US4351897A
Expired / Lapsed
US
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Color photographic light-sensitive material
Assignee: Fujifilm Holdings Corp
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Filing: 1981-08-11
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Granted: 1982-09-28
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Expires: 2001-08-11
Abstract
Abstract A silver halide color photographic light-sensitive material is described comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) <IMAGE> (I) <IMAGE> (II) wherein Ar represents a phenyl group substituted with at least one substituent selected from a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; X represents a halogen atom or an alkoxy group; R1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; R3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R2 and R3 represents an alkoxy group; m1 and m2 each represents an integer from 1 to 4; R4 represents an alkyl group or an aryl group; R5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m1, m2 and n each is 2 or more, each R1, R3 and R5 may be the same or different. The color photographic light-sensitive material containing a 2-equivalent magenta color image-forming coupler as described above has various advantages, for example, in that the dye formation efficiency in the color development step is high, the photographic properties are not influenced by variations in the pH of the color development bath, and the color images formed are fast to heat or light.
Inventors
- 👤 Kozo Aoki
- 👤 Nobuo Seto
- 👤 Yoshiharu Yabuki
- 👤 Masakazu Morigaki
- 👤 Nobuo Furutachi
- 👤 Kotaro Nakamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 22:35
CPC Classifications
C; C07; C07D; C07D231/00; C07D231/02; C07D231/10; C07D231/14; C07D231/44; C07D231/52; G; G03; G03C; G03C7/00; G03C7/30; G03C7/32; G03C7/36; G03C7/38; G03C7/384
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
273 words
A silver halide color photographic light-sensitive material comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) ##STR27## wherein Ar represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group, and a cyano group; X represents a halogen atom or an alkoxy group; R 1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R 2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group, or an aryl group; R 3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R 2 and R 3 represents an alkoxy group; m 1 and m 2 each represents an integer from 1 to 4; R 4 represents an alkyl group or an aryl group; R 5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m 1 , m 2 and n each is 2 or more, each R 1 , R 3 and R 5 may be the same or different.
Claim 2
Dependent Claim
273 words
A silver halide color photographic light-sensitive material comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) ##STR27## wherein Ar represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group, and a cyano group; X represents a halogen atom or an alkoxy group; R 1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R 2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group, or an aryl group; R 3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R 2 and R 3 represents an alkoxy group; m 1 and m 2 each represents an integer from 1 to 4; R 4 represents an alkyl group or an aryl group; R 5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m 1 , m 2 and n each is 2 or more, each R 1 , R 3 and R 5 may be the same or different.
Claim 3
Dependent Claim
36 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkyl group for the substituent on the phenyl group represented by Ar is an alkyl group having from 1 to 22 carbon atoms.
Claim 4
Dependent Claim
36 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkoxy group for the substituent on the phenyl group represented by Ar is an alkoxy group having from 1 to 22 carbon atoms.
Claim 5
Dependent Claim
36 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkoxycarbonyl group for the substituent on the phenyl group represented by Ar is an alkoxycarbonyl group having from 2 to 23 carbon atoms.
Claim 6
Dependent Claim
29 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkoxy group represented by X is an alkoxy group having from 1 to 22 carbon atoms.
Claim 7
Dependent Claim
27 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the group R 1 includes an alkyl moiety having from 1 to 36 carbon atoms.
Claim 8
Dependent Claim
27 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the group R 1 includes an aryl moiety having from 6 to 38 carbon atoms.
Claim 9
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkyl group represented by R 2 is an alkyl group having from 1 to 22 carbon atoms.
Claim 10
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkoxy group represented by R 2 is an alkoxy group having from 1 to 22 carbon atoms.
Claim 11
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkyl group represented by R 3 is an alkyl group having from 1 to 22 carbon atoms.
Claim 12
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkoxy group represented by R 3 is an alkoxy group having from 1 to 22 carbon atoms.
Claim 13
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkyl group represented by R 4 is an alkyl group having from 1 to 22 carbon atoms.
Claim 14
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkyl group represented by R 5 is an alkyl group having from 1 to 22 carbon atoms.
Claim 15
Dependent Claim
30 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the alkoxy group represented by R 5 is an alkoxy group having from 1 to 22 carbon atoms.
Claim 16
Dependent Claim
33 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the total number of carbon atoms included in the groups represented by R 2 and R 3 is at least 6.
Claim 17
Dependent Claim
33 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the total number of carbon atoms included in the groups represented by R 4 and R 5 is at least 4.
Claim 18
Dependent Claim
22 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the photographic layer is a light-sensitive silver halide emulsion layer.
Claim 19
Dependent Claim
25 words
A silver halide color photographic light-sensitive material as in claim 17, wherein the light-sensitive silver halide emulsion layer is a green-sensitive silver halide emulsion layer.
Claim 20
Dependent Claim
40 words
A silver halide color photographic light-sensitive material as in claim 18, wherein the photographic material further contains a blue-sensitive silver halide emulsion layer containing a yellow color-forming coupler and a red-sensitive silver halide emulsion layer containing a cyan color-forming coupler.
Claim 21
Dependent Claim
25 words
A silver halide color photographic light-sensitive material as in claim 19, wherein the yellow color-forming coupler and the cyan color-forming coupler are 2-equivalent couplers, respectively.
Claim 22
Dependent Claim
226 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the coupler is a coupler represented by formula (I) ##STR28## wherein Ar represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; X represents a halogen atom or an alkoxy group; R 1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group or a trifluoromethyl group; R 2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; R 3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R 2 and R 3 represents an alkoxy group; m 1 and m 2 each represents an integer from 1 to 4; and when m 1 and m.sub. 2 each is 2 or more, each R 1 and R 3 may be the same or different.
Claim 23
Dependent Claim
39 words
A silver halide color photographic light-sensitive material as in claim 1, wherein the coupler of the formula (I) or (II) is coated in an amount of about 2×10 -3 mol to about 5×10 -1 mol per mol of silver.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-27 | 1986-03-29 | 1986-09-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-27 | 1990-03-29 | 1990-09-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-27 | 1994-03-29 | 1994-09-28 | $7700.00 | Window Closed / Lapsed |