given surface, contacting the exposed crystallographic surface with a second chemical etchant selective of quarternary layers composed of InGaAsP for a time period sufficient to expose InGaAsP portions of a preferred crystallographic plane substantially perpendicular to the given surface, and contacting the exposed crystallographic surface corresponding to the InP layers with HCl for a time period sufficient to expose the InP portions of the preferred crystallographic plane to complete an optically flat mirror facet of the semiconductor heterostructure body.
Claim 9
Independent Claim
148 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: processing a predetermined area on a given surface of the semiconductor body with a first chemical etchant for a time period sufficient to expose a first crystallographic surface through the alternating layers of the semiconductor body at a substantially definite slope to the given surface, contacting the exposed crystallographic surface with a second chemical etchant selective of quarternary layers composed of InGaAsP for a time period sufficient to expose InGaAsP portions of a preferred crystallographic plane substantially perpendicular to the given surface, and contacting the exposed crystallographic surface corresponding to the InP layers with HCl for a time period sufficient to expose the InP portions of the preferred crystallographic plane to complete an optically flat mirror facet of the semiconductor heterostructure body.
Claim 10
Dependent Claim
20 words
The method as defined in claim 6 wherein the first chemical etchant is a dilute solution of Br:CH 3 OH.
Claim 11
Dependent Claim
22 words
The method as defined in claim 10 wherein the first chemical etchant is HCl:HNO 3 =(1:α) for α in the range 1≦α≦5.
Claim 12
Dependent Claim
18 words
The method as defined in claim 7 or claim 8 wherein the second chemical etchant is AB etchant.
Claim 13
Dependent Claim
27 words
The method as defined in claim 7 or claim 8 wherein the second chemical etchant is H 2 SO 4 :H 2 O 2 :H 2 O=(10:1:1).
Claim 14
Dependent Claim
26 words
The method as defined in claim 7 or claim 8 wherein the second chemical etchant is a solution of KOH:K 3 Fe(CN) 6 :H 2 O.
Claim 15
Independent Claim
200 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: processing a predetermined area on a given surface of the semiconductor body with a first chemical etchant for a time period sufficient to expose a first crystallographic surface through the alternating layers of the semiconductor body at a substantially definite slope to the given surface, contacting the first crystallographic surface with HCl for a time period sufficient to expose a portion of a second crystallographic surface corresponding to an exposed portion of each InP layer substantially perpendicular to the given surface, contacting the first and second crystallographic surfaces with a second chemical etchant selective of layers composed of InGaAsP for a time period sufficient to expose a portion of a preferred crystallographic plane corresponding to an exposed portion of each InGaAsP layer substantially perpendicular to the given surface, and contacting the second crystallographic surface with HCl for a time period sufficient to expose portions of the preferred crystallographic plane corresponding to exposed portions of the InP layers, thereby completing the preferred crystallographic plane as an optically flat mirror facet of the semiconductor heterostructure body.
Claim 16
Independent Claim
200 words
A method for etching a multilayer semiconductor heterostructure body having alternating layers of InGaAsP and InP on a substrate layer, the method comprising the steps of: processing a predetermined area on a given surface of the semiconductor body with a first chemical etchant for a time period sufficient to expose a first crystallographic surface through the alternating layers of the semiconductor body at a substantially definite slope to the given surface, contacting the first crystallographic surface with HCl for a time period sufficient to expose a portion of a second crystallographic surface corresponding to an exposed portion of each InP layer substantially perpendicular to the given surface, contacting the first and second crystallographic surfaces with a second chemical etchant selective of layers composed of InGaAsP for a time period sufficient to expose a portion of a preferred crystallographic plane corresponding to an exposed portion of each InGaAsP layer substantially perpendicular to the given surface, and contacting the second crystallographic surface with HCl for a time period sufficient to expose portions of the preferred crystallographic plane corresponding to exposed portions of the InP layers, thereby completing the preferred crystallographic plane as an optically flat mirror facet of the semiconductor heterostructure body.
Claim 17
Dependent Claim
31 words
The method as defined in claim 12 wherein the processing step includes contacting the predetermined area of the semiconductor body with a dry chemical etchant to expose the first crystallographic surface.
Claim 18
Dependent Claim
40 words
The method as defined in claim 12 wherein the processing step includes contacting the predetermined area of the semiconductor body with a solution of HCl:HNO 3 =(1:α) to expose the first crystallographic surface, and α is in the range 1≦α≦5.
Claim 19
Dependent Claim
18 words
The method as defined in claim 13 or claim 14 wherein the second chemical etchant is AB etchant.
Claim 20
Dependent Claim
27 words
The method as defined in claim 13 or claim 14 wherein the second chemical etchant is H 2 SO 4 :H 2 O 2 :H 2 O=(10:1:1).
Claim 21
Dependent Claim
26 words
The method as defined in claim 13 or claim 14 wherein the second chemical etchant is a solution of KOH:K 3 Fe(CN) 6 :H 2 O.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-10-18 | 1986-04-19 | 1986-10-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-18 | 1990-04-19 | 1990-10-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-18 | 1994-04-19 | 1994-10-19 | $7700.00 | Window Closed / Lapsed |